SAFETY DATA SHEET. professional, scientific and technical activities: other professional, scientific and technical activities

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1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code CAS number Synonyms Recommended use Recommended restrictions FERROUS ETHYLENEDIAMMONIUM SULFATE, REAGENT GRADE ETHYLENEDIAMMONIUM FERROUS SULFATE, TETRAHYDRATE * OESPER'S REAGENT professional, scientific and technical activities: other professional, scientific and technical activities ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name GFS Chemicals, Inc. Address P.O. Box 245 Powell, OH United States Telephone Phone Toll Free Fax Website service@gfschemicals.com Emergency phone number 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Emergency Assistance Chemtrec hazards resulting from the material as supplied. Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information ne. ne. The substance does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known. ne. 3. Composition/information on ingredients Substances Chemical name FERROUS ETHYLENEDIAMMONIUM SULFATE Common name and synonyms ETHYLENEDIAMMONIUM FERROUS SULFATE, TETRAHYDRATE OESPER'S REAGENT CAS number % *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Move to fresh air. Call a physician if symptoms develop or persist. Rinse skin with water/shower. Rinse with water. Get medical attention if irritation develops and persists. Revision date: August Issue date: August / 6 100

2 Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Use extinguishing agent suitable for type of surrounding fire. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. This product is miscible in water. Stop the flow of material, if this is without risk. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Observe good industrial hygiene practices. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Material Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Material should be stored under an inert atmosphere. Type Value FERROUS ETHYLENEDIAMMONIUM SULFATE (CAS ) TWA US. NIOSH: Pocket Guide to Chemical Hazards Material Type 1 mg/m3 Value FERROUS ETHYLENEDIAMMONIUM SULFATE (CAS ) Biological limit values Appropriate engineering controls TWA biological exposure limits noted for the ingredient(s). 1 mg/m3 Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Eye wash fountain is recommended. Wear safety glasses with side shields (or goggles). Skin protection Hand protection Other Wear appropriate chemical resistant gloves. Gloves are recommended for prolonged use. Wear suitable protective clothing. Revision date: August Issue date: August / 6

3 Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Crystals Solid. Solid. Pale green Odorless. Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Soluble. Decomposition temperature Viscosity Other information Explosive properties Molecular formula Molecular weight Oxidizing properties 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products t explosive. Fe[NH3CH2CH2NH3](SO4)2.4H2O C2H8N2.Fe.2H2O4S t oxidizing. The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. dangerous reaction known under conditions of normal use. Contact with incompatible materials. Exposure to air. Oxidizing agents. hazardous decomposition products are known. Revision date: August Issue date: August / 6

4 11. Toxicological information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization adverse effects due to inhalation are expected. May be irritating to the skin. May be irritating to eyes. Expected to be a low ingestion hazard. Direct contact with eyes may cause temporary irritation. t known. Prolonged skin contact may cause temporary irritation. May irritate eyes. Respiratory sensitization t a respiratory sensitizer. Skin sensitization Germ cell mutagenicity Carcinogenicity May be irritating to the skin. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. t classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity OSHA Specifically Regulated Substances (29 CFR ) US. National Toxicology Program (NTP) Report on Carcinogens Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT t regulated as dangerous goods. This product is not expected to cause reproductive or developmental effects. t an aspiration hazard. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. data is available on the degradability of this substance. data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Revision date: August Issue date: August / 6

5 IATA t regulated as dangerous goods. IMDG t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations t applicable. This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations International Inventories California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Taiwan Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Taiwan Toxic Chemical Substances (TCS) Revision date: August Issue date: August / 6

6 Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # 02 August August Disclaimer Revision information The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. GFS Chemicals, Inc. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. This document has undergone significant changes and should be reviewed in its entirety. Revision date: August Issue date: August / 6