5.5 Lbs (2.5 Kg) C AV1 FUNGICIDE

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1 FUNGICIDE ACTIVE INGREDIENT: Aluminum tris (O-ethyl phosphonate) % OTHER INGREDIENTS: % TOTAL: 100.0% EPA Reg. No KEEP OUT OF REACH OF CHILDREN CAUTION F MEDICAL and TRANSPORTATION Emergencies ONLY Call 24 Hours A Day F PRODUCT USE Infmation Call If swallowed: If in eyes: If on skin clothing: If inhaled: FIRST AID Call a poison control center doct immediately f treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a poison control center doct. Do not give anything by mouth to an unconscious person. Hold eyes open and rinse slowly and gently with water f minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a poison control center doct f treatment advice. Take off contaminated clothing. Rinse skin immediately with plenty of water f minutes. Call a poison control center doct f treatment advice. Move person to fresh air. If person is not breathing, call 911 an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center doct f further treatment advice. Have the product container label with you when calling a poison control center doct going f treatment. Net Contents 5.5 Lbs (2.5 Kg) C AV1

2 PRECAUTIONARY STATEMENTS HAZARDS TO HUMANS AND DOMESTIC ANIMALS CAUTION Harmful if swallowed absbed through the skin inhaled. Causes moderate eye injury. Avoid contact with skin, eyes, clothing. PERSONAL PROTECTIVE EQUIPMENT Some materials that are chemical-resistant to this product are listed below. Applicats and other handlers must wear long-sleeved shirt and long pants, chemical resistant gloves made of any waterproof material such as polyethylene polyvinyl chlide, shoes plus socks, and protective eyewear. Follow manufacturer's instructions f cleaning/maintaining personal protective equipment (PPE). If no such instructions f washables, use detergent and hot water. Keep and wash PPE separately from other laundry. When handlers use closed systems, enclosed cabs, aircraft in a manner that meets the requirements listed in the Wker Protection Standard (WPS) f agricultural pesticides [40 CFR (d) (4-6)], the handler PPE requirements may be reduced modified as specified in the WPS. ENVIRONMENTAL HAZARDS This product is toxic to aquatic and estuarine invertebrates. Drift and runoff may be hazardous to aquatic and estuarine ganisms in neighbing areas. Do not apply directly to water, to areas where surface water is present to intertidal areas below the mean high water mark. Do not contaminate water by disposal of equipment washwaters. USER SAFETY RECOMMENDATIONS Users should: Wash hands befe eating, drinking, chewing gum, using tobacco, using the toilet. Remove PPE clothing immediately if pesticide gets inside. Then wash thoughly and put on clean clothing. DIRECTIONS FOR USE It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Read entire label befe using this product. Do not apply this product in a way that will contact wkers other persons, either directly through drift. Only protected handlers may be in the area during application. F any requirements specific to your State Tribe, consult the agency responsible f pesticide regulation. AGRICULTURAL USE REQUIREMENTS Use this product only in accdance with its labeling and with the Wker Protection Standard, 40 CFR part 170. This Standard contains requirements f the protection of agricultural wkers on farms, fests, nurseries, and greenhouses, and handlers of agricultural pesticides. It contains requirements f training, decontamination, notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the statements on this label about personal protective equipment (PPE) and restricted-entry interval. The requirements in this box only apply to uses of this product that are covered by the Wker Protection Standard. Do not enter allow wker entry into treated areas during the restricted entry interval of 12 hours. PPE required f early entry to treated areas that is permitted under the Wker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, water, is: coveralls, chemical resistant gloves made of any waterproof material, shoes plus socks, and protective eyewear. NON AGRICULTURAL USE REQUIREMENTS The requirements in this box apply to uses of this product that are not within the scope of the Wker Protection Standard f agricultural pesticides (40 CFR Part 170). The WPS applies when this product is used to produce agricultural plants on farms, fests, nurseries, greenhouses. Keep unprotected persons out of the treated areas until sprays have dried.

3 DIRECTIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Apply this product only through sprinkler irrigation systems including microjet, drip, solid set, and center pivot. Do not apply this product through any other type of irrigation system. SPRAY PREPARATION: Remove scale, pesticide residues, and other feign matter from the chemical tank and entire inject system. Flush with clean water. APPLICATION INSTRUCTIONS: First prepare a suspension of Chipco Signature in a mix tank. Fill tank with 1/2 to 3/4 the desired amount of water. Start mechanical hydraulic agitation. Add the required amount Chipco Signature, and then the remaining volume of water. Then set sprinkler to deliver 0.1 to 0.3 inch of water per acre. Start sprinkler and unifmly inject the suspension of Chipco Signature into the irrigation water line so as to deliver the desired rate per acre. The suspension of Chipco Signature should be injected with a positive displacement pump into the main line ahead of a right angle turn to insure adequate mixing. If you should have any other questions about calibration, you should contact State Extension Service specialists, equipment manufacturers other experts. NOTE: F Microjet and Drip Irrigation Systems: When treatment with Chipco Signature has been completed, further field irrigation over the treated area should be avoided f 24 to 48 hours. F Solid Set and Center Pivot Irrigation Systems: When treatment with Chipco Signature has been completed, further field irrigation over the treated area should be avoided until foliage is dry to prevent washing the chemical off the plants. GENERAL PRECAUTIONS FOR APPLICATIONS THROUGH SPRINKLER IRRIGATION SYSTEMS Maintain continuous agitation in mix tank during mixing and application to assure a unifm suspension. The system must contain a functional check valve, vacuum relief valve, and low-pressure drain appropriately located on the irrigation pipeline to prevent water source contamination from backflow. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent the flow of fluid back toward the injection pump. The pesticide injection pipeline must also contain a functional, nmally closed solenoid operated valve located on the intake side of the injection pump and connected to the system interlock to prevent fluid from being withdrawn from the supply tank when the irrigation system is either automatically manually shut down. The system must contain functional interlocking controls to automatically shut off the pesticide injection pump when the water pump mot stops. The irrigation line water pump must include a functional pressure switch, which will stop the water pump mot when the water pressure decreases to the point where pesticide distribution is adversely affected. Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump) effectively designed and constructed of materials that are compatible with pesticides and capable of being fitted with a system interlock. Do not apply when wind speed favs drift, when system connection fittings leak, when nozzles do not provide unifm distribution when lines containing the product must be dismantled and drained. Crop injury, lack of effectiveness, illegal pesticide residues in the crop may result from nonunifm distribution of treated water. Allow sufficient time f pesticide to be flushed through all lines and all nozzles befe turning off irrigation water. A person knowledgeable of the chemigation system and responsible f its operation shall shut the system down and make necessary adjustments should the need arise. Do not connect an irrigation system (including greenhouse systems) used f pesticide application to a public water system unless the label-prescribed safety devices f public water supplies are in place. General Infmation This product may cause staining. Avoid off-target sites such as sidewalks, patios, driveways, pavers, similar materials. Do not enter treated areas until spray has dried. Rinse spray equipment thoughly with warm water and detergent. TURF Chipco Signature is a systemic fungicide, which may be used, in a seasonal program f the control of Pythium diseases, such as blight and root rot, and yellow tuft on common turfgrasses on golf courses, sod farms, spts fields, residential, commercial, and other turfgrass areas. Apply as a foliar spray, using 1 to 5 gallons of water per 1,000 square feet, as indicated in the table below. Apply with a properly calibrated sprayer. DISEASE Pythium diseases, Yellow Tuft INTERVAL OF APPLICATION 21 days RATE OZ. PRODUCT/ 1,000 SQ. FT Begin preventive applications when conditions first fav disease and repeat at recommended interval. Do not mow and/ water treated areas until foliage is completely dry. Maintain agitation during spray operations. Bacterial Wilt Chipco Signature is prescribed f the alleviation of symptoms on golf course greens affected with bacterial wilt. Apply 8 oz of Chipco Signature in 2 to 4 gall of water /1,000 square feet at an interval of 7 to depending on severity of the outbreak. Use the me frequent interval when severe symptoms appear. Produced f: Bayer Environmental Science A Division of Bayer CropScience LP 2 T. W. Alexander Drive Research Triangle Park, NC 27709

4 TURF TANK MIXTURES A Chipco Signature program encourages the development of a thick, vigous turf stand that is better able to tolerate various stresses (heat, humidity, drying winds, traffic etc) that can have a negative effect on turf health. A thick, vigous Chipco Signature treated turf is better able to resist disease development and suppress the development of other pests such as weeds and algae. Summer Decline: F control of Summer Decline caused by a complex of Pythium and Rhizoctonia diseases, Chipco Signature can be tank-mixed with the products listed below in accdance with the most restrictive of label limitations and precautions. Do not exceed label dosage rates. This product cannot be mixed with any product containing a label prohibition against such mixing. Anthracnose: F improved control of anthracnose Chipco Signature can be tank-mixed with the products listed below in accdance with the most restrictive of label limitations and precautions. A preventative, multi-application (repeated every ) program must be started pri to the appearance of the disease and the conditions favable to anthracnose. Bentgrass Dead spot: F control of Bentgrass dead spot, Chipco Signature can be tank-mixed with the products listed below in accdance with the most restrictive of label limitations and precautions. A preventative, multi-application (repeated every ) program must be started pri to the appearance of the disease and the conditions favable f development of Bentgrass dead spot. PRODUCT Chipco Signature 26 GT Tartan Daconil Ultrex Fe WP ProStar 70WP Chipco Signature Fe Rainshield Daconil Ultrex RATE OZ. PRODUCT/ 1,000 SQ. FT DISEASE 4.0 to to to to to Summer Decline (Pythium, Anthracnose, and Rhizoctonia spp.) and/ Anthracnose (Colletotrichum graminicola) Bentgrass Deadspot (Ophiosphaerella agrostis) APPLICATION INTERVAL The following fungicides are physically compatible with Chipco Signature and may be substituted f the partner products listed above f use with Chipco Signature in a Summer Decline program: Bayleton 50, Cavalier 50WSB, Cavalier Flowable, Chlostar, Cleary s 3336 WP, Cleary s 3336 F, Compass, Curalan EG, Daconil Weather Stik, Daconil ZN, Eagle, Echo 90DF, Echo Flowable, Endse, Fungo Flo, Fungo 50WSB, Manicure 6 Flowable, Manicure T/O Flowable, Manicure Ultrex, Medallion, Pentathlon, Pentathlon DF, Revere 4000, SysStar, SysTec 1998, SysTec 1998 WDG, Terracl 75WP and 400, Terraguard 50W, Terrazole 35% WP, Turfcide 400, TwoSome Flowable Fungicide. Mixing Instructions Add Chipco Signature to the tank after the tank mix partner has been added and allowed to fully disperse. The der in which products are added to the tank can affect its ability to go into solution. Apply as a foliar spray using 1 to 5 gallons of water per 1,000 square feet. Apply with a properly calibrated sprayer. Begin preventative applications when conditions first fav disease and repeat at recommended interval. Do not mow and/ water treated areas until foliage is completely dry. Maintain agitation during spray operations. If a tank mix with other fungicides is used, follow label directions f the use of that product and apply at the recommended rate f control of the target disease ganism. COMPATIBILITY Chipco Signature may not be chemically compatible with foliar fertilizers with copper-based fungicides and phytotoxicity may occur. Do not mix Chipco Signature with any sticker, extender, wetting agent. To determine the physical compatibility of Chipco Signature with any other product, use a small container to mix a small amount (e.g. 1 pint) of spray solution, containing all ingredients in the same der and ratio as the anticipated use. If any indication of physical incompatibility develops, do not use this mixture f spraying. Indication of incompatibility usually appears within 5-15 minutes after mixing. Read and follow all directions and precautions on this label and on the labels of any products f which a tank mixture is being considered. Chipco Signature is not physically compatible Rubigan A.S. and Spectro 90 WDG Fungicides as a tank mixture. These products should not be combined f application. Do not graze animals on treated turf. Do not feed clippings from treated turf to livestock and poultry.

5 STORAGE AND DISPOSAL Do not contaminate water, food, feed by stage disposal. PESTICIDE STORAGE Ste in iginal container and keep tightly closed when not in use. Ste in a cool dry place. Avoid cross-contamination with other pesticides. PESTICIDE DISPOSAL Pesticides wastes are toxic. Improper disposal of excess pesticide, spray mixture, rinsate is a violation of Federal Law. If these wastes cannot be used accding to label instructions, contact your State Pesticide Environmental Control Agency Hazardous Waste representative at the nearest EPA regional office f guidance in proper disposal methods. CONTAINER HANDLING Nonrefillable container. Do not reuse refill this container. Completely empty container into application equipment. Then offer f recycling if available dispose of in a sanitary landfill by other procedures approved by state and local authities. IMPORTANT: READ BEFORE USE Read the entire Directions f Use, Conditions, and Disclaimer of Warranties and Limitations of Liability befe using this product. If terms are not acceptable, return the unopened product container at once. By using this product, user buyer accepts the following Conditions, Warranty, Disclaimer of Warranties and Limitations of Liability. CONDITIONS: The directions f use of this product are believed to be adequate and must be followed carefully. However, because of extreme weather and soil conditions, manner of use and other facts beyond Bayer CropScience LP s control, it is impossible f Bayer CropScience LP to eliminate all risks associated with the use of this product. As a result, crop injury ineffectiveness is always possible. All such risks shall be assumed by the user buyer. DISCLAIMER OF WARRANTIES: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE LP MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY. No agent of Bayer CropScience LP is authized to make any warranties beyond those contained herein to modify the warranties contained herein. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BAYER CROPSCIENCE LP DISCLAIMS ANY LIABILITY WHATSOEVER FOR CONSEQUENTIAL, SPECIAL, OR INDIRECT DAMAGES RESULTING FROM THE USE, HANDLING, OR APPLICATION OF THIS PRODUCT. LIMITATIONS OF LIABILITY: TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, THE EXCLUSIVE REMEDY OF THE USER OR BUYER FOR ANY AND ALL LOSSES, INJURIES OR DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT WHETHER IN CONTRACT, WARRANTY, TORT, NEGLIGENCE, STRICT LIABILITY OR OTHERWISE, SHALL NOT EXCEED THE PURCHASE PRICE PAID, OR AT BAYER CROPSCIENCE LP S ELECTION, THE REPLACEMENT OF PRODUCT. Bayer (reg d), the Bayer Cross (reg d), 26 GT, Bayleton, Chipco, Compass, ProStar, Tartan and Signature are trademarks of Bayer. Manicure and TwoSome are trademarks of LESCO Technologies, LLC. Endse is a trademark of Arysta Lifescience Nth American Cpation. Daconil, Daconil Ultrex, Daconil Weather Stik and Daconil ZN are registered trademarks of GB Biosciences Cpation. Fe, Rainshield and Eagle are trademarks of Dow Agrosciences LLC. Rubigan is a registered trademark of Gowan Company. Curalan is a registered trademark of BASF Aktiengesellschaft and Spectro are trademarks of Cleary Chemical Cpation. SysStar and SysTec are trademarks of Regal Chemical Company. Echo is a registered trademark of Sipcam Agro USA, Inc. Fungo is a registered trademark of The Andersons Inc. Terraguard, Terrazole and Turfcide are registered trademarks of Uniroyal Chemical Company Inc. Pentathlon is a registered trademark of Sepro Cpation. Medallion is a registered trademark of Syngenta. Terracl is a registered trademark of AMVAC.