Version: 104. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 104 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Glycerol 86 % Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Intermediate product Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2

2 Page Substance Mixture Chemical Characterization: Glycerol, CAS No , EINECS : % Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: After ingestion: No special measures required. Supply fresh air and seek medical advice in case of complaints. This product is in general not irritating to the skin. Wash with soap and rinse with plenty of water. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. Rinse mouth thoroughly with plenty of water and drink plenty of water. Consult a physician Most important Symptoms and Effects, both Acute and Delayed Symptoms: No further information available. Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: No further information available Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: CO2, extinguishing powder, water jet. Fight larger fire with water jet or alcohol resistant foam. Water with full jet Special Hazards arising from the Substance or Mixture Special hazards: In case of fire: formation of irritating gases/vapors. In case of fire: formation of carbon oxides and organic 3

3 decomposition products Advice for Firefighters Page 3 Protective equipment: Wear self-contained respiratory protective device and full protective gear Further information: Accidential Release Measures Do not inhale explosion and fire gases. Fire class: B (flammable liquid substances). Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear protective clothing. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Dilute with plenty of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent, saw dust) and dispose accordingly. For information for safe handling see Section 7. Dispose of contaminated material according to Section 13. Provide adequate ventilation Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash hands at the end of work. Preventive skin protection recommended. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry and cool room. Protect against heat and direct sunlight. Protect against humidity and water. Product is hygroscopic. Protect from frost. Store in a cool place. Information on fire and explosion protection: Do not store together with: oxidants. 4

4 Storage class (VCI): Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TWA: 50E mg/m3 Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Preventive skin protection by applying protective cream. Remove contaminated clothing immediately. Avoid contact with eyes. Not required. Protective gloves. The glove material has to be impermeable and resistant to the product / substance / preparation. Butyl or nitrile rubber. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Safety glasses recommended when refilling (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: viscous 5

5 Color: colorless Page 5 Odor: Odor threshold: ph-value: Melting temperature: odorless -10 C Boiling temperature: ca. 290 C Flash point: > 180 C Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: 1.22 g/cm3 completely miscible Product is not auto-ignitable. Decomposition temperature: ca. 400 C Viscosity, dynamic: Explosive properties: Oxidizing properties: Product does not present an explosion hazard. no information available Bulk density: Further Information Solubility in solvents: Viscosity, kinematic 6

6 Burning class: Page Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Product is hygroscopic. Stable if used according to specifications. Stable if used according to specifications. Reacts with strong oxidants. Do not overheat. Avoid humidity. Thermal decomposition above 250 C. Strong acids and strong oxidizing agents. Carbon monoxide and dioxide. Acrolein mg/kg (rat); > mg/kg (rabbit) > mg/kg (rabbit) Non irritating Non-irritating to eyes Ingestion: 7

7 No information available Page Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: No sensitizing effects known. No health impairments known or expected when used according to specifications. LC50: > mg/l (96h, Leuciscus idus) LC50: mg/l (Salmo gairdneri) EC50: > mg/l (24h, Daphnia magna) Readily biodegradable. No bioaccumulation. Not applicable. 1, slightly hazardous AOX Value: 8

8 Page Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: Environmental Hazards Not classified as environmentally hazardous. 9

9 Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water Not listed Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.