SAFETY DATA SHEET ZOBELL SOLUTION, ORP STANDARD

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier means of identification Product code 5525 Recommended use Recommended restrictions ZOBELL SOLUTION, ORP STANDARD professional, scientific and technical activities: other professional, scientific and technical activities ne known. Manufacturer/Importer/Supplier/Distributor information Company name Address GFS Chemicals, Inc. P.O. Box 245 Powell OH US Telephone Phone Toll Free Fax Website Emergency phone number 2. Hazard(s) identification Physical hazards Health hazards OSHA hazard(s) Emergency Assistance Chemtrec hazards resulting from the material as supplied. Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) symbol. 3. Composition/information on ingredients Mixtures n-hazardous components Chemical name CAS number % WATER POTASSIUM CHLORIDE POTASSIUM FERROCYANIDE, TRIHYDRATE POTASSIUM FERRICYANIDE *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret First-aid measures Inhalation Unlikely route of exposure as the product does not contain volatile substances. 1 / 6

2 Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed 5. Fire-fighting measures Rinse with water. Rinse with water. Get medical attention if irritation develops and persists. Drink water as a precaution. Get medical attention if symptoms occur. Treat symptomatically. Suitable extinguishing media Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Use extinguishing agent suitable for type of surrounding fire. Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage t applicable. Wear suitable protective equipment. Precautions for safe handling Avoid release to the environment. Conditions for safe storage, including any incompatibilities This product is miscible in water. Stop the flow of material, if this is without risk. Large Spills: Dike the spilled material, where this is possible. Flush into sewer with plenty of water. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Keep refrigerated. 8. Exposure controls/personal protection Occupational exposure limits exposure limits noted for ingredient(s). Biological limit values Appropriate engineering controls biological exposure limits noted for the ingredient(s). General ventilation normally adequate. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Respiratory protection Thermal hazards General hygiene considerations Wear safety glasses with side shields (or goggles). t normally needed. rmal work clothing (long sleeved shirts and long pants) is recommended. personal respiratory protective equipment normally required. 9. Physical and chemical properties Appearance Physical state Handle in accordance with good industrial hygiene and safety practice. Clear. Liquid. 2 / 6

3 Odor Form Color Odor threshold ph Aqueous solution. Colorless. Odorless. Melting point/freezing point 32 F (0 C) estimated Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) t applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor density Relative density Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Miscible Decomposition temperature Viscosity information Density Percent volatile Specific gravity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information 1.01 g/cm3 estimated 99 % estimated 1.01 estimated Material is stable under normal conditions. Hazardous polymerization does not occur. ne under normal conditions. ne known. Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects toxicity hazardous decomposition products are known. Based on available data, the classification criteria are not met. 3 / 6

4 Product Species ZOBELL SOLUTION, ORP STANDARD (CAS Mixture) Oral Rat Components Species POTASSIUM CHLORIDE (CAS ) Oral LD50 Guinea pig Mouse Rat Rat POTASSIUM FERRICYANIDE (CAS ) POTASSIUM FERROCYANIDE, TRIHYDRATE (CAS ) Oral LD50 Rat mg/kg, estimated mg/kg, estimated 5200 mg/kg, estimated 2500 mg/kg 383 mg/kg 2600 mg/kg 117 mg/kg 39 mg/kg 2970 mg/kg 6400 mg/kg, (anhydrous) * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Further information 12. Ecological information Ecotoxicity Product ZOBELL SOLUTION, ORP STANDARD (CAS Mixture) Crustacea Components May irritate eyes. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product has no known adverse effect on human health. Contains a substance which causes risk of hazardous effects to the environment. EC50 POTASSIUM CHLORIDE (CAS ) Aquatic Crustacea EC50 Species Daphnia Species Water flea (Daphnia magna) Western mosquitofish (Gambusia affinis) mg/l, 48 hours, estimated mg/l, 96 hours, estimated 83 mg/l, 48 hours 435 mg/l, 96 hours 4 / 6

5 Components POTASSIUM FERRICYANIDE (CAS ) Aquatic Species Rainbow trout,donaldson trout (Oncorhynchus mykiss) POTASSIUM FERROCYANIDE, TRIHYDRATE (CAS ) Aquatic Rainbow trout,donaldson trout (Oncorhynchus mykiss) mg/l, 96 hours mg/l, 96 hours * Estimates for product may be based on additional component data not shown. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential Mobility in soil adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information Wash to drains with lots of water. Dispose in accordance with all applicable regulations. DOT t regulated as a hazardous material by DOT. IATA t regulated as a dangerous good. IMDG t regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. information available. CERCLA/SARA Hazardous Substances - t applicable. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) t on regulatory list. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical federal regulations Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 5 / 6

6 Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) and Chemical Code Number t listed. Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) DEA Exempt Chemical Mixtures Code Number Food and Drug Administration (FDA) US state regulations US. Massachusetts RTK - Substance List California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance t listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s) 16. information, including date of preparation or last revision Issue date Version # 01 Further information Disclaimer August The information in the sheet was written based on the best knowledge and experience currently available. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 6 / 6