Lyreco Mechanical Pencil 0.5mm Blk

Transcription

1 Lyreco Chemwatch Hazard Alert Code: 1 Safety Data Sheet (Conforms to Regulation (EU) No 2015/830) S.REACH.GBR.EN SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPAN / UNDERTAKING 1.1. Product Identifier Product Synonyms Other means of identification 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against SDS are intended for use in the workplace. Pencil Details of the supplier of the safety data sheet Registered company Lyreco Address Deer Park Court, Donnington Wood Telford, TF2 7NB United Kingdom Telephone Fax Website steve.weston@lyreco.com 1.4. Emergency telephone number Association / Organisation Emergency telephone numbers Other emergency telephone numbers SECTION 2 HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Not considered a hazardous mixture according to Reg. (EC) No 1272/2008 and their amendments. Not classified as Dangerous Goods for transport purposes. CHEMWATCH HAZARD RATINGS Flammability 0 Toxicity 0 Body Contact 0 Reactivity 1 Chronic 0 Min Max 0 = Minimum 1 = Low 2 = Moderate 3 = High 4 = Extreme Classification according to regulation (EC) No 1272/2008 [CLP] 2.2. Label elements CLP label elements SIGNAL WORD NOT APPLICABLE Hazard statement(s) Supplementary statement(s)

2 Page 2 of 7 Precautionary statement(s) Prevention P101 If medical advice is needed, have product container or label at hand. Precautionary statement(s) Response Precautionary statement(s) Storage Precautionary statement(s) Disposal 2.3. Other hazards REACh - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS 3.1.Substances See 'Composition on ingredients' in Section Mixtures 1.CAS No 2.EC No 3.Index No 4.REACH No %[weight] Name Classification according to regulation (EC) No 1272/2008 [CLP] 100 ingredients determined to be non-hazardous balance ingredients, non-hazardous 1. Classified by Chemwatch; 2. Classification drawn from EC Directive 67/548/EEC - Annex I ; 3. Classification drawn from EC Directive 1272/ Annex VI 4. Classification drawn from C&L SECTION 4 FIRST AID MEASURES 4.1. Description of first aid measures General Eye Contact Skin Contact Inhalation Ingestion Wash affected areas with warm water and soap. Seek medical attention if swelling/redness/blistering or irritation occurs. If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Not considered a normal route of entry. If this product comes in contact with eyes: Wash out immediately with water. If irritation continues, seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. Wash affected areas with warm water and soap. Seek medical attention if swelling/redness/blistering or irritation occurs. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Not considered a normal route of entry. 4.2 Most important symptoms and effects, both acute and delayed See Section Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5 FIREFIGHTING MEASURES 5.1. Extinguishing media Water spray or fog Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

3 Page 3 of Advice for firefighters Fire Fighting Fire/Explosion Hazard Alert Fire Brigade and tell them location and nature of hazard. Combustible. Combustion products include:, carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) SECTION 6 ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures See section Environmental precautions See section Methods and material for containment and cleaning up Minor Spills Major Spills Clean up all spills immediately. Minor hazard Reference to other sections Personal Protective Equipment advice is contained in Section 8 of the SDS. SECTION 7 HANDLING AND STORAGE 7.1. Precautions for safe handling Safe handling Fire and explosion protection Other information Remove all ignition sources. No special handling procedures required. See section 5 Keep dry Conditions for safe storage, including any incompatibilities Suitable container Storage incompatibility Plastic container Packaging as recommended by manufacturer. Avoid reaction with oxidising agents 7.3. Specific end use(s) See section 1.2 SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Control parameters DERIVED NO EFFECT LEVEL (DNEL) PREDICTED NO EFFECT LEVEL (PNEC) OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material TWA STEL Peak Notes EMERGENC LIMITS Ingredient Material TEEL-1 TEEL-2 TEEL Lyreco Mechanical Pencil 0.5mm Blk Ingredient Original IDLH Revised IDLH ingredients determined to be non-hazardous 8.2. Exposure controls Appropriate engineering controls None under normal operating conditions.

4 Page 4 of Personal protection Eye and face protection Skin protection Hands/feet protection Body protection Other protection Thermal hazards See Hand protection below See Other protection below Environmental exposure controls See section 12 SECTION 9 PHSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Solid; insoluble in water. Physical state Manufactured Relative density (Water = 1) Odour Odour threshold ph (as supplied) Melting point / freezing point ( C) Initial boiling point and boiling range ( C) Partition coefficient n-octanol / water Auto-ignition temperature ( C) Decomposition temperature Viscosity (cst) Molecular weight (g/mol) Flash point ( C) Taste Evaporation rate Explosive properties Upper Explosive Limit (%) Flammability Oxidising properties Surface Tension (dyn/cm or mn/m) Lower Explosive Limit (%) Volatile Component (%vol) Vapour pressure (kpa) Gas group Solubility in water (g/l) Immiscible ph as a solution (1%) Vapour density (Air = 1) VOC g/l 9.2. Other information SECTION 10 STABILIT AND REACTIVIT 10.1.Reactivity See section Chemical stability Unstable in the presence of incompatible materials Possibility of hazardous reactions See section Conditions to avoid See section Incompatible materials See section Hazardous decomposition products See section 5.3 SECTION 11 TOXICOLOGICAL INFORMATION Information on toxicological effects Inhaled Ingestion Skin Contact Eye Chronic Not normally a hazard due to non-volatile nature of product Not normally a hazard due to the physical form of product. Not normally a hazard due to physical form of product. Generated dust may be discomforting Not normally a hazard due to physical form of product. Generated dust may be highly discomforting

5 Page 5 of Lyreco Mechanical Pencil 0.5mm Blk TOXICIT IRRITATION 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances Lyreco Mechanical Pencil 0.5mm Blk No significant acute toxicological data identified in literature search. Acute Toxicity Skin Irritation/Corrosion Serious Eye Damage/Irritation Respiratory or Skin sensitisation Mutagenicity Carcinogenicity Reproductivity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard Data available but does not fill the criteria for classification Data available to make classification Data to make classification SECTION 12 ECOLOGICAL INFORMATION Toxicity Ingredient Endpoint Test Duration (hr) Species Value Source Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air Bioaccumulative potential Ingredient Bioaccumulation Mobility in soil Ingredient Mobility 12.5.Results of PBT and vpvb assessment P B T Relevant available data PBT Criteria fulfilled? Other adverse effects No data available SECTION 13 DISPOSAL CONSIDERATIONS Waste treatment methods Product / Packaging disposal Waste treatment options Sewage disposal options Recycle wherever possible or consult manufacturer for recycling options. SECTION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZCHEM NO Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

6 Page 6 of UN number 14.2.UN proper shipping Class Subrisk 14.4.Packing group 14.5.Environmental hazard Hazard identification (Kemler) Classification code Hazard Label Limited quantity Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS UN number UN proper shipping ICAO/IATA Class ICAO / IATA Subrisk ERG Code Packing group Environmental hazard Cargo Only Packing Instructions Cargo Only Maximum Qty / Pack Passenger and Cargo Packing Instructions Passenger and Cargo Maximum Qty / Pack Passenger and Cargo Limited Quantity Packing Instructions Passenger and Cargo Limited Maximum Qty / Pack Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS UN number UN proper shipping IMDG Class IMDG Subrisk Packing group Environmental hazard EMS Number Limited Quantities Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS UN number UN proper shipping Packing group Environmental hazard Classification code Limited quantity Equipment required Fire cones number Transport in bulk according to Annex II of MARPOL and the IBC code

7 Page 7 of 7 SECTION 15 REGULATOR INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : 98/24/EC, 92/85/EC, 94/33/EC, 91/689/EEC, 1999/13/EC, Commission Regulation (EU) 2015/830, Regulation (EC) No 1272/2008 and their amendments Chemical safety assessment For further information please look at the Chemical Safety Assessment and Exposure Scenarios prepared by your Supply Chain if available. ECHA SUMMAR National Inventory Australia - AICS Canada - DSL Canada - NDSL China - IECSC Europe - EINEC / ELINCS / NLP Japan - ENCS Korea - KECI New Zealand - NZIoC Philippines - PICCS USA - TSCA Status = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SECTION 16 OTHER INFORMATION Full text Risk and Hazard codes Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references. The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards: EN 166 Personal eye-protection EN 340 Protective clothing EN 374 Protective gloves against chemicals and micro-organisms EN Footwear protecting against chemicals EN 133 Respiratory protective devices Definitions and abbreviations PC-TWA: Permissible Concentration-Time Weighted Average PC-STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit IDLH: Immediately Dangerous to Life or Health Concentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index This document is copyright. end of SDS