Safety Data Sheet. 1. Identification. 2. Hazards Identification. 3. Composition and Information on Ingredients

Transcription

1 Product identifier General description Recommended use Restriction(s) on use Supplier information Emergency phone number: Physical hazards Health hazards Environmental hazards Safety Data Sheet 1. Identification Concrete Dissolver Modified Acid Concrete Acid Etching None Acrow-Richmond 172 Bethridge Rd. Toronto, ON M9W 1N Chemtrec (US & Canada) Chemtrec (Outside the US & Canada) Hazards Identification Not classified Skin irritation Category 2 Metal corrosion Category 1 Eye irritation Category 2 Not classified Label elements Signal word Hazard statements Danger H290 May be corrosive to metals H315 Causes skin irritation H319 Causes serious eye irritation P261 Avoid breathing vapors/mist P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. P273 Avoid release to the environment. 3. Composition and Information on Ingredients Chemical Name % by Weight CAS# Synthetic Salts Trade Secret Trade Secret Precautionary statements HMIRA Registry Number : 9211The granted date associated with this product is: Page 1 of 5

2 Eye contact Skin contact Ingestion Inhalation Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Hazardous combustion products Personal precautions Environmental precautions Methods and materials for containment and cleaning up Precautions for safe handling Shelf Life Conditions for safe storage 4. First Aid Measures Flush with water while holding eyelids open for several minutes. Remove contact lenses if present and able to do. Call a physician if irritation persists. Remove contaminated clothing. As a precaution, wash exposed area with soap and water when convenient. Call a physician if rash or other symptoms develop. Launder clothes before reuse. If ingested, may cause loose stools. Drink plenty (3-4 glasses) of water and consult a physician. Do not induce vomiting. Remove to fresh air. Treat symptoms. Seek medical attention if required. 5. Fire-Fighting Measures Water fog. Foam. Dry chemical powder. This chemical is not classified as flammable Self-contained breathing apparatus and full protective clothing must be worn in case of fire Decomposition may produce toxic gases. May include, but is not limited to : Carbon dioxide, Carbon monoxide and Nitrous gases 6. Accidental Release Measures Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not handle damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection see section 8 of the SDS. Do not allow to enter into sewer, water system or soil Small spills may be absorbed with non-reactive absorbent and placed in suitable, labeled containers. Prevent large spills from entering sewers and waterways. Never return spills in original containers for re-use. Product can be neutralized with water and magnesium oxide or soda ash. Dispose in accordance to local and federal regulations. Always sample spill and calculate via titration the suitable amount of material to be used to properly neutralize. 7. Handling and Storage Provide adequate ventilation. Avoid contact with skin and eyes. Wash thoroughly after handling. No known limit. Recommended: Use within 1 year. For increased shelf life keep in a closed container away from incompatible materials (e.g. bases, strong oxidizing agents, or strong reducing agents). Page 2 of 5

3 Occupational exposure limit values Engineering controls Eye/face protection Hand protection Respiratory protection Other information 8. Exposure Controls and Personal Protection Ensure adequate ventilation Wear safety glasses Wear nitrile gloves Where exposure guideline levels may be exceeded, use an approved NIOSH respirator The availability of an eye wash station/safety shower is required. 9. Physical and Chemical Properties Appearance Liquid Color Amber Odor Almost odorless Odor threshold ph <0.5 Freezing point -10 O C Boiling point >212 O F (>100 O C) Pour point -10 O C Specific gravity 1.05 Partition coefficient (n-octanol/water) Flash point >212 O F (>100 O C) Vapor pressure 10. Stability and Reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products LD50 oral Routes of exposure Respiratory sensitization Skin sensitization Carcinogenicity 11. Toxicological Information Inhalation Skin contact Eye contact Ingestion Reacts with bases Do not mix with strong bases, strong oxidizing agents, or strong reducing agents. Will not occur. No recommendation given Strong bases. Strong oxidizing agents. Strong reducing agents None under normal conditions >2000 mg/kg (rat oral) Eye, Skin Contact, Inhalation, Ingestion The chemical irritates the respiratory system and may cause itching, stinging and coughing Irritates the skin. May cause redness, stinging and itching. Irritating to eyes and may cause redness, watering and stinging. May cause irritation of the mucous membranes, nausea, vomiting and diarrhea Page 3 of 5

4 Mutagenicity Reproductive toxicity Teratogenicity Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Disposal instructions Hazardous waste code Waste from residues/unused products Contaminated packaging Transport of Dangerous Goods (TDG) Proof of Classification 12. Ecological Information No available data No available data Low potential to bioaccumulate The product is water soluble and may spread in water systems Large spills can negatively impact the aquatic environment locally due to a decrease in the ph value 13. Disposal Considerations Dispose of contents/container in accordance with local/regional/national/international regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company Empty containers may retain some product residues. This material and its container must be disposed of in a safe manner. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal 14. Transport Information In accordance with Part of the TDG regulations, we certify that the classification of this product is correct as of the SDS date of issue U.S. Department of Transportation (DOT) UN number 1760 Proper shipping name Corrosive liquid, n.o.s. Technical name Synthetic Salts Hazard class 8 Packing group III Transportation of Dangerous Goods (TDG Canada) UN number 1760 Proper shipping name Corrosive liquid, n.o.s. Technical name Synthetic Salts Hazard class 8 Packing group III Page 4 of 5

5 Canadian federal regulations US federal regulations 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the HPR and the SDS contains all the information required by the HPR This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard, 29 CFR Inventory status Country Inventory name On Inventory? Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States Toxic Substances Control Act (TSCA) Inventory 16. Other Information Yes HMIS Rating Health 1 Flammability 0 Physical Hazard 1 Personal Protection B The information accumulated herein is believed to be accurate based on the information provided, although no guarantee or warranty, either expressed or implied is made as to the accuracy or completeness of this information, whether originating with this company or not. Recipients are advised to confirm in advance of need that the information is correct, applicable and suitable to their circumstances. The conditions or methods of handling, storage, use and disposal Disclaimer of the product and container are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage or use of this information or product. If the product is used as a component in another product, this information may not be applicable. Issue date 25 th January 2017 Version # 1 Effective date 25 th January 2017 Prepared by Alexander Jamieson, Global Compliance Officer +1 (403) Page 5 of 5