APPYCLEAN 6781 Materiel Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue : 15/05/2012 Revision date : 15/05/2012 Release 2

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1 SECTION_1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical type : Mixture Trade name : REACH number : all the ingredients of this product in the scope of Regulation 1907/2006/EC (REACH), if not exempted, have been pre-registered. C&L notification reference no. : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Industrial use Industrial/Professional use spec. : wide dispersive use Industrial category : IC2 - Chemical industry: basic chemicals,ic3 - Chemical industry: chemicals used in synthesis Uses advised against 1.3. Details of the supplier of the safety data sheet WHEATOLEO Route de Bazancourt POMACLE (FRANCE) Tel : +33 (0) Fax : +33 (0) Emergency telephone number Emergency number : +33 (0) (0) (ORFILA) Country Official advisory body Address Emergency number SECTION2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Dam. 1 H318 Full text of H-phrases: see section Classification according to Directive 67/548/EEC or 1999/45/EC Xi;R Adverse physicochemical, human health and environmental effects 1/6

2 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS05 Signal word (CLP) : Danger Hazard statements (CLP) : H318 - Causes serious eye damage Precautionary statements (CLP) : P280 - Wear face protection, protective clothing, protective gloves. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minuts. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTER or doctor/physician Labelling according to Directive 67/548/EEC or 1999/45/EC Hazard symbols : Xi - Irritant Hazardous ingredients : D-Xylopyranose, oligomeric, C8-10-alkyl, D-Glucopyranose, oligomeric, C8-10-alkyl R-phrases : R41 - Risk of serious damage to eyes. S-phrases : S25 - Avoid contact with eyes. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek Medical advice. S39 - Wear eye/face protection. Extra phrases : The surfactant(s) contained in this preparation complies(comply) with the Biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Warning - this preparation contains a substance not yet tested completely 2.3. Other hazards SECTION 3 : Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Chemical Name Product Identifier % Classification according to Directive 67/548/EEC D-Glucopyranose, oligomeric, C8-10-alkyl (constituant principal) D-Xylopyranose, oligomeric, C8-10-alkyl (constituant) CAS N : CAS N : Xi ; R Xi ; R41 Chemical Name Product Identifier % Classification according to Regulation (EC) N. 1272/2008 [CLP] D-Glucopyranose, oligomeric, C8-10-alkyl (constituant principal) D-Xylopyranose, oligomeric, C8-10-alkyl (constituant) CAS N : CAS N : Eye Dam. 1, H Eye Dam. 1, H318 Full text of R-, H- and EUH-phrases: see section 16. 2/6

3 SECTION_4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice. First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Wash immediately with lots of water. Soap may be used. Take victim to a doctor if irritation persists. First-aid measures after eye contact : Take victim to an ophthalmologist. Rinse immediately with plenty of water for 15 minutes. First-aid measures after ingestion : Rinse mouth with water. Call Poison Information Centre ( Consult a doctor/medical service if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries : 4.3. Indication of any immediate medical attention and special treatment needed SECTION_5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard : DIRECT FIRE HAZARD. Combustible. INDIRECT FIRE HAZARD. Heating increases the fire hazard. Temperature above flashpoint: higher fire/explosion hazard. Explosion hazard : No direct explosion hazard. Reactivity : On burning: release of (carbon monoxide - carbon dioxide). General measures : Mark the danger area. Exposure to heat: have neighbourhood close doors and windows Advice for firefighters Other information : SECTION_6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up Other information : 6.4. Reference to other sections SECTION_7: Handling and storage 7.1. Precautions for safe handling Handling temperature : 10 C above melting point 7.2. Conditions for safe storage, including any incompatibilities Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: ignition sources. (strong) acids. (strong) bases. Storage area : Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements. Special rules on packaging : SPECIAL REQUIREMENTS: closing. correctly labelled. meet the legal requirements. Packaging materials : 7.3. Specific end use(s) SECTION_8: Exposure controls/personal protection 8.1. Control parameters 3/6

4 8.2. Exposure controls Personal protective equipment : Materials for protective clothing : Gloves. Protective clothing. Safety glasses. GIVE GOOD RESISTANCE: nitrile rubber. SECTION_9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance (room temperature) : Liquid. Viscous. Colour : Brown. Odour : Characteristic odour. Sweet odour. ph : 4-8 (10%v/v H2O:IPA [1:1]) Melting point : No supplementary information available Boiling point : > 100 C Flash point : > 100 C Vapour pressure : No supplementary information available Relative vapour density at 20 C : No data available Density : ca. 1,15 g/cm³ Solubility : No data available Log Pow : No data available Self ignition temperature : > 200 C Decomposition temperature : No data available Viscosity: No data available 9.2. Other information Softening point: Other properties: <20 C Soluble in water SECTION_10: Stability and reactivity Reactivity On burning: release of carbon monoxide - carbon dioxide Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION_11: Toxicological information Information on toxicological effects Serious eye damage/irritation : Causes serious eye damage. : D-Xylopyranose, oligomeric, C8-10-alkyl ( ) : D-Glucopyranose, oligomeric, C8-10-alkyl ( ) : 4/6

5 SECTION_12: Ecological information Toxicity Ecology - general : According to literature: no environmental hazard. Ecology - air : Ecology - water : No bioaccumulation data available BOD (% de ThOD) > 60 % ThOD (OECD 301F; 28days) D-Xylopyranose, oligomeric, C8-10-alkyl ( ) : BOD (% de ThOD) > 60 % ThOD (OECD 301F; 28days) D-Glucopyranose, oligomeric, C8-10-alkyl ( ) : BOD (% de ThOD) > 60 % ThOD (OECD 301F; 28days) Bioaccumulative potential Mobility in soil Ecology - soil Biodegradability in soil: no data available. D-Xylopyranose, oligomeric, C8-10-alkyl ( ) : Ecology - soil Biodegradability in soil: no data available. D-Glucopyranose, oligomeric, C8-10-alkyl ( ) : Ecology - soil Biodegradability in soil: no data available Results of PBT and vpvb assessment Other adverse effects Other information: SECTION_13: Disposal considerations Waste treatment methods Disposal : Prevent dispersion by covering with dry absorbent, Scoop solid spill into closing containers, Scoop absorbed substance into closing containers, Clean contaminated surfaces with an excess of water and soap solution, Wash clothing and equipment after handling Ecology - waste materials : Do not discharge into drains or the environment. Remove to an authorized waste treatment plant. Regional legislation (waste) : SECTION_14: Transport information No dangerous good in sense of transport regulations. SECTION_15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Extra phrases : The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Warning - this preparation contains a substance not yet tested completely National regulations EURAL code : No supplementary information available Chemical inventories : Listed on EC inventories WGK class : 1 (weak water endangering) Chemical safety assessment 5/6

6 SECTION_16: Other information Chem. inventories legend : EC inventories = European Community inventories of chemicals (EINECS/ELINCS/NLP/REACh) SDS Reason for revision : No supplementary information available SDS changed sections : 16 - Other information;1 - Identification of the substance or preparation Training advice : Other information : Full text of R-, H- and EUH-phrases: Eye Dam.1 Serious Eye Damage/Irritation Category H318 Causes serious eye damage R41 Risk of serious damage to eyes. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 6/6