Version: 2. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 2 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Canada Balsam Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H226 Cat.: 3 H312 Cat.: 4 H315 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 R10 Harmful (Xn) R20 R21 Irritating (Xi) R38 Flammable liquids, category 3 Acute toxicity (dermal), hazard category 4 Skin irritation, category 2 Flammable liquid and vapour. Harmful in contact with skin. Causes skin irritation. Flammable. Harmful by inhalation. Harmful in contact with skin. Irritating to skin Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 See Section 12. Hazard designation: 2

2 Page 2 GHS02-1 GHS07 Signal word: Hazard designation: Safety designation: H226 H312 H315 P102 P210 P233 P240 P241 P242 P243 P264 P280 P302+P352 P303+P361+P353 P321 P362 P370+P378 P403+P235 P501 Warning Flammable liquid and vapour. Harmful in contact with skin. Causes skin irritation. Keep out of reach of children. Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Wear protective gloves/ clothing/ eye/ face protection. If on skin: Wash with soap and water. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Specific treatment (see label). Take off contaminated clothing and wash before reuse. In case of fire: Use sand, dry extinguishing powder or foam for extinction. Store in a well ventilated place. Keep cool. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Mixture of oleoresin acid and ethereal oils. Hazardous Ingredients: Canada balsam (R10-20/21-38; H ) 100 % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: 3

3 Page First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Supply fresh air and seek medical advice in case of complaints. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water. In case of discomfort seek medical help After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. CO2, extinguishing powder, sand or earth Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Never apply a strong water jet Special hazards: Advice for Firefighters Protective equipment: Wear self-contained respiratory protective device Further information: Cool exposed containers with water spray. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Ensure adequate ventilation. Wear appropriate protective equipment. Keep spectators away. 4

4 6. 2. Environmental Precautions Page Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, universal absorbent, Oil Dri) and dispose accordingly. Protective clothing, see Section 8. Avoid the formation of aerosol Hygienic measures: Conditions for Safe Storage, including any Incompatibilities No further measures, see Section 8. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a cool and well ventilated location. Do not store together with food stuff and animal feed. Avoid pollution of soil. Combustible liquid. Keep away from sources of ignition. 3: Flammable liquids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 5

5 Additional Information: Exposure Controls Page 5 Technical protective measures: No further measures, see Section 7. Personal Protection General protective measures: Respiratory protection: Hand protection: Avoid contact with eyes. Do not eat, drink or smoke during work. In case of long-term or higher exposure. Protective gloves (EN 374) Protective glove material: Eye protection: Body protection: Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: highly viscous liquid yellowish characteristic Flash point: 43 C Evaporation rate: Flammability (solid, gas): Upper explosion limit: not applicable Lower explosion limit: 6

6 Page Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid g/cm3 (20 C) insoluble not available no information available Flammable liquid. Fire hazard. Stable if used according to specifications. None if handled and stored according to specifications. Conditions to avoid: 7

7 Avoid heat and sources of ignition. Page 7 Thermal decomposition: No further information available Imcompatible Materials Strong oxidizing agents Hazardous Decomposition Products None known Further Information 11. Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: > 5000 mg/kg (rat) LD50, dermal: > 5000 mg/kg (rabbit) LC50, inhalation: Primary effects Irritant effect on skin: Slight irritant effect. Irritant effect on eyes: Slight irritant effect Inhalation: Ingestion: No information available Sensitization: May cause sensitization. Mutagenicity: Reproductive toxicity: Cancerogenity: No data available. Teratogenicity: Specific target organ toxicity (STOT): No data available. Additional toxicological information: 12. Ecological Information Aquatic Toxicity 8

8 Fish toxicity: Page Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number Not easily eliminated from water. No data available. 1, slightly hazardous Do not let product enter waterways or sewage system. Dispose of according to official national and local regulations. Uncontaminated packaging may be recycled ADR, IMDG, IATA 1993 UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ENTZÜNDBARER FLÜSSIGER STOFF, N.A.G. (Terpenkohlenwasserstoff) FLAMMABLE LIQUID, N.O.S.(Terpenoid hydrocarbon, terpene) ADR Class: 3 Hazard no.: 3 Classification code: Tunnel no.: F1 D/E 9

9 Page 9 IMDG Class (sea): 3 Hazard no.: 3 EmS No.: F-E, S-E IATA Class: 3 Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User III III III None none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water Appendix II: not listed Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties. This Safety Data Sheet replaces that of