MATERIAL SAFETY DATA SHEET

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Cleaning product Restrictions on use : Reserved for industrial and professional use. Product dilution information : 2.5 % % Company : ECOLAB PTY LTD (A.B.N ) 2 Drake Avenue Macquarie Park, NSW Australia Emergency telephone number : Issuing date : Section: 2. HAZARDS IDENTIFICATION Classified as hazardous according to the criteria of Safe Work Australia and not classified as dangerous goods according to the ADG Code. Hazard classification R-phrase(s) S-phrase(s) : Xi - IRRITANT : R36/38 - Irritating to eyes and skin. : S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37 - Wear suitable protective clothing and gloves. S39 - Wear eye/face protection. Not classified as hazardous according to the criteria of Safe Work Australia nor classified as dangerous goods according to the ADG Code. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) dodecylbenzene sulfonic acid and its salt monoethanolamine sodium dodecylbenzene sulfonate ethanol No hazardous ingredients Section: 4. FIRST AID MEASURES / 9

2 In case of eye contact In case of skin contact If swallowed : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. : Rinse mouth with water. Contact the Poison's Information Centre (eg Australia ; New Zealand ). If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth with water. Contact the Poison's Information Centre (eg Australia ; New Zealand ). If inhaled : Get medical attention if symptoms occur. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides : Use personal protective equipment / 9

3 Specific extinguishing methods : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products will cause chlorine gas. : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : -15 C to 50 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Permissible concentration Basis / 9

4 monoethanolamine TWA 3 ppm 7.5 mg/m3 VLE 6 ppm 15 mg/m3 ethanol TWA 1,000 ppm 1,880 mg/m3 AU OEL AU OEL AU OEL Engineering measures : Effective exhaust ventilation system Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Safety glasses with side-shields : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Colour : clear, purple purple Odour : citrus citrus ph : , 100 % Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate : Not applicable. : > 100 C / 9

5 Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble : The substance or mixture is not classified as oxidizing. Section: 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : Do not mix with bleach or other chlorinated products will cause chlorine gas. : None known. : Acids : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation : Causes eye irritation. : Causes skin irritation / 9

6 Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain : Redness, Irritation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity / 9

7 Acute oral toxicity : dodecylbenzene sulfonic acid and its salt LD50 rat: 890 mg/kg monoethanolamine LD50 rat: 1,089 mg/kg sodium dodecylbenzene sulfonate LD50 rat: 1,086 mg/kg ethanol LD50 rat: 10,470 mg/kg Acute inhalation toxicity : monoethanolamine 4 h LC50 rat: > 1.6 mg/l ethanol 4 h LC50 rat: 117 mg/l Acute dermal toxicity : dodecylbenzene sulfonic acid and its salt LD50 rabbit: 800 mg/kg monoethanolamine LD50 rabbit: 1,025 mg/kg ethanol LD50 rabbit: > 15,800 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish : This product has no known ecotoxicological effects. : dodecylbenzene sulfonic acid and its salt 96 h LC50 Fish: 4.3 mg/l sodium dodecylbenzene sulfonate 96 h LC50: 3.2 mg/l ethanol 96 h LC50 Fish: 11,000 mg/l Toxicity to daphnia and other aquatic invertebrates : monoethanolamine 48 h EC50 Daphnia: 65 mg/l / 9

8 Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (ADG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Not intended for transport. Section: 15. REGULATORY INFORMATION National regulatory information Standard for the Uniform Scheduling of Medicines and Poisons : No poison schedule number allocated The components of this product are reported in the following inventories: United States TSCA Inventory : / 9

9 Canadian Domestic Substances List (DSL) : This product contains the following components that are not on the Canadian DSL nor NDSL. Australia. Industrial Chemical (Notification and Assessment) Act : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : On the inventory, or in compliance with the inventory Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : Section: 16. OTHER INFORMATION Sources of key data used to compile the Material Safety Data Sheet Globally Harmonized System of Classification and Labelling of Chemicals (GHS) IARC: (International Agency for Research on Cancer) US. National Toxicology Program (NTP) Report on Carcinogens ECHA List of Publishable Substances Registered EU HPVCs (High Production Volume Chemicals) Issuing date : Date of first issue : version : 1.0 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the MSDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 9