SAFETY DATA SHEET SLF16S42, SOLFLEX 16S42

Transcription

1 SAFETY DATA SHEET SLF16S42, SOLFLEX 16S42 SDS No. G3811A NA / EN 1. IDENTIFICATION of the SUBSTANCE and COMPANY Trade Name Chemical Name Synonym(s): SLF16S42, SOLFLEX 16S42 Styrene-butadiene polymer SBR Company Identification The Goodyear Tire & Rubber Company Akron, Ohio U.S.A. Goodyear Canada, Inc., 450 Kipling Ave., Etobicoke, Ontario M8Z 5E1 Canada Emergency Phone Number Chemical Transportation Emergency Assistance Chemtrec (USA) Canutec (Canada) Goodyear / 24 hour Assistance MSDS Information ISSUED BY - Global Chemical Material Management - Akron, Ohio Technical Assistance HAZARDS IDENTIFICATION Emergency Overview If ignited by excessive heat or open flame, this product will burn. Vapors generated during processing may be irritating to the eyes, skin or respiratory system. APPEARANCE: Solid ODOR: Odorless Potential Health Effects --- PRIMARY ROUTES OF ENTRY --- Dermal (skin) contact --- SHORT-TERM EXPOSURE --- Vapors generated during processing may be irritating to the eyes, skin or respiratory system. Contact with the molten material will burn the skin and eyes. --- LONG-TERM EXPOSURE --- None known for product as produced. USA/Canada This product does not contain a SARA S-313 Toxic Chemical above the de minimis thresholds. This material is not considered hazardous under the OSHA Hazard Communication Standard CFR Title 29, Part or the WHMIS Canadian legislation. Page 1 of 6

2 G3811A - SLF16S42, SOLFLEX 16S42 3. COMPOSITION / INFORMATION on the COMPONENTS Product Description: Polymer Hazardous components Chemical name Percentage by wt. CAS-No Rosin < Non-hazardous information Chemical name Percentage by wt. CAS-No Styrene-Butadiene polymer FIRST AID MEASURES No procedures are expected to be required. Eye Contact Flush with plenty of water. If irritation persists, seek medical attention. Contact with molten materials, requires immediate medical assistance. Skin Contact Wash with soap and water. If irritation persists, seek medical attention. In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin. Seek immediate medical attention/advice. Inhalation If overcome by exposure, remove victim to fresh air. If symptoms persist, obtain medical attention. Ingestion Seek immediate medical attention. Note for Physician: Treat symptomatically 5. FIRE-FIGHTING MEASURES FLASH POINT and METHOD Not determined. FLAMMABLE LIMITS LEL Not established for product UEL Not established for product AUTO-IGNITION TEMP Not determined. --- EXTINGUISHING MEDIA --- Water, all purpose (ABC) dry chemical, CO2, foam. --- SPECIAL FIRE-FIGHTING PROCEDURES --- During emergency conditions, overexposure to thermal decomposition products may cause a health hazard. An approved, self-contained breathing apparatus should be worn. --- UNUSUAL FIRE AND EXPLOSION HAZARD --- When exposed to excessive heat or open flames, emits acrid and toxic fumes and/or smoke. Page 2 of 6

3 G3811A - SLF16S42, SOLFLEX 16S42 NFPA Rating Health 1 Fire 1 Reactivity 0 Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme 6. ACCIDENTAL RELEASE MEASURES ---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up) Sweep or shovel up. Reuse material. 7. HANDLING and STORAGE --- PRECAUTIONS --- Keep away from excessive heat and open flame. Avoid breathing gas/vapor from heated material. --- HANDLING --- Avoid eye contact. Avoid skin contact. Avoid inhalation. --- STORAGE --- Avoid sunlight. Store in a cool dry place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Chemical name ACGIH (TLV-TWA) OSHA (PEL-TWA) Styrene-Butadiene polymer Not established Not established Rosin Not established Not established --- VENTILATION PROTECTION --- If heated, there should be enough fresh air flowing past the user to prevent vapor exposure. --- RESPIRATION PROTECTION --- Under normal conditions of use, respiratory protection should not be required. --- SKIN PROTECTION --- Employees who have prolonged contact with this material should practice good personal hygiene by frequent washing of hands and arms with soap and water. --- EYE PROTECTION --- Safety glasses. --- PROTECTIVE GLOVES --- Recommended to prevent contact OTHER PROTECTION --- Use good personal hygiene. 9. PHYSICAL and CHEMICAL PROPERTIES APPEARANCE: Solid ODOR: Odorless ph Not determined. FLASH POINT and METHOD Not determined. FLAMMABLE LIMITS LEL Not established for product UEL Not established for product THERMAL DECOMPOSITION Not determined. AUTO-IGNITION TEMP Not determined. INITIAL BOILING POINT Not determined. Page 3 of 6

4 G3811A - SLF16S42, SOLFLEX 16S42 9. PHYSICAL and CHEMICAL PROPERTIES MELT POINT Not determined. SPECIFIC GRAVITY 0.93 % VOLATILE BY VOLUME Maximum % VOLATILE BY VOLUME 0.75 SOLUBILITY IN WATER Insoluble 10. STABILITY and REACTIVITY --- CONDITIONS TO AVOID --- Material is stable. --- MATERIALS TO AVOID --- None known, none expected. --- HAZARDOUS DECOMPOSITION PRODUCTS --- Carbon monoxide and carbon dioxide.. Formaldehyde. Amines. Styrene. 11. TOXICOLOGY INFORMATION ORAL LD50 DERMAL LD50 INHALATION LC50 Not established for product Not established for product Not established for product 12. ECOLOGICAL INFORMATION Rosin Freshwater Algae Data EC50 = 400 mg/l Desmodesmus subspicatus 72 h Microtox Data EC50 = 31.5 mg/l Photobacterium phosphoreum 30 min Water Flea Data EC mg/l Daphnia magna 48 h --- OTHER --- This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known. 13. DISPOSAL CONSIDERATIONS --- DISPOSAL --- Incinerate, treat or landfill in accordance with applicable environmental control regulations. Recycle if possible. Based upon most recent TCLP data and process knowledge this product, as sold, would not be hazardous waste (if disposed) per 40CFR TRANSPORTATION INFORMATION United States Page 4 of 6

5 G3811A - SLF16S42, SOLFLEX 16S TRANSPORTATION INFORMATION --- BASIC DESCRIPTION --- Not Applicable --- FREIGHT DESCRIPTION --- Rubber Compounds, Unvulcanized. NMFC REPORTABLE QUANTITY --- Not Applicable STCC Number: AA 15. REGULATORY INFORMATION USA/Canada This product does not contain a SARA S-313 Toxic Chemical above the de minimis thresholds. This material is not considered hazardous under the OSHA Hazard Communication Standard CFR Title 29, Part or the WHMIS Canadian legislation. Canada --- WHMIS CLASSIFICATION --- None USA --- OTHER LOCAL, STATE & FEDERAL --- None --- INTERNATIONAL --- TSCA CANADIAN (DSL) EINECS AICS ENCS KECL PICCS CHINA New Zealand One or more ingedients are not on the Japanese Inventory 16. OTHER INFORMATION / ADDITIONAL COMMENTS Page 5 of 6

6 G3811A - SLF16S42, SOLFLEX 16S OTHER INFORMATION / ADDITIONAL COMMENTS The SDS has been updated to meet the requirements stipulated in commission regulation (EU) 453/2010. Goodyear believes that the information herein is correct at the date that this Material Safety Data Sheet w as prepared. The data may not be exhaustive and should only be used as a guide to determine the best conditions for the safe use of the product. Goodyear is not responsible for any injury or liability resulting from misuse of this product. --- END of DOCUMENT --- S Page 6 of 6