Safety Data Sheet MSDS No.: B11214 Date Prepared:

Transcription

1 Safety Data Sheet Date Prepared: Section 1: PRODUCT AND COMPANY IDENTIFICATION Product Name: Product Number: Supplier: Applied Spectrometry Associates, Inc 2325 Parklawn Drive, Suite I Waukesha, WI Telephone: 262/ Emergency Contact (CHEMTREC): [CHEMTREC Code: APSP] Section 2. HAZARDS IDENTIFICATION Emergency Overview: OSHA Hazards CORROSIVE GHS Classification Skin corrosion (Category 1A) Serious eye damage (Category 1) Acute aquatic toxicity (Category 3) GHS Label Elements: Pictogram Signal word Hazard statement(s) H314 H402 Danger Causes severe skin burns and eye damage. Harmful to aquatic life. Precautionary statement(s) P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. HMIS Health: 3 Flammability: 0 Reactivity: 1

2 Page 2 Section 2. HAZARDS IDENTIFICATION (Count.) NFPA Health: 3 Flammability: 0 Reactivity: 0 Symbol: Not applicable Potential Health Effects: Eye Contact: Causes serious eye damage. Skin Contact: Causes skin burns. Skin Absorption: May be harmful if absorbed through the skin. Ingestion: May be harmful if swallowed. Inhalation: May be harmful if inhaled. Extremely destructive to mucous membranes. Target Organs: Mucous membranes; upper respiratory tract Chronic Effects: Chronic exposure may cause destruction of any tissue contacted Other: May aggravate pre-existing eye conditions, respiratory conditions, or skin conditions Section 3. COMPOSITION/INFORMATION ON INGREDIENTS Sodium Hydroxide CAS No.: TSCA No.: Percent Range: Range Units: weight/volume TLV: 2 mg/m 3 PEL: 2 mg/m 3 Deionized Water CAS No.: TSCA 8(b) Inventory: Water Percent Range: Range Units: weight/volume TLV: Not established PEL: Not established Section 4: FIRST AID General Advice: Move out of the dangerous area. Consult a physician and show this Safety Data Sheet to the doctor in attendance. Eye Contact: Immediately flush eyes with water for 15 min. Seek medical aid. Continue rinsing eyes during transport to hospital. Skin Contact (First Aid): Wash skin with soap and plenty of water. Remove contaminated clothing. Seek medical aid if irritation develops and persists. Ingestion (First Aid): Do NOT induce vomiting. Rinse mouth with water. (Never give anything by mouth to an unconscious person!) Seek medical aid. Inhalation: Remove to fresh air.

3 Page 3 Section 5: FIRE FIGHTING MEASURES Flammability: Material will not burn. Flash Point: Not applicable Extinguishing Media: Water; Water fog; Foam; Dry chemical powder; Carbon dioxide. Use media appropriate to surrounding fire conditions. Fire Fighting Procedures: As with any fire, wear self-contained breathing apparatus and full protective gear. Hazardous Combustion Products:. Sodium oxides may be formed under fire conditions. Section 6: ACCIDENTAL RELEASE MEASURES Containment: Absorb on sand or vermiculite and place in closed containers for disposal. Do not allow to enter drains. Clean-up: Decontaminate the spill site using a weak acid solution. Special Instructions: Material contains a component that is regulated as hazardous waste. Section 7: HANDLING AND STORAGE Precautionary Measures: Avoid contact with eyes, skin, or clothing. Do not breathe mist or vapor. Wash thoroughly after using. Keep away from acids, acid vapors, and heat. Storage Conditions: Keep container tightly closed in a dry and well-ventilated location. Containers which have been opened must be reclosed tightly and kept upright to prevent leakage. Section 8: EXPOSURE CONTROL/PERSONAL PROTECTION General Controls: Have an eyewash station nearby. Have a safety shower nearby. Maintain good industrial hygiene practices when using this product. Personal Protective Equipment Eye Protection: Safety glasses with top and side shields Skin Protection: Disposable latex or nitrile gloves and lab coat Inhalation Protection: Adequate ventilation Section 9: PHYSICAL/CHEMICAL CHARACTERISTICS Appearance: Clear, colorless liquid Odor: None Specific Gravity (water = 1): ~1.16 Boiling Point: ~100 C (~212 F) Vapor Pressure: < 18 mm 20 C Evaporation Rate (water = 1): Not determined Solubility: Miscible with water ph: > 13

4 Page 4 Section 10: STABILITY and REACTIVITY DATA Stability: Material is stable when stored properly. Conditions to avoid: Extreme temperatures, oxidizing agents. Reactivity/Incompatibility: Reacts with acids, organic materials, metals (aluminum, tin, zinc), phosphorus, and oxidizing agents. Hazardous Decomposition Products: Sodium oxides. Section 11: TOXICOLOGICAL INFORMATION Acute toxicity Oral LD50 (rat) = 500 mg/kg Inhalation LC50 Dermal LD50 Other information on acute toxicity Skin corrosion/irritation Causes skin burns Serious eye damage/eye irritation: Eyes Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure (Globally Harmonized System) Specific target organ toxicity - repeated exposure (Globally Harmonized System) Aspiration hazard (Globally Harmonized System)

5 Page 5 Section 11: TOXICOLOGICAL INFORMATION (Count.) Potential Health Effects: Eye Contact: Causes serious eye damage. Skin Contact: Causes skin burns. Skin Absorption: May be harmful if absorbed through the skin. Ingestion: May be harmful if swallowed. Inhalation: May be harmful if inhaled. Extremely destructive to mucous membranes. Target Organs: Mucous membranes; upper respiratory tract Chronic Effects: Chronic exposure may cause destruction of any tissue contacted. Other: May aggravate pre-existing eye conditions, respiratory conditions, or skin conditions Signs and Symptoms of Exposure: Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. (Sodium hydroxide) Synergistic effects Additional information RTECS: Not available Section 12: ECOLOGICAL INFORMATION Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil PBT and vpvb assessment Other adverse effects Harmful to aquatic life Section 13: DISPOSAL CONSIDERATIONS Waste must be disposed of in accordance with all federal, state, and local environmental regulations. Contact a licensed professional waste disposal service to dispose of this material. Section 10: TRANSPORT INFORMATION D.O.T. Shipping Name: Sodium Hydroxide Solution D.O.T Hazard Class: 8 U.N./N.A. Number: UN1824 Packing Group: II D.O.T. Label: 8 DOT Emergency Response Guide Number: 154

6 Page 6 Section 15: REGULATORY INFORMATION OSHA Hazards: Corrosive SARA 302 Components: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 Components: This material does not contain any chemical conponents with known CAS numbers that exceed the threshold (De Minimus) reporting levels established by SARA Title III, Section 313. SARA 311/312 Hazards: Acute health hazard. Section 16: OTHER INFORMATION Abbreviations used in Section 12: ECOLOGICAL INFORMATION: NOEC No Observable Effect Concentration PBT Persistent, Bioaccumulative and Toxic [per European Union REACH Regulation: Registration, Evaluation, Authorization and Restriction of Chemicals] vpvb Very Persistent and Very Bioaccumulative [per European Union REACH Regulation: Registration, Evaluation, Authorization and Restriction of Chemicals] Revisions: 01/29/15 Corrections to Section 11 Signs and Symptoms of Exposure THE INFORMATION CONTAINED IN THIS DOCUMENT IS BASED ON DATA CONSIDERED TO BE ACCURATE. HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THEIR USE.