: SEIREPOX R CONDUCTIVO Comp A

Transcription

1 SEIREPOX R CONDUCTIVO Comp A Date of issue: 12/28/2017 Revision date: 9/10/2018 Supersedes: 12/28/2017 Version: 2.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Name : Product code : A Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture : Professional use : Coating Uses advised against 1.3. Details of the supplier of the safety data sheet SEIRE PRODUCTS, S.L. Los Muchos Polígono Ind. Albolleque Sector III E CHILOECHES, GUADALAJARA address of competent person responsible for the SDS : oscar.velasco@seire.net 1.4. Emergency telephone number Emergency number : (8:00-17:30) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin corrosion/irritation, Category 2 Serious eye damage/eye irritation, Category 2 Skin sensitisation, Category 1 Hazardous to the aquatic environment Chronic Hazard, Category 2 Full text of H statements : see section 16 H315 H319 H317 H411 Adverse physicochemical, human health and environmental effects Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Toxic to aquatic life with long lasting effects Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) GHS07 : Warning Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove 9/21/2018 GB - en 1/9 GHS09 : reaction product: molecular weight 700); formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol; oxirane, mono[(c12-14-alkyloxy)methyl] derivs.; TERPENE HYDROCARBONS : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H411 - Toxic to aquatic life with long lasting effects.

2 EUH-statements contact lenses, if present and easy to do. Continue rinsing. P501 - Dispose of contents and container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : EUH205 - Contains epoxy constituents. May produce an allergic reaction Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] reaction product: resin (number average molecular weight 700) formaldehyde, oligomeric reaction products with 1-chloro-2,3- epoxypropane and phenol (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) (CAS-No.) (EC-No.) (REACH-no) benzyl alcohol (CAS-No.) (EC-No.) (EC Index-No.) oxirane, mono[(c12-14-alkyloxy)methyl] derivs. (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) TERPENE HYDROCARBONS (CAS-No.) (EC-No.) methyl-2-pyrrolidone substance listed as REACH Candidate (CAS-No.) (EC-No.) (EC Index-No.) Eye Irrit. 2, H319 Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 2, H Skin Irrit. 2, H315 Skin Sens. 1, H317 Aquatic Chronic 2, H Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Acute Tox. 3 (Inhalation:vapour), H Skin Irrit. 2, H315 Skin Sens. 1, H Flam. Liq. 3, H226 Skin Irrit. 2, H315 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H Repr. 1B, H360D Eye Irrit. 2, H319 STOT SE 3, H335 Skin Irrit. 2, H315 Specific concentration limits: Name Product identifier Specific concentration limits reaction product: resin (number average molecular weight 700) (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) methyl-2-pyrrolidone (CAS-No.) (EC-No.) (EC Index-No.) Full text of H-statements: see section 16 (C >= 5) Eye Irrit. 2, H319 (C >= 5) Skin Irrit. 2, H315 (C >= 10) STOT SE 3, H335 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 9/21/2018 GB - en 2/9

3 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Toxic fumes may be released Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. : Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. EU Local name n-methyl-2-pyrrolidone EU IOELV TWA (mg/m³) 40 mg/m³ (n-methyl-2-pyrrolidone; EU; Time-weighted average exposure limit 8 h; Indicative occupational exposure limit value) EU IOELV TWA (ppm) 10 ppm (n-methyl-2-pyrrolidone; EU; Time-weighted average exposure limit 8 h; Indicative occupational exposure limit value) EU IOELV STEL (mg/m³) 80 mg/m³ (n-methyl-2-pyrrolidone; EU; Short time value; Indicative occupational exposure limit value) EU IOELV STEL (ppm) 20 ppm (n-methyl-2-pyrrolidone; EU; Short time value; Indicative occupational exposure limit value) EU Notes skin United Kingdom Local name n-methyl-2-pyrrolidone United Kingdom WEL TWA (mg/m³) 40 mg/m³ United Kingdom WEL TWA (ppm) 10 ppm United Kingdom WEL STEL (mg/m³) 80 mg/m³ United Kingdom WEL STEL (ppm) 20 ppm United Kingdom Remark (WEL) Sk (Can be absorbed through the skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity) 9/21/2018 GB - en 3/9

4 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves. Type: Disposable gloves Material: Nitrile rubber Permeation: 6 (> 480 minutes) Thickness: > 0.4 mm Standard: EN 374 Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Various. Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Not applicable Freezing point Boiling point Flash point : 97 C ASTM D93 Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Not applicable Vapour pressure Relative vapour density at 20 C Relative density Density : g/cm³ Solubility Log Pow Viscosity, kinematic Viscosity, dynamic : cp Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport. 9/21/2018 GB - en 4/9

5 10.2. Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity reaction product: molecular weight 700) ( ) ku/kg formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol ( ) > 5000 mg/kg LD50 dermal rat > 2000 mg/kg LD50 dermal > mg/kg LC50 inhalation rat (mg/l) > mg/kg mg/kg bodyweight (Other, Rat, Male, Expert judgement) LD50 dermal rabbit > 4000 mg/kg LD50 dermal rabbit LC50 inhalation rat (mg/l) 1620 mg/kg bw/day (Rat, Male, Experimental value) > 2000 mg/kg (Rabbit, Inconclusive, insufficient data) 8.8 mg/l/4h LD50 dermal rabbit LC50 inhalation rat (mg/l) > LC50 inhalation rat (ppm) > 5100 ppm/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity 3914 mg/kg (Rat; Equivalent or similar to OECD 401; Literature study; 4150 mg/kg bodyweight; Rat; Experimental value) 8000 mg/kg : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general : Toxic to aquatic life with long lasting effects. formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol ( ) LC50 fish mg/l EC50 Daphnia mg/l ErC50 (algae) 1.8 mg/l NOEC chronic crustacea 0.3 mg/l LC50 fish 1 > 5000 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value) 9/21/2018 GB - en 5/9

6 LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae 1 Threshold limit algae mg/l (EPA OPP 72-1, 96 h, Pimephales promelas, Static system, Fresh water, Experimental value) 230 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Fresh water, Experimental value) 770 mg/l (OECD 201: Alga, Growth Inhibition Test, 72 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value) 3048 mg/l (LC50; 96 h; Salmo gairdneri) 4897 mg/l (EC50; 48 h; Daphnia magna) > 500 mg/l (EC50) mg/l (EC50; DIN ; 72 h; Desmodesmus subspicatus; Static system; Fresh water; Experimental value) Persistence and degradability Persistence and degradability Readily biodegradable in water. Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Biodegradable in the soil. Readily biodegradable in water. 1.6 g O₂/g substance 2.4 g O₂/g substance 2.5 g O₂/g substance Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Bioaccumulative potential Readily biodegradable in water. Inherently biodegradable. Biodegradable in the soil. Highly mobile in soil. Photodegradation in the air g O₂/g substance 1.56 g O₂/g substance 1.9 g O₂/g substance formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol ( ) Log Pow BCF other aquatic organisms (BCFWIN, QSAR) Log Pow 3.77 (Experimental value, OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method, 20 C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Log Pow (Experimental value, Other, 20 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Log Pow Bioaccumulative potential Mobility in soil (Experimental value; Experimental value; OECD 107: Partition Coefficient (noctanol/water): Shake Flask Method) Not bioaccumulative. Log Koc > 5.63 (log Koc, OECD 121: Estimation of the Adsorption Coefficient (Koc) on Soil and on Sewage Sludge using High Performance Liquid Chromatography (HPLC), Experimental value, GLP) Ecology - soil Low potential for mobility in soil. Surface tension Ecology - soil Surface tension Log Koc Results of PBT and vpvb assessment Component oxirane, mono[(c12-14-alkyloxy)methyl] derivs. ( ) 39 mn/m (20 C) No (test)data on mobility of the substance available N/m Koc,20.94; Calculated value; log Koc; 1.32; Calculated value This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII 9/21/2018 GB - en 6/9

7 Component This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. ADR IMDG IATA ADN RID UN number UN proper shipping name ENVIRONMENTALLY ENVIRONMENTALLY SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, N.O.S. (reaction product: N.O.S. (reaction product: molecular weight 700)) molecular weight 700)) Transport document description UN 3082 UN 3082 ENVIRONMENTALLY ENVIRONMENTALLY SUBSTANCE, LIQUID, SUBSTANCE, LIQUID, N.O.S. (reaction product: N.O.S. (reaction product: molecular weight 700)), molecular weight 700)), 9, III, (-) 9, III, MARINE POLLUTANT Environmentally hazardous substance, liquid, n.o.s. (reaction product: molecular weight 700)) UN 3082 Environmentally hazardous substance, liquid, n.o.s. (reaction product: molecular weight 700)), 9, III ENVIRONMENTALLY SUBSTANCE, LIQUID, N.O.S. (reaction product: molecular weight 700)) UN 3082 ENVIRONMENTALLY SUBSTANCE, LIQUID, N.O.S. (reaction product: molecular weight 700)), 9, III ENVIRONMENTALLY SUBSTANCE, LIQUID, N.O.S. (reaction product: molecular weight 700)) UN 3082 ENVIRONMENTALLY SUBSTANCE, LIQUID, N.O.S. (reaction product: molecular weight 700)), 9, III Transport hazard class(es) Packing group III III III III III Environmental hazards environment : Yes environment : Yes Marine pollutant : Yes Special precautions for user - Overland transport Classification code (ADR) Limited quantities (ADR) Excepted quantities (ADR) : M6 : 5l : E1 Transport category (ADR) : 3 Orange plates : environment : Yes No supplementary information available environment : Yes environment : Yes Tunnel restriction code (ADR) : - EAC code : 3Z 9/21/2018 GB - en 7/9

8 - Transport by sea Special provisions (IMDG) : 274, 335, 969 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) PCA max net quantity (IATA) - Inland waterway transport Classification code (ADN) Limited quantities (ADN) Excepted quantities (ADN) : E1 : Y964 : 30kgG : 450L : M6 : 5 L : E1 - Rail transport Classification code (RID) Excepted quantities (RID) : M6 : E1 Transport category (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains a substance on the REACH candidate list in concentration 0.1% or with a lower specific limit: 1-Methyl-2-pyrrolidone (EC , CAS ) Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 3 (Inhalation:vapour) Acute toxicity (inhalation:vapour) Category 3 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Asp. Tox. 1 Aspiration hazard, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Repr. 1B Reproductive toxicity, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Skin sensitisation, Category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H360D May damage the unborn child. 9/21/2018 GB - en 8/9

9 H411 EUH205 Toxic to aquatic life with long lasting effects. Contains epoxy constituents. May produce an allergic reaction. ARDEX SDS EU This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 9/21/2018 GB - en 9/9