Date: 5 December 2017 Former date: 19 November 2014

Transcription

1 X SAFETY DATA SHEET (INFORMATION FORM FOR CHEMICALS DATA) Date: 5 December SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product identifier Trade name BASE OIL Company product code Reach registration number According to REACH regulation (1907/2006) article 2(7)(d) exempted from registration obligations. 1.2 Relevant identified uses of the substance or mixture and uses advised against The uses of the chemical Manufacturing of lubricating oil products. Classification of economic activities (NACE) Use categories (UC62) The chemical can be used by the general public The chemical is used by the general public only 1.3 Details of the supplier of the safety data sheet Manufacturer, importer, other undertaking Fortum Waste Solutions Oy Street address Kuulojankatu 1 Postcode and post office Post-office box PL 181 Postcode and post office Riihimäki Riihimäki Telephone number address Finnish Business ID (Y code) myyntijkoski@fortum.com 1.4 Emergency telephone number 112 Poison Information Centre (in Finland), open 24 h daily or SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture Not classified as dangerous according to current legislation (CLP regulation EC No 1272/2008). 2.2 Label elements None: Not classified as dangerous according to current legislation. 2.3 Other hazards The product may irritate unprotected skin. Page 1

2 SECTION 3:COMPOSITION/INFORMATION ON INGREDIENTS Hazardous ingredients CAS/EC number and the registration number Name of the ingredient Concentration Classification CAS EC REACH: Lubricating oils; Baseoil unspecified (DMSO < 3 %) % - The product is a mixture of used, recovered lubricating oils. SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures Inhalation: If respiratory symptoms develop, move victim away from source of exposure and into fresh air. Keep warm and at rest. Skin contact: Remove contaminated clothing. Cleanse affected area(s) by washing with mild soap and plenty of water. Eye contact: Immediately rinse with water continuously for several minutes occasionally lifting upper and lower lids. Ingestion: DO NOT INDUCE VOMITING. Rinse the mouth with water. Seek medical attention. If the symptoms persist, seek medical attention. 4.2 Most important symptoms and effects, both acute and delayed May irritate skin and eyes. Prolonged and/or repeated skin contact may cause drying and cracking or dermatitis. Inhalation of oil mist may irritate respiratory tract. Ingestion may cause nausea and diarrhea. 4.3 Indication of any immediate medical attention and special treatment needed No special treatment needed. SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media Foam, dry chemical, CO2, water spray DO NOT use direct water jet or high pressure jet for fire extinction. 5.2 Special hazards arising from the substance or mixture Exposure to decomposed or damaged product can be hazardous to health. 5.3 Advice for firefighters Use appropriate protective equipment and a self-contained breathing apparatus. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Prevent unauthorized entering. Use personal protection (see section 8). Stop leak if without risk. Keep away from sparks/open flames/hot surfaces. Ensure adequate ventilation. 6.2 Environmental precautions Prevent entry into sewers, soil and waterways. Contain the leak with non-combustible materials such as sand or earth. If the product pollutes lakes, watercourses or drainage systems, inform the local authorities. 6.3 Methods and material for containment and cleaning up Absorb with non-combustible materials such as sand, earth or vermiculite and collect in suitable labeled containers to be disposed of in accordance with local regulations. High risk of slipping due to leakage / spillage of product. Clean and ventilate the area. 6.4 Reference to other sections Page 2

3 Personal protection: section 8. Waste treatment methods: section 13 SECTION 7: HANDLING AND STORAGE 7.1 Precautions for safe handling Avoid repeated skin contact and inhalation of oil mist. Do not eat, drink or smoke while working. Handle in accordance with good industrial hygiene and safety practices. 7.2 Conditions for safe storage, including any incompatibilities To be stored in a dry and well-ventilated place tightly closed. To be kept separate from strong oxidizing agents and away from sparks/open flames/hot surfaces. Keep only in the original container or in a suitable container for this kind of product. 7.3 Specific end use(s) No special instructions. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters National occupational exposure limit values Oil mist 5 mg/m 3 (8 h) Other limit values - DNEL Not available. PNEC Hazard for predators PNEC oral : 9.33 mg/kg food 8.2 Exposure controls Appropriate engineering controls Ensure adequate ventilation. Eye/face protection Goggles with side shields. Skin protection Avoid prolonged / repeated skin contact. Hand protection Use protective plastic gloves. Respiratory protection Normally not needed. In cases where formation of oil mist is possible, use appropriate respiratory protection (filter A2/P2). Thermal hazards High temperatures can generate hazardous decomposition products. Environmental exposure controls Prevent entry into soils, sewers and waterways. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Page 3

4 Appearance Brownish yellow liquid Odour Mild oil like Odour threshold ph Melting point/freezing point Initial boiling point and boiling range > 300 C Flash point > 115 C Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density 0,88 Solubility(ies) Insoluble in water Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity 32, 46, 68 cst (40 C) Explosive properties Not explosive Oxidising properties Not oxidizing 9.2 Other information Pour point ca. 30 C SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Not reactive under normal use and storage conditions Chemical stability Chemically stable under normal storage conditions Possibility of hazardous reactions No hazardous reactions under normal use and storage conditions Conditions to avoid Keep away from ignition sources Incompatible materials Strong oxidizing agents Hazardous decomposition products Fire or high temperatures can generate hazardous decomposition products. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Page 4

5 Acute toxicity The product is not classified as toxic nor harmful. Lubricating oils LD50 (oral, rat) > 5000 mg/kg LC50 (inhalation, rat, 4 h): 2.18 mg/l LD50 (dermal, rabbit) > 5000 mg/kg Skin corrosion/irritation The product is not classified as corrosive or irritant. Serious eye damage/irritation The product is not classified as corrosive or irritant for eyes. Respiratory or skin sensitisation The product is not classified as sensitizer. Germ cell mutagenicity The product does not cause genetic defects. Carcinogenicity The product does not cause cancer. DMSO extractible compounds according to IP 346 <3% Reproductive toxicity The product is not classified as a reproductive toxicant. STOT-single exposure The product is not classified as toxic to specific target organs. STOT-repeated exposure The product is not classified as toxic to specific target organs. Aspiration hazard The product does not cause aspiration hazard. Other information May irritate skin and eyes. Prolonged and/or repeated skin contact may cause drying and cracking or dermatitis. Inhalation of oil mist may irritate respiratory tract. SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity The product is not classified as dangerous for the environment Persistence and degradability Not easily biodegradable Bioaccumulative potential Possibly bioaccumulative Mobility in soil The very low vapour pressures of the hydrocarbons found in lubricating oil basestocks means low volatilisation. In water, lubricating oil basestocks will float and will spread at a rate that is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process (CONCAWE) Results of PBT and vpvb assessment The substance is not PBT/vPvB. Page 5

6 12.6 Other adverse effects Not known. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Liquid residue from the product and the contaminated packaging are to be disposed of as hazardous waste. Waste class: * mineral-based non-chlorinated engine, gear and lubricating oils SECTION 14: TRANSPORT INFORMATION 14.1 UN number The product is not classified as hazardous goods for land, sea and air transport according to the respective regulations (ADR, IMDG, IATA-DGR) UN proper shipping name None Transport hazard class(es) None Packing group None Environmental hazards Not classified as hazardous for the environment Special precautions for user No special precautions Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code. SECTION 15: REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No specific regulations Chemical safety assessment Chemical safety assessment has been performed as part of REACH registration. SECTION 16: OTHER INFORMATION Changes to previous version December 5, 2017: Content checked. Name of the manufacturer changed (former Ekokem Oyj) November 19, 2014: Exposure limit values checked, REACH-registration number added, more specific instructions given in sections handling and storage; accidental release measures. Disclaimer of liability added. November 17, 2010: Content checked and moved to new SDS template. References Product analysis results from manufacturer (Ekokem Oyj) TOXNET database Degree on Concentrations known to be Hazardous (1214/2016) (HTP-arvot 2016) CONCAWE: Lubricating oil basestocks, product dossier no. 97/108, 1997 ECHA registered substances database List of relevant H-statements No H-statements have been given to this specific product Disclaimer of liability The information contained herein is accurate according to our knowledge and according to relevant EU and local regulations as of the date of this material safety data sheet. The information herein is given as Page 6

7 a guidance on safe use, handling, storage, transport and disposal of the chemical and should not be regarded as a product guarantee or warranty of any kind. Page 7