SECTION 1: Identification of the substance/mixture and of the company/undertaking. SECTION 2: Hazards identification

Transcription

1 Date of issue: 4/20/2018 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : art.nr Type of product : Paste 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Industrial use,professional use Uses advised against 1.3. Details of the supplier of the safety data sheet Service Best BV De Run LM Veldhoven -the Netherlands T +31 (0) F +31 (0) info@servicebest.com 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazardous to the aquatic environment Chronic Hazard, Category 3 Full text of H statements : see section 16 H412 Adverse physicochemical, human health and environmental effects Harmful to aquatic life with long lasting effects Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) : - : H412 - Harmful to aquatic life with long lasting effects. : P273 - Avoid release to the environment. P501 - Dispose of contents and container to Collection point Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Copper (CAS-No.) Acute Tox. 4 (Oral), H302 (EC-No.) Aquatic Acute 1, H400 (REACH-no) Aquatic Chronic 2, H411 zinc oxide (CAS-No.) Aquatic Acute 1, H400 (EC-No.) Aquatic Chronic 1, H410 (EC Index-No.) Full text of H-statements: see section 16 4/20/2018 EN (English) 1/6

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity in case of fire Hazardous decomposition products in case of fire 5.3. Advice for firefighters Protection during firefighting SECTION 6: Accidental release measures : Not flammable. : No direct explosion hazard. : Product is not explosive. : Toxic fumes may be released Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. : Ventilate spillage area For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. Copper ( ) EU Local name Copper EU IOELV TWA (mg/m³) 0.01 mg/m³ (respirable fraction) EU Notes (Year of adoption 2014) 4/20/2018 EN (English) 2/6

3 Copper ( ) EU Regulatory reference SCOEL Recommendations Netherlands Local name Koper Netherlands Grenswaarde TGG 8H (mg/m³) 0.1 mg/m³ en anorganische koperverbindingen (inhaleerbaar) Netherlands Regulatory reference Arbeidsomstandighedenregeling 2017 Copper ( ) DNEL/DMEL (Workers) Acute - systemic effects, dermal Acute - systemic effects, inhalation Long-term - systemic effects, dermal DNEL/DMEL (General population) Acute - systemic effects, dermal Acute - systemic effects, inhalation Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: 273 mg/kg bodyweight/day 20 mg/m³ 137 mg/kg bodyweight/day 273 mg/kg bodyweight In case of insufficient ventilation, wear suitable respiratory equipment Environmental exposure controls: Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties : Liquid : Paste. : dark grey. : characteristic. : : : g/cm³ (estimated value) 4/20/2018 EN (English) 3/6

4 Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects. : Harmful to aquatic life with long lasting effects Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects 4/20/2018 EN (English) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose of contents/container in accordance with licensed collector s sorting instructions. ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport No supplementary information available Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information 4/20/2018 EN (English) 5/6

6 Abbreviations and acronyms: ADN ADR ATE European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road Acute Toxicity Estimate BCF Bioconcentration factor CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DMEL DNEL DPD DSD EC50 IARC IATA IMDG LC50 LD50 LOAEL NOAEC NOAEL NOEC OECD PBT Derived Minimal Effect level Derived-No Effect Level Dangerous Preparations Directive 1999/45/EC Dangerous Substances Directive 67/548/EEC Median effective concentration International Agency for Research on Cancer International Air Transport Association International Maritime Dangerous Goods Median lethal concentration Median lethal dose Lowest Observed Adverse Effect Level No-Observed Adverse Effect Concentration No-Observed Adverse Effect Level No-Observed Effect Concentration Organisation for Economic Co-operation and Development Persistent Bioaccumulative Toxic PNEC Predicted No-Effect Concentration REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006 RID SDS STP TLM vpvb Data sources Regulations concerning the International Carriage of Dangerous Goods by Rail Sewage treatment plant Median Tolerance Limit Full text of H- and EUH-statements: Very Persistent and Very Bioaccumulative Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 : Classification according to Classification, Labelling and Packaging of Substances and Mixtures (SEA) Regulation published in the Official Journal numbered on December 11, Manufacturer/Supplier. REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 H302 Harmful if swallowed. H400 H410 H411 H412 Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 4/20/2018 EN (English) 6/6