Version: 3.0. Kremer Pigmente GmbH & Co. KG. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 3.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Zinc Sulphide Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Production of paints, printing colors and putties Additive, fillers, colorants, pigments Uses advised against: Details of the Supplier of the (Producer/Importer) Not for cosmetics, foods additives, medicine, feed additives, permanent implants Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: 2

2 2. 3. Other Hazards 3. Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Information on Components / Hazardous Ingredients: Zinc sulphide, ZnS; REACH Reg. No Zinc sulphide, ZnS % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: No special measures required. Supply fresh air. Consult physician if symptoms persist. Remove contaminated clothing and shoes immediately. Wash with soap and rinse with plenty of water. Rinse eyes with water. Remove contact lens. Protect unharmed eye. Seek medical attention if irritation persists After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Do not give milk or alcoholic beverages to drink. Never give anything by mouth to an unconscious person. Symptoms: None known Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Treat symptomatically. Suitable extinguishing media: Use extinguishing media for surrounding fire. 3

3 Unsuitable extinguishing media: Water with full jet Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of sulfur oxides. Wear self-contained respiratory protective device. Usual measures for chemical fires Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Avoid formation of dust Environmental precautions: Methods and Material for Containment and Cleaning Up No special measures required Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Wear adequate protective clothing (see para. 8) Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry and well ventilated location. Electrical installation/working materials must comply with the technological safety standards. Information on fire and explosion protection: Avoid dust formation. 4

4 Storage class (VCI): 13; Non combustible solids Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Personal Protection General protective measures: Respiratory protection: Hand protection: Do not eat, drink or smoke during work. None required under normal operating conditions. Protective gloves recommended in case of prolonged or repeated contact. Protective glove material: Eye protection: Body protection: Safety glasses (EN 166) Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: powder white odorless ph-value: ca. 7 5

5 Melting temperature: > 800 C (subl.) Page 5 Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: not flammable no information available no information available 4 g/cm3 (20 C) < 0,0005 g/l (20 C) Product is not auto-ignitable. No data available. not oxidizing Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: 6

6 Particle size: Page Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity Stable if used according to specifications. Stable if used according to specifications. Dust can form explosive mixtures with air. Acids Sulphur oxides (SOx). Hydrogen sulfide gas. LD50, oral: > mg/kg (rat; OECD 401) LD50, dermal: LC50, inhalation: 5.7 mg/l (4h, rat; OECD 403) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Non irritating Non-irritating to eyes No information available No sensitizing effects known. No mutagenic effects known. Reproductive toxicity: 7

7 No relevant data found. Page 7 Carcinogenicity: No cancerogenic effect known. Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: Single exposure: no information available. Repeated exposure: Swallowing, target organs: brain, thyroid gland, thymus, eyes, pituitary gland, kidneys, liver, spleen, adrenal glands, testicles, female reproductive organs, muscle. Evaluation: no significant effects at a concentration of 300 mg/kg bw/day. Aspiration hazard: Zinc sulphide: EC50: 100 mg/l ((96h, Danio rerio; OECD 203) EC50: 100 mg/l (48h, Daphnia magna; OECD 202) No data available. EC50: 100 mg/l (72h, Scenedesmus subspicatus; OECD 202) Zinc sulphide: does not contain any substances which are enviromentally hazardous substances nor any which are not biodegradable. On the basis of available data, the product does not contain and PBT or vpvb in percentage greater than 0.1 %. Not hazardous. AOX Value: 13. Disposal Considerations Waste Treatment Methods 8

8 Page 8 Product: Product residues and non recyclable solutions have to discarded by a recognized disposal company. European Waste Code (EWC): Uncleaned packaging: Empty containers should be taken to an approved waste handling site for recycling or disposal. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code 9

9 Further Information 15. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Page 9 Water hazard class: 0, not hazardous (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has been carried out for this product. EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern (REACH Regulation (EC) 1907/2006, Article 57) Listed in the following inventories: EINECS (EU), TSCA (US), AICS (AUS), DSL (CA), ENCS (JP), PICCS (PH), KECI (KR), IECSC (CN), NZIoC (NZ), TCSI (TW) This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.