Revision Number: Issue date: 06/13/ PRODUCT AND COMPANY IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 06/13/ PRODUCT AND COMPANY IDENTIFICATION Product type: Surface pretreatment Restriction of Use: identified Region: United States Company address: Contact information: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Telephone: +1 (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Wash affected area thoroughly after handling. Wear protective gloves, eye protection, and face protection. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Not prescribed Not prescribed Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Zinc orthophosphate Carboxymethyl cellulose, sodium salt Page 1 of 5

2 * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: If inhaled, immediately remove the affected person to fresh air. If symptoms develop and persist, get medical attention. Immediately wash skin thoroughly with soap and water. If symptoms develop and persist, get medical attention. Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Ingestion: Get immediate medical attention. Do not induce vomiting. Symptoms: See Section 11. Notes to physician: Treat symptomatically and supportively. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Use media appropriate for surrounding material. Wear full protective clothing. Wear self-contained breathing apparatus. This product is an aqueous mixture which will not burn. Irritating and toxic gases or fumes may be released during a fire. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear appropriate protective equipment and clothing during clean-up. Do not allow product to enter sewer or waterways. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Prevent contact with eyes, skin and clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do not take internally. For industrial use only. For safe storage, store between 4.4 C (39.9 F) and 37.8 C (100 F) Keep the container tightly closed and in a cool, well-ventilated place. Protect from freezing. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Zinc orthophosphate Carboxymethyl cellulose, sodium salt Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists generated from the handling of this product. If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. Wear chemical goggles; face shield (if splashing is possible). Chemical resistant, impermeable gloves. Use of impervious apron and boots are recommended. Suitable glove materials may include: Butyl rubber gloves. Nitrile gloves. Neoprene gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: White Odor: Mild Odor threshold: ph: Vapor pressure: Boiling point/range: > 93.3 C (> F)calculated Melting point/ range: Specific gravity: at C (60.01 F) Vapor density: Flash point: > 93.4 C (> F) calculated; Aqueous solution Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Not applicable Evaporation rate: Solubility in water: Disperses in water as a suspension Partition coefficient (n-octanol/water): VOC content: 0 % EPA Method 24 Viscosity: Decomposition temperature: 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. Will not occur. Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. identified. Do not expose to extreme hot or cold temperatures. Page 3 of 5

4 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Inhalation of vapors or mists of the product may be irritating to the respiratory system. This product is irritating to the skin. Causes serious eye irritation. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Harmful if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Zinc orthophosphate Irritant, Immune system Carboxymethyl cellulose, sodium salt Allergen, Respiratory Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Zinc orthophosphate No No No Carboxymethyl cellulose, sodium salt No No No 12. ECOLOGICAL INFORMATION Ecological information: Do not empty into drains / surface water / ground water. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Hazard class or division: Identification number: Not regulated International Air Transportation (ICAO/IATA) Environmentally hazardous substance, liquid, n.o.s. (Zinc phosphate) Hazard class or division: 9 Identification number: UN 3082 III Water Transportation (IMO/IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Zinc phosphate) Hazard class or division: 9 Identification number: UN 3082 III Marine pollutant: Zinc phosphate Page 4 of 5

5 Additional information: IMDG-Code: Segregation group 7- Heavy metals and their salts Exceptions: Classified per IMDG Amendment 34; Effective Jan 1, United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimis above reporting de minimis. Immediate Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Zinc orthophosphate (CAS# ). This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Regulatory Affairs Issue date: 06/13/2018 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5