Table of Contents. Paint production process Raw material storage details Hazardous waste quantity and proposed details

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1 Table of Contents Annexure No Annexure 1 Annexure 2 Annexure 3A Annexure 3B Annexure 3C Annexure 4 Annexure 5 Annexure 6 Annexure 7A Annexure 7B Annexure 7C Annexure 7D Annexure 8 Annexure 9 Annexure 10A Annexure 10B Annexure 11A Annexure 11B Annexure 12A Annexure 12B Annexure 13 Details Site location map (Google Map) Site layout Land receiving order Land allotment letter Land allotment order Paint production process Raw material storage details Hazardous waste quantity and proposed details Water supply agreement Borewell-1 Agreement Borewell-2 and 3 Agreement Borewell order Stack and process vent details List of hazardous chemicals as per MSIHC rules GEPIL Agreement TSDF Purchase Order ETP process Process of STP Water balance (Existing) Water balance (Proposed) Details of NH waste

2 Annexure 1 Site Location Map (Google Map)

3 Annexure 2 Site Layout

4 Annexure 3A: Land Receiving Order

5 Annexure 3B Land Allotment Letter

6 Annexure 3C Land Allotment Order

7 Annexure 4: Paint Production Process 1. Manufacturing Paint Unlike several other chemical industries, the paint manufacturing process does not involve any chemical reactions and the operations are basically mechanical in nature. The complexity in the industry is at the stage of formulating the recipe of the product and selection of equipment and process to be used. The actual manufacturing process consists of the following four stages: - -dispersion Numerous variations exist in each of these four stages depending upon the particular product and the volume of product. The basic stages involved are further elaborated as follows: Pre-dispersion: Wetting the pigments with sufficient quantity of appropriate binder, breaking large agglomerates to make a mill base which has a required consistency for grinding Dispersion: The raw material is further reduced to smaller particles of uniform size, which are dispersed uniformly in the medium. The type of paint and the final particle size required, determine the equipment to be used and the time required for dispersion. An appropriately sized disperser is used for this purpose. Mixing: Dispersed mill base is then thinned with water, small quantities of driers and additives are added. By this, the paint is thinned down to the required consistency and tinted to the exact shade required. Quality checks are carried out for consistency, viscosity, colour, drying time and other specified properties before batch is approved for packing. Packing: The paint goes through this final stage wherein it is filtered and packed in desired pack sizes. Normal pack sizes vary from 4 lt. to 20 lt. The process flow diagram is shown below:

8 PROCESS FLOW DIAGRAM Silo/Sacktip Batching Tank Charge Hopper Additives - Tankfarm Twin Shaft Dispersor Water Mixer Packing

9 Tankfarm Additives & Liquid RM Tank farm Barrel Storage Silo - farm for Powder Storage Other Powder RM Low Pressure Steam Other Liquid RM Compressed Air Cooling Water Chilled Water Twin Shaft Disperser (TSD) Utility Block MANUFACTURING BLOCK Mixer FINISHED GOODS BSR Packing Line

10 2. Manufacture of Water Based Polymers: Water Based Polymers are polymeric dispersion in aqueous phase. These are polymers manufactured by free radical polymerization of monomers in presence of catalyst, buffers and surfactants. The reactions are exothermic and the reactions take place in a reactor connected to PET from which pre polymer mix is added into reactors at controlled flow rate. During the course of reaction, cooling or heating is provided as per the temperature requirement of thebatch. The reaction is monitored for Stirrer RPM, flow rate of pre emulsion, temperature, wetting and non-volatiles. After digestion the batch is cooled in a let-down vessel where neutralizer and other additives are added. Properties like ph, Viscosity and solids are adjusted in let-down vessel. After required properties are achieved the batch is strained (filtered) through a strainer and pumped into a holding vessel for further usage in paint. The simplified process flow diagram of water based polymers manufacturing is shown below.

11 Annexure 5 Raw Material Storage Details

12 Annexure 6: Hazardous waste quantity and proposed details S.No 1 2 Details of wastes 3.1 Oil-Containing cargo residue, washing water and sludge 3.3 Sludge & Filters contaminated with oil Category Number Quantity Existing Quantity Proposed for Expansion Total Quantity after expansion Unit of Measurement Waste Characteristics Ton Raw material Ton Oil contaminated soil, cleaning cloth, oil filters Disposal methods Collection, Storage & disposal through incineration - captive / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi / Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR Collection, Storage & disposal through incineration - captive / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi / Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR Used/Spent Oil Ton Waste oil Collection, Storage, transport & disposal to authorized/registered recyclers 21.1 Wastes and residues [Dried Dried gelled water based paint, water gelled water based paint, water based polymer & raw material which based polymer & raw material] - cannot be recycled Non-Recyclable Wastes and residues [Dried gelled water based paint, water based polymer & raw material] - Recyclable Ton Chemical containing residue arising from decontamination 33.3 Disposal of barrels/containers used for handling of hazardous wastes/chemicals a. Waste Pigment containers b. Waste raw material containers and liners (Recyclable) b. Waste raw material containers and liners (non - Recyclable) Dried gelled water based paint, water based polymer & raw material which can be recycled Ton Raw material Collection Storage, transportation and disposal to the authorized recyclers Ton Numbers Numbers Empty containers contaminated by hazardous material which cannot be recycled Empty containers contaminated by hazardous raw material Empty containers contaminated by hazardous material which cannot be recycled Collection, storage, transportation and disposal to the authorized recyclers Collection, storage, transportation and disposal to the authorized recyclers Collection, storage, transportation and disposal to the authorized recyclers Flue gas cleaning residue Ton Powder residue Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi Spent ion exchange resin containing toxic metals 34.3 Chemical sludge from waste water treatment 34.4 Oil and grease skimming residues Ton Resin beads Ton Paint ingredients, flocculants used in water treatment Ton Oily material Spent Carbon Ton Ash from incineration of hazardous waste, flue gas cleaning residues Hazardous Waste Quantity and Disposal Details Carbon granules contaminated by hazardous waste Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR / Collection, Storage & disposal through incineration - captive / Collection, Storage, transport & disposal to the authorized recyclers / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi Collection, Storage & disposal through incineration - captive / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi/ Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR Collection, Storage and disposal through incineration - captive / Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi Collection, Storage & disposal through incineration - captive / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi / Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR Collection, Storage & disposal through incineration - captive / Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi / Collection, Storage, transport & disposal through coprocessing/co-incineration in cement kiln / Collection, Storage, transport & disposal through authorized Pre-Processing agencies as AFR Ton Inorganic material Collection, Storage, transportation and disposal to Tamil Nadu Waste Management ltd., Gummidipoondi *Quantity existing are as per HWA application.

13 Annexure 7A: Water Supply Agreement

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18 Annexure 7B: Borewell 1 - Agreement

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23 Annexure 7C: Borewell-2 and 3 Agreement

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29 Annexure 7D: Borewell Order

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31 Annexure 8: Stack and Process Vent Details

32 Annexure 9: List of hazardous chemicals as per MSIHC rules

33 Annexure 10A: GEPIL Agreement

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47 Annexure 10B: TSDF Purchase Order

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50 Annexure 11A: ETP Process

51 Annexure 11B: STP Process

52 Annexure 12A: Water Balance (Existing) Raw water Raw water Treatment Plant Cooling Tower Washing/ Cleaning Domestic Process Effluent % Recovery 75 Evap. + Drift 7 82 losses Process 75 STP Boiler Gardening 41 Sludge Manure Geneartion Consumed in Product Losses Treated Sewage for Gardening RO Permeate 85 % ETP &RO All Values are in KLD 8 9 MEE ( kg/day) Salts from TSDF Raw Water Effluent Loses Recycled Water

53 Annexure 12B: Water Balance (Proposed) Raw water Raw water Treatment Plant Cooling Tower Washing/ Cleaning Domestic % Recovery 110 Evap. + Drift losses Process 110 STP Boiler Gardening 41 Sludge Manure Geneartion Consumed in Product Losses Treated Sewage for Gardening RO Permeate 85 % ETP &RO All Values are in KLD MEE ( kg/day) Salts to TSDF Raw Water Effluent Loses Recycled Water

54 Annexure 13: Details of NH waste Name of Solid Waste Mode of Disposal Unit Quantity Paper Waste Sale of non-hazardous waste to recyclers T/Annum 678 Wooden Waste Sale of non-hazardous waste to recyclers T/Annum 791 Miscellaneous Sale of non-hazardous waste to recyclers T/Annum 21 Plastic Waste (excluding the RM Sale of non-hazardous waste to containers) recyclers T/Annum 278 Metal Waste (excluding the RM Sale of non-hazardous waste to containers) recyclers T/Annum 142 Metal RM containers Sale of non-hazardous waste to recyclers Numbers/Annum 4410 Plastic RM containers Sale of non-hazardous waste to recyclers Numbers/Annum Powder waste Sale of non-hazardous waste to recyclers T/Annum 126