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1 Revised edition: Version: 02/12 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Cembran Pine Oil Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H226 Cat.: 3 H304 Cat.: 1 H315 Cat.: 2 H317 Cat.: 1 H410 Cat.: 1 Classification according to EC Regulation No. 67/548 or No. 1999/45 R10 Flammable liquids, category 3 Aspiration hazard, category 1 Skin irritation, hazard category 2 Skin sensitization, hazard category 1 Hazardous to the aquatic environment, hazard category 1 Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Very toxic to aquatic life with long lasting effects. Flammable. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC 2

2 Regulation 1272/2008 Page 2 Hazard designation: GHS02 GHS07 GHS08-2 GHS09 Signal word: Hazard designation: Safety designation: H226 H304 H315 H317 H410 P210 P262 P273 P280 P301+P330+P331 P302 P310 P352 Danger Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Very toxic to aquatic life with long lasting effects. Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. Do not get in eyes, on skin, or on clothing. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Rinse mouth. Do not induce vomiting. If on skin: Immediately call a poison center or physician. Wash with soap and water Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Essential oil (terpene hydrocarbons) of the cembran pine (Pinus cembra) CAS-Nr: EINECS-Nr: EC-Nr: 3

3 Page Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Do not leave affected persons unattended. Take person away from hazardous area. Supply fresh air. Remove contaminated clothing immediately. Wash off with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Do NOT induce vomiting. Consult a doctor. Risk of aspiration! Rinse mouth with plenty of water. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, CO2, dry extinguishing powder Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Water with full jet Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon oxides. Do not inhale fumes. Wear self-contained respiratory protective device. 6. Further information: Accidential Release Measures 4

4 6. 1. Personal Precautions, Protective Equipment and Emergency Procedures Page Personal precautions: Environmental Precautions Wear protective clothing. Avoid contact with skin, eyes and clothing. Keep away from sources of ignition. No smoking Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent) and dispose accordingly. For information for safe handling see Section 7. Protective clothing, see Section 8. Wear adequate protective clothing (see para. 8) Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Do not inhale gas/fumes/vapours/aerosols. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry room. No special measures necessary. Take measures to prevent static electricity discharge, earth/ground all equipment. Storage class (VCI): Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): 5

5 Derived No-Effect Level (DNEL): No values available. Page 5 Predicted No-Effect Concentration (PNEC): No values available Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Technical protective measures have priority to personal protective measures. Personal Protection General protective measures: Respiratory protection: Hand protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Provide adequate ventilation. Recommended. Protective gloves (EN 374) Solvent resistant protective gloves. Protective glove material: Eye protection: Tightly fitting safety goggles (EN 166). Body protection: Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: liquid colorless - yellowish characteristic neutral not applicable not available Flash point: 39 C 6

6 Evaporation rate: Page Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: not available no information available no information available not determined ca g/cm3 (20 C) insoluble no information available not determined not applicable no information available not determined ethanol 1:8 (clear) Other information: No further information. 7

7 10. Stability and Reactivity Reactivity Chemical Stability Stable at room temperature Possibility of Hazardous Reactions This material is considered to be stable Conditions to Avoid Page Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Avoid temperatures above room temperature: facilitates transition of the liquid into the vapor phase and the formation of explosive atmospheres. Do not store the product in open containers over a longer period of time: facilitates the formation of peroxides and impairs the product quality. No further information available. None known. > 5000 mg/kg > 5000 mg/kg No information available No information available Mutagenicity: 8

8 Reproductive toxicity: Page Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: No toxicity expected. 2 (German Regulation) (Assessment by list): hazardous. Dispose of according to official national and local regulations. Uncontaminated packaging may be recycled. Waste Code No.: 9

9 Page Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: KIEFERNOEL PINE OIL Transport Hazard Classes ADR Class: 3 Hazard no.: 3 Classification code: Tunnel no.: F1 D/E IMDG Class (sea): 3 Hazard no.: 3 EmS No.: F-E, S-D IATA Class: 3 Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User III III III Labelled with "P" according 2.10 IMDG: yes not applicable Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code not applicable Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this 10

10 Further Information Other Information product. Page 10 This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.

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