Dual Media Filtration System for Reducing Pollutants in Storm Water Runoff
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1 Dual Media Filtration System for Reducing Pollutants in Storm Water Runoff Naval Facilities Engineering Service Center rd Avenue Port Hueneme, CA Presenter: Gary Anguiano
2 Outline Background Dual Media Treatment Technology Demonstration Technology Transition 2
3 Background The Navy is required to self-monitor their storm water discharges, identify and install best management practices (BMPs) appropriate to their facilities. The EPA is establishing guidelines for total maximum daily loadings (TMDL) for impaired water bodies. This will result in stricter discharge limits being placed on Navy storm water discharges. Navy industrial activities and other DoD components will be forced to implement storm water treatment systems in order to comply with stricter permit requirements. 3
4 Background Navy industrial sites have limited real estate and limited resources. The ideal storm water treatment system concept should: 1. Have a low capital cost 2. Be easy to install 3. Require little land area 4. Be inexpensive to maintain 5. Enable sites to comply with permit requirements 4
5 Storm Water Treatment Technology Demonstration Project Approach Identify Navy industrial site storm water runoff permit requirements. Analyze storm water runoff characteristics. Evaluate commercially available structural BMP treatment technologies. Demonstrate new storm water treatment technology to address Navy industrial site specific requirements. Transition technology. 5
6 Navy Site Specific Storm Water Permit Requirements The Naval Regional Recycling Center (NRRC) was selected because they must comply with an order from the California Regional Water Quality Control Board (CRWQCB) that requires them to: (1) pass a 96-hour acute toxicity test, (2) reduce copper discharges to less than 63 ppb, and (3) reduce zinc discharges to less the 117 ppb. In the past, NRRC discharges significantly exceeded the metals discharge limits and failed the toxicity tests. 6
7 Naval Regional Recycling Center (NRRC) San Diego Location of demonstration Storm drain system Location of Test Site 7
8 8 Previous Method of Handling Storm Water Runoff at NRRC
9 Characterize Storm Water Runoff Simulated Rain Event at NRCC 9
10 Storm Water Runoff from Simulated Rainfall Event Metals Runoff Level ( g/l) Hydrant Level ( g/l) Permit Limit ( g/l) Antimony Arsenic 18 ND 168 Beryllium ND ND Cadmium 136 ND 15.9 Chromium 102 ND Copper 3, Lead 1, Mercury ND ND 2.4 Nickel 245 ND 1417 Selenium Silver 4 ND 32 Thallium ND ND Zinc 6, Aluminum 19,
11 Evaluate Available Structural Best Management Practices Compliance with the CRWQCB order will require a significant investment by the Navy. Commercial off the shelf (COTS) technologies are expensive. (> $57K per acre of drainage area) COTS technologies have not reliably passed toxicity test. 11
12 Evaluate Available Structural Best Management Practices Large scale StormWater Management, Inc. Installation This 165 cartridge SMI installation at NASSCO costs $530K 12
13 Storm Water Treatment Technology Demonstration NFESC developed and tested a storm water runoff treatment system that meets the stated Navy industrial site requirements. The system is similar to a sand filter. However, instead of using sand as the filter medium, heavy metals from storm water are removed by flowing the runoff through a bed of special filter-adsorption materials. 13
14 Storm Water Treatment System Overview Industrial area Pollutants in storm water will be removed through an innovative three staged filter process. Screen out trash Filter out particles Adsorb heavy metals 14
15 Organic Materials Adsorption Media Tested Active Minerals Inert Minerals Proprietary Materials Others Loose peat moss A-400 activated alumina Perlite Forager sponge cubes Iron chips and filings Hardwood chips FS-50 activated alumina Washed plaster s sand Dynaphore granules Sodium alginate beads Bone char DD-2 activated alumina Washed concrete sand Ancor M-20/80 zero valence iron geotextile Anthracite Chabasite Washed wellpacking gravel Stormwater Management Metal Rx Sulphonated peat moss Manganese green sand Ilmanite Environmental H20, LLC White Karbon Glauconite 15
16 Treatment Media Test Stands Test Column Setup Dual Chamber Test Device Tanks hold runoff water from NRRC; cylinders contain filter/adsorption media 16
17 Media Selection The performing media selected are: activated alumina with surface coating of iron oxide and bone char. Both are readily available and inexpensive. Bone char is used to adsorb heavy metals, fluorides, and iron. Activated alumina is commonly used to remove arsenic and fluoride. 17
18 1/20 th Scale Model Test Setup Scale model installed at NRRC 18
19 1/20 th Scale Model Treatment Test Results Metal Influent mg/l Effluent, mg/l Permit Limit, mg/l Detection Limit, mg/l Aluminum ND Cadmium ND ND Chromium ND ND Copper ND Iron ND Lead ND Zinc ND Test Method EPA Below practical detection limit - ND 19
20 Basic Design Overview Pre-cast concrete vault Porous pavement curb acts as coarse filter Fiber-glass grating Paved apron Parking lot serves as temporary pond Collection piping Gravity flow to storm drain Sand Bone char Activated alumina 20
21 Cell Water Level Control Float Control rod in protective casing Water Sand Bone char Activated alumina Direct lift gate valve Mechanical Level Control Valve 21
22 22 Containment Cell Installation
23 23 Drain Manifold Installation
24 24 Backfilling and Pouring Concrete
25 Sampler and Instrumentation Shed Samples are taken from influent and effluent. Takes first flush and composite samples. 25
26 Completed System 26 Installation completed 4/22/2005.
27 Results Date Total Rainfall (inches) First Flush Intensity (in/hr) Survival 100% Concentration (%) First Flush Influent/Effluent Cu ( g/l) Cu % Removal First Flush Influent/Effluent Zn ( g/l) Zn % Removal 3/28/ /14/ /23/ /22/ /16/ /29/ /18/ /22/ /27/ /22/ /20/
28 Results Influent / Effluent, Average Event Mean Concentration ( g/l) 1 Date Al Cd Cu Fe Pb Ni Zn 2/18/ / / / / / 5 11 / / 74 2/22/ / 92 7 / / / / 2 9 / / 71 2/27/ / / / / / 5 14 / / 129 3/22/ / / / / / 9 29 / / 122 4/20/ / / / / / 5 15/ / 113 Last 5 Storm Events Efficiency Ratio 1. ER in parenthesis / 172 (87) 10 / 2 (83) 198 / 40 (80) 1946 / 268 (86) 45 / 5 (88) 16 / 4 (75) 721 / 122 (83) 28
29 29 Other Applications
30 30 Other Applications
31 Potential Sites Industrial areas Recycling Centers DRMOs Drydocks & Boatyards Maintenance Facilities Storage yards Facilities with copper gutters, galvanized roofs & fences. 31
32 Benefits 1. Enable sites to comply with permit requirements. 2. Treatment system has a low capital cost. ($20,000 per acre of watershed) 3. Virtually no operational/maintenance costs. 4. Requires little land area. 5. Installation similar to other commercially available systems. 32
33 Technology Transfer Technology is patented and will be commercially licensed. The NAVFAC-ESC Technology Integration Team is actively identifying potential user of this technology. NAVFAC-ESC has published project results. 33
34 Publications Publications: R.E. Kirts, M.E. Foreman, and G.D. Anguiano, Removal of Toxic Metals from Storm water Runoff at Naval Installations, NAVFAC Technical Report TR-2256-ENV, November, G.D. Anguiano, and M.E. Foreman, Low Impact Technologies to Reduce Pollution from Storm Water Runoff, NAVFAC Technical Report TR-2300-ENV, September, R. E. Kirts, et. al., METHOD AND MATERIALS TO REDUCE POLLUTION CAUSED BY COPPER, ZINC, AND OTHER METALS IN WASTE WATER, Patent application, November, 2004, 34
35 Acknowledgements Funding provided by: Navy Pollution Abatement Ashore Technology Demonstration/Validation Program (0817) for BMP Pilot study. Environmental Security Technology Certification Program (ESTCP) for a large-scale demonstration of filter-adsorption storm water treatment technology. Site support provided by: Commander Navy Region Southwest Engineering Field Division Southwest San Diego Navy Regional Recycling Center San Diego 35
36 Contact Information Naval Facilities Engineering Service Center (NFESC) rd Avenue Port Hueneme CA Gary Anguiano P.E. (Principal Investigator) (805) Mark Foreman (Project Engineer) (805) Ron Tsumura (Technology Transfer) (805)
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