SAFETY DATA SHEET QC 52 GLASS CLEANER

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Glass Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information :. % - 5. % Company : Ecolab Inc. 37 N. Wabasha Street St. Paul, Minnesota USA Emergency telephone : (US/Canada), (outside US) Issuing date : 2/3/215 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids : Category 3 Skin irritation : Category 2 Eye irritation Specific target organ systemic toxicity - single exposure Not a hazardous substance or mixture. GHS Label element Hazard pictograms : : Category 2A : Category 3 (Central nervous system) Signal Word Hazard Statements Precautionary Statements : Warning : Flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. : Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Use only / 11

2 outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection. Response: IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/ physician if you feel unwell. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration (%) lsopropyl Alcohol butoxyethanol GLYCOLS -Glycolethers Chemical Name CAS-No. Concentration (%) lsopropyl Alcohol SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. : Rinse mouth. Get medical attention if symptoms occur. : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur / 11

3 Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus : Use personal protective equipment. : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so / 11

4 containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. Use only with adequate ventilation. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Wash hands thoroughly after handling. Open drum carefully as content may be under pressure. : Keep away from heat and sources of ignition. Keep in a cool, wellventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : C to 4 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Ingredients CAS-No. Form of exposure / 11 Permissible concentration Basis lsopropyl Alcohol TWA 2 ppm ACGIH STEL 4 ppm ACGIH TWA 4 ppm NIOSH REL 98 mg/m3 STEL 5 ppm NIOSH REL 1,225 mg/m3 TWA 4 ppm OSHA Z1

5 98 mg/m3 2-butoxyethanol TWA 2 ppm ACGIH TWA 5 ppm NIOSH REL 24 mg/m3 TWA 5 ppm 24 mg/m3 OSHA Z1 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Safety glasses with side-shields : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : blue light blue Odor : alcoholic alcoholic ph : 7.65, 1 % Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range : 26 C closed cup / 11

6 Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Relative density :.916 Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble SECTION 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : None known. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion : Causes serious eye irritation. : Causes skin irritation / 11

7 Inhalation Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure : Inhalation may cause central nervous system effects. Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : Redness, Irritation : No symptoms known or expected. : Dizziness, Drowsiness : No symptoms known or expected. : No symptoms known or expected. : No symptoms known or expected. : No symptoms known or expected. Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity IARC : Acute toxicity estimate : 3,921 mg/kg : 4 h Acute toxicity estimate : mg/l : Acute toxicity estimate : 4,26 mg/kg No component of this product present at levels greater than or equal to.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA NTP No ingredient of this product present at levels greater than or equal to.1% is identified as a carcinogen or potential carcinogen by OSHA. No ingredient of this product present at levels greater than or equal to / 11

8 .1% is identified as a known or anticipated carcinogen by NTP. Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : This product has no known ecotoxicological effects. : lsopropyl Alcohol 96 h LC5 Fish: 9,64 mg/l 2-butoxyethanol 96 h LC5: 1,474 mg/l GLYCOLS -Glycolethers 96 h LC5 Fish: > 1 mg/l Ingredients Toxicity to daphnia and other aquatic invertebrates Ingredients Toxicity to algae : 2-butoxyethanol 48 h EC5: 69 mg/l : 2-butoxyethanol 72 h EC5: 911 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available / 11

9 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations RCRA - Resource Conservation and Recovery Authorization Act Hazardous waste Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. : D1 (Ignitable) : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) UN number : 1993 Description of the goods : Flammable liquids, n.o.s. (Isopropanol, 2-propanol, 1-propoxy-) Class : 3 Packing group : III Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1993 Description of the goods : FLAMMABLE LIQUID, N.O.S. (Isopropanol, 2-propanol, 1-propoxy-) Class : 3 Packing group : III Marine pollutant : no Not intended for transport. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 34 Extremely Hazardous Substances Reportable Quantity / 11

10 This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Fire Hazard Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : The following components are subject to reporting levels established by SARA Title III, Section 313: 2-butoxyethanol % California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia Inventory of Chemical Substances (AICS) : New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION / 11

11 Health Health Instability Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: 3 HEALTH 2 2 FLAMMABILITY 3 PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 2/3/215 Version : 1. Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 11