S A F E T Y D A T A S H E E T. Zeolite silica-rich, powder

Transcription

1 S A F E T Y D A T A S H E E T according to Regulation (EC) No. 1907/2006 (amended by Regulation (EU) 2015/830) 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier CAS-No EC-No ; REACH No Product code Synonyms ZEOflair x: x = amendment of the product designation by up to four numerals. ZEOcat PZ-2/x: x = amendment of the product designation by up to six characters Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture Adsorbent Catalyst Desiccant 1.3. Details of the supplier of the safety data sheet Company/Undertaking Identification Zeochem AG, Seestrasse 108, CH-8707 Uetikon am See, Schweiz Tel info@zeochem.ch Only representative according to Art. 8 Regulation (EC) No 1907/2006: Dr. Knoell Consult GmbH, Dynamostr. 19, Mannheim, Deutschland Tel or-services@knoell.com Print Date / 7

2 1.4. Emergency telephone number Tox-Zentrum Zürich : 145 / [24h/7d] Issuing date Version, this safety data sheet replaces the following ones: ZEOcat PZ-2 version GHS 3 ZEOflair version GHS 5 2. Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 Additional information The substance or mixture is not classified. For the full text of the phrases mentioned in this Section, see Section Label elements Signal Word Hazard Statements Precautionary statements Supplemental information Product identifier Zeolite, CAS-No , EC-No ; , REACH No Other hazards No dangerous ingredients according to Regulation (EC) No. 1272/2008. The activated product generates much heat in contact with water. 3. Composition/information on ingredients Chemical characterization Zeolite, crystalline, synthetic, non fibrous Components CLP Classification Product identifier Zeolite > 90% Water < 10% CAS-No.: EC-No.: ; REACH No.: CAS-No.: EC-No.: For the full text of the phrases mentioned in this Section, see Section 16. Hazardous impurities None known. Print Date / 7

3 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion Wash with water and soap as a precaution. Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation persists, consult a specialist. Clean mouth with water and drink afterwards plenty of water Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed None known. None known. 5. Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Extinguishing media which must not be used for safety reasons 5.2. Special hazards arising from the substance or mixture No data is available on the product itself Advice for firefighters Special protective equipment for firefighters Specific methods Standard procedure for chemical fires. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel Advice for emergency responders Handle in accordance with good industrial hygiene and safety practice. Print Date / 7

4 6.2. Environmental precautions No special environmental precautions required Methods and material for containment and cleaning up Use mechanical handling equipment. After cleaning, flush away traces with water. 7. Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Take precautionary measures against static discharges. Store at room temperature in the original container Specific end use(s) 8. Exposure controls/personal protection 8.1. Control parameters Exposure limit(s) No data is available on the product itself Exposure controls Occupational exposure controls General industrial hygiene practice. Personal protection equipment Respiratory protection Hand protection Eye protection Skin and body protection Thermal hazards No special protective equipment required. DRY moleskin gloves. Avoid contact with eyes. Environmental exposure controls Print Date / 7

5 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Form Pellets. Colour Beige. Odour Odorless Odour Threshold ph: (5% in H2O) Melting point/range: > 400 C Boiling point/range: Flash point: does not flash Vitesse d'évaporation: Flammability: Explosion limits: Vapour pressure: Vapor density: Relative density: g/l Water solubility: practically insoluble Partition coefficient (noctanol/water): n.a. Autoignition temperature: Decomposition temperature: Viscosity: Combustion/explosion hazards: not hazardous Oxidizing properties: None 9.2. Other information General Product Characteristics 10. Stability and reactivity Reactivity Chemical stability No decomposition if used as directed Possibility of hazardous reactions Conditions to avoid Not required Incompatible materials The activated product generates much heat in contact with water Hazardous decomposition products None under normal use. Print Date / 7

6 11. Toxicological information Information on toxicological effects Acute toxicity Zeolite (CAS ) LD50/oral/rat > 5000 mg/kg. LD50/dermal/rabbit > 2000 mg/kg. LC50/inhalation/rat > 15 mg/l. No observed adverse effect level (NOAEL): mg/kg (rat, oral). Skin corrosion/irritation Serious eye damage/eye irritation Respiratory / Skin Sensitisation Carcinogenicity Germ cell mutagenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Human experience No skin irritation. Slight eye irritation. Animal testing did not show any carcinogenic effects. Animal testing did not show any mutagenic effects. Animal testing did not show any hazardous effects. This product has no known adverse effect on human health. 12. Ecological information Toxicity Zeolite (CAS ) EC50/48h/daphnia > 100 mg/l. LC50/96h/fish > 680 mg/l. EC50/96h/algae = 300 mg/l Persistence and degradability Bioaccumulative potential Does not bioaccumulate. Accumulation in aquatic organisms is unlikely. Accumulation in terrestrial organisms is unlikely Mobility in soil Results of PBT and vpvb assessment Other adverse effects Print Date / 7

7 13. Disposal considerations Waste treatment methods Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. Offer rinsed packaging material to local recycling facilities. 14. Transport information ADR/RID IMDG IATA Further Information Not regulated. Not regulated. Not regulated. Not classified as dangerous in the meaning of transport regulations. 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Regulatory Information In accordance with Regulation (EC) No. 1272/2008, the product does not need to be classified nor labelled Chemical safety assessment Not required. 16. Other information Key or legend to abbreviations and acronyms Full text of phrases referred to under sections 2 and 3 Disclaimer CLP: Classification according to Regulation (EC) No. 1272/2008 (GHS) PEL: Permissible Exposure Limit The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release. It is not to be considered a warranty or quality specification. Print Date / 7