MATERIAL SAFETY DATA SHEET UltraFiber 500. Buckeye Technologies Inc Tillman Street - P. O. Box Memphis, TN

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1 Buckeye Technologies Inc Tillman Street - P. O. Box Memphis, TN SECTION 1 SECTION 1.1 IDENTIFICATION OF THE SUBSTANCE OR PREPARATION Identification of the Substance or Preparation SUBSTANCE IDENTIFICATION: CHEMICAL NAME: CAS NUMBER: EINECS NUMBER: OTHER IDENTIFICATION MEANS: MANUFACTURED AT: None. is classified as a mixture or preparation. None. is classified as a mixture or preparation. None. is classified as a mixture or preparation. None. Perry, FL U.S.A. SECTION 1.2 Use of the Substance or Preparation is used as a fiber admixture for cementitious composites. SECTION 1.3 Emergency Telephone SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS is predominantly (>95% by weight) cellulose pulp (CAS No ), containing two proprietary additives. SECTION 3 HAZARDS IDENTIFICATION is not classified as dangerous according to Directive 1999/45/EC. SECTION 3.1 Emergency Overview fibers are formed into white, odorless sheets that are converted into rectangular dice. The sheets may catch fire and burn if exposed to ignition sources such as sparks and open flames. Combustion products mainly are compounds of carbon, hydrogen and oxygen, including carbon monoxide. Page 1 of 7

2 SECTION 3.2 Potential Health Effects By Route Of Exposure Chronic (Cancer): fibers themselves, cellulose pulp, and the additives are not listed in lists of carcinogens published by IARC, NTP, or OSHA. Conditions Aggravated: Data are not available. Eye: Dust released from is predominately cellulose, and may mechanically irritate eyes, causing redness and watering. Ingestion: is predominantly cellulose. Cellulose swallowed in association with exposures below published TLV s is not likely to be harmful. (See Section 8.1.) The extent to which the additives may alter this conclusion about cellulose is not known. Inhalation: Dust released from is predominately cellulose. Cellulose inhaled in association with exposures below published TLV s is not likely to be harmful. (See Section 8.1.) The extent to which the additives may alter this conclusion about cellulose is not known. Skin Absorption: Unlikely to occur. Cellulose is virtually insoluble in lipid solvents and water. The extent to which the additives may alter this conclusion is not known. Skin Contact: Repeatedly handling finished forms may mechanically roughen skin. SECTION 4 SECTION 4.1 Eye: Inhalation: SECTION 5 SECTION 5.1 FIRST AID MEASURES First Aid Procedures Treat dust in eyes as a foreign object. Flush with water to remove. Get medical Help if irritation persists. Remove to fresh air. Get medical help if persistent irritation, severe coughing or breathing difficulty occurs. FIRE FIGHTING MEASURES Flammable Properties, as loose fibers, sheets, or rectangular dice, can be ignited and will burn with a self-sustained flame. Combustion products include compounds of carbon, hydrogen and oxygen, for example carbon monoxide. SECTION 5.2 Explosion Properties dust, as any cellulosic dust, is an explosion hazard. SECTION 5.3 Extinguishing Media Water is effective to extinguish burning. Other extinguishing methods may be used as deemed appropriate. No extinguishing method is known to be unsafe for use with. SECTION 5.4 Fire-fighting Instruction Keep personnel removed from and upwind of fire. Wear appropriate fire-fighting gear and respiratory protection. SECTION 6 ACCIDENTAL RELEASE MEASURES Collect for recovery or disposal. No special personal or environmental precautions are necessary. Page 2 of 7

3 SECTION 7 SECTION 7.1 HANDLING AND STORAGE Handling Use equipment and practices appropriate for large, heavy items. Special precautions are not necessary. SECTION 7.2 Storage Store in a cool, dry location away from heat sources, open flames, and sparks. SECTION 8 SECTION 8.1 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limit Values dust may be considered cellulose (CAS No ). The effects of the additives on these values are unknown. ACGIH TLV-TWA 1 10 mg/m 3 Total dust OSHA TLV-TWA 2 15 mg/m 3 Total dust OSHA TLV-TWA 2 5 mg/m 3 Respirable dust TLVs and BEIs, ACGIH 2 29 CFR , Table Z-1 SECTION 8.2 SECTION Exposure Controls Occupational Exposure Controls Minimize practices that generate dust. Use general mechanical and/or local exhaust ventilation to keep dust concentrations below exposure guidelines. SECTION Respiratory Protection Wear particulate filter and/or air-purifying respirator when allowable exposure limits may be exceeded. SECTION Hand Protection Wear gloves to minimize potential mechanical irritation from handling. SECTION Eye Protection Wear safety glasses or goggles where high dust levels are encountered. SECTION Skin Protection Outer garments may be desirable in dusty areas. SECTION Environmental Exposure Controls Special environmental exposure controls are not known. SECTION 9 SECTION 9.1 Appearance: PHYSICAL AND CHEMICAL PROPERTIES General Information Short fibers in odorless, white sheets that are converted into rectangular dice. Page 3 of 7

4 SECTION 9.2 Important Health, Safety, and Environmental Information Boiling Point (760 mmhg): Evaporation Rate (Butyl Acetate = 1): Flash Point (Method Used): Melting Point: ph: Solubility in Water: Not expected to exceed 1% Specific Gravity (H 2 O = 1): 1.5 Vapor Density (Air = 1): Vapor Pressure (mmhg at 20 C): SECTION 9.3 Ignition Temperature: Other Information ignition temperature is expected to be about 400 C. This expectation is based on the chemical similarity among cellulose, cotton fibers, and viscose rayon fibers. Reported ignition temperatures for cotton and rayon fibers are C and 420 C, respectively (Polymer Handbook, Brandrup and Immergut (eds.), 2 nd edition, page V-96, 1975). Minimum Explosive Concentration: Cellulose minimum explosive concentration is oz/ft 3 (55 g/m 3 ), and explosivity indices for cellulose dusts range from weak (<0.1) for raw cotton linters to severe (>10) for ground cotton flock. Variables that affect explosivity include dust concentration, fiber length, heating rate, and moisture content. Data are from Explosivity Of Dusts Used In the Plastics Industry, report of investigations 5971, U.S. Department Of Interior, Bureau Of Mines. Thermal Decomposition: C (Polymer Handbook, Brandrup and Immergut (eds.), 2 nd edition, page V-94, 1975). SECTION 10 SECTION 10.1 STABILITY AND REACTIVITY Conditions to Avoid Dust deposits on hot pipes and machines. SECTION 10.2 Materials to Avoid Open flames, sparks and strong oxidizing agents, e.g. concentrated nitric and sulfuric acid. SECTION 10.3 Hazardous Decomposition Products Chemical Stability: is stable. Hazardous Decomposition Products: None known. Hazardous Polymerization: Will not occur. SECTION 11 TOXICOLOGICAL INFORMATION Information is available upon request. SECTION 12 SECTION 12.1 ECOLOGICAL INFORMATION Ecotoxicity Page 4 of 7

5 SECTION 12.2 Mobility is not expected to migrate into groundwater or travel far from the site of release. SECTION 12.3 Persistence and Biodegradability SECTION 12.4 Bioaccumulative Potential SECTION 12.5 Other Adverse Effects SECTION 13 DISPOSAL CONSIDERATIONS EUROPEAN UNION, as made, does not have the properties of a hazardous waste (Council Directive 94/31/EC), and it may be disposed in Member Countries according to Council Directive 75/442/EEC, as amended. UNITED STATES, as made, is not a hazardous waste, and it may be landfilled or incinerated in accordance with federal, state, and local requirements. SECTION 14 TRANSPORT INFORMATION is predominantly cellulose. The U. S. Department of Transportation does not regulate cellulose as a hazardous material. SECTION 15 REGULATORY INFORMATION Regulatory information is provided as a service to our customers. This information may not address all applicable local, state, national and international regulations. The customer is responsible to determine regulatory information that is relevant to their usage of this product. If further assistance is needed, contact your Buckeye Product Manager. SECTION 15.1 Inventories CANADA CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA):, as cellulose pulp (CAS No ), and the additives are included in the Canadian DSL/NDSL. EUROPEAN UNION (EU) DIRECTIVE 67/548 (as amended by DIRECTIVE 92/32):, as cellulose pulp (CAS No ), and the additives are included in the EINECS inventory. Page 5 of 7

6 SECTION 15.1 Inventories (cont d) UNITED STATES TOXIC SUBSTANCE CONTROL ACT (TSCA):, as cellulose pulp (CAS Number ), and the additives are included in the TSCA Chemical Substance Inventory. SECTION 15.2 U.S. Federal Regulations COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT OF1980 (CERCLA), also called SUPERFUND : Cellulose and the additives are not designated as hazardous substances (40 CFR 302.4), and there are no reportable quantities (40 CFR 302.5) for cellulose releases. Therefore, releases to the environment are not subject to CERCLA notification requirements (40 CFR 302.6). SOLID WASTE DISPOSAL ACT/RESOURCE CONSERVATION AND RECOVERY ACT (RCRA): Cellulose and the additives are not hazardous waste., as cellulose, does not have characteristics of ignitability (40 CFR ), corrosivity (40 CFR ), or reactivity (40 CFR ); and based on knowledge of its composition, it should not exhibit toxicity characteristics (40 CFR ). Furthermore, cellulose and the additives are not included among the lists of hazardous wastes at 40 CFR Part 261, Subpart D. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA): TITLE III - EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW Subtitle A - Emergency Planning and Notification Sec Substances and facilities covered and notification Cellulose and the additives are not included in the List of Extremely Hazardous Substances and Their Threshold Planning Quantities (40 CFR Part 355, Appendices A and B). Subtitle B - Reporting Requirements Sec Material Safety Data Sheets (MSDS) A MSDS may be required to be available for. (See OSHA below.) If so, and if exceeds threshold levels (40 CFR (b)), this MSDS may be subject to MSDS reporting regulations at 40 CFR Sec Emergency and hazardous chemical inventory forms A MSDS may be required to be available for. (See OSHA below.) If so, and if exceeds threshold levels (40 CFR (b)), may be subject to Inventory reporting regulations at 40 CFR Sec Toxic chemical release forms is exempt from Toxic Chemical Release Reporting and Supplier Notification Requirements (40 CFR, Part 372, Subparts B and C, respectively). Cellulose and the additives are not included in the Specific Toxic Chemical Listings (40 CFR, Subpart D) to which release reporting and supplier notification requirements apply. Furthermore, chemicals included in the Specific Toxic Chemical listings that might appear as impurities in will be present at or below de minimus concentrations (40 CFR ). FOOD DRUG AND COSMETIC ACT: contains cellulose, which meets the definition for pulp at 21 CFR , and the additives comply with one or more FDA regulations. Page 6 of 7

7 SECTION 15.2 U.S. Federal Regulations (cont d) OCCUPATIONAL SAFETY AND HEALTH ACT: A Material Safety Data Sheet (MSDS) may be required to be available for. The OSHA Hazard Communication Standard (29 CFR ) requires a MSDS for hazardous substances. Although a hazard is not specified, OSHA includes cellulose among toxic and hazardous substances (29 CFR Part 1910, Subpart Z) and limits its inhalation exposure (29 CFR ). Therefore, since is essentially cellulose, a MSDS may be required to be available. SECTION 15.3 U.S. State Regulations CALIFORNIA PROPOSITION 65: Cellulose and the additives are not included in the list of chemicals known to California to cause cancer or reproductive toxicity. SECTION 15.4 European Union Legislation Cellulose pulp and the two proprietary additives are not classified as dangerous according to Annex I of Directive 67/548/EEC., as a mixture or preparation, is not classified as dangerous according to Directive 1999/45/EC. SECTION 16 OTHER INFORMATION To the best of our knowledge, the information contained herein is accurate. However, Buckeye Technologies makes no warranties or representations concerning the information in this document. This document was prepared by: Laura H. Long, Manager, Product Safety & Regulatory Affairs Signature: Page 7 of 7

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