MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Chem International, Inc. 1. Chemical Product and Company Identification Product Name... OLEYL AMINE, Distilled Product Description... Palm-based Oleyl Amine Chem International, Inc. Emergency Telephone Numbers P.O. Box 5501 Transportation: Greenville, SC CHEMTREC ( Outside United States) Information: Chem International, Inc Composition/Information on Ingredients Principle Components CAS# Percentage Amines, Oleyl Alkyl Hazards Identification Emergency Overview: Danger! Corrosive: Causes eye and skin burns. May be harmful if swallowed. Do not get in eyes, on skin or on clothing. Do not ingest. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Potential Health Effects: Corrosive (Eyes, Skin, Mucous Membranes) Routes of Exposure: Absorbed through skin. Eye contact. Target Organ Effects: Eyes: Causes eye burns. Contact with product at elevated temperatures can result in thermal burns. Skin: Causes skin burns. Contact with product at elevated temperatures can result in thermal burns. Ingestion: Can burn mouth, throat, and stomach. Inhalation: Inhalation of vapors or mists may cause damage to mucous membranes or severe irritation of respiratory passages. Carcinogenicity: January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 1 of 6

2 NTP... Not listed. IARC... Not listed. OSHA... Not listed. 4. First Aid Measures Eye Contact: Immediately flush eyes with water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Do not let victim rub eyes. Check for and remove any contact lenses. Do not attempt to neutralize with chemical agents. Do not use eye ointment. Seek medical attention immediately. Repeated or prolonged contact with spray mist may produce chronic eye irritation. Skin Contact: Immediately flush skin with plenty of water while removing contaminated clothing and shoes. Get medical attention. Contaminated clothing should be discarded in a manner which limits further exposure. Repeated or prolonged contact with spray mist may produce chronic skin irritation. Ingestion: If swallowed, do NOT induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Repeated or prolonged contact with spray mist may produce respiratory tract irritation leading to request attacks of bronchial infection. 5. Fire Fighting Measures Flammable Properties: Flash Point ( F/ C)...: Test Method...: Flammable Limits (Percent by Volume) Lower Explosion Limit...: Upper Explosion Limit...: Flammability Classification...: (As per 29 CFR ) 300 F/ C Pensky-Martens Closed Cup Not Known Not Known Not Classified Extinguishing Media: Use dry chemical powder for small fires. Use water spray, fog or foam for large fires. Do not use water jet. Hazardous Products of Combustion: These products are carbon oxides (CO, CO2) nitrogen oxides (NO, NO2 ). Incomplete combustion may produce hydrogen cyanide. Fire Fighting Instructions: Fire fighters should wear full protective gear including self-contained breathing apparatus (SCBA) with full face shield operated in positive pressure mode, and full protective clothing. May be combustible at high temperatures. Closed containers may swell and rupture when exposed to extreme heat. Water runoff may cause environmental damage. Dike and collect water used to fight fires. 6. Accidental Release Measures January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 2 of 6

3 Personal Precautions: Individuals involved in clean up activities must use appropriate protective equipment as listed in Section 8. This material forms slippery surfaces on floors, posing an accident risk. Environmental Precautions: If material is released into the environment (air, land, water - via sewage system), the user should determine whether spill must be reported to appropriate local, state, and/or federal authorities. Spill Response Procedures: Wear suitable protective clothing and eye/face protection. Isolate spill area and restrict non-essential personnel from the area. Use an approved, properly fitted, powdered-air purifying respirator or respirator of equivalent or greater protection. Stop leak if without risk. Confine spill by diking with sand, earth, or inert absorbent material if without risk. Absorb onto suitable material (sand, vermiculite, etc.), then shovel into suitable container for disposal. Use a non-sparking or explosion proof means to transfer material to a sealed, appropriate container for disposal. Pump spilled material to salvage according to a predetermined plan. Flush residual spill (area) with large amount of water. Do not allow to enter drains or watercourses. 7. Handling and Storage Handling: Wear suitable protective clothing and eye/face protection. Avoid contact with skin and eyes. Wash thoroughly after handling. Empty containers retain product residue and can be hazardous. Follow all warnings and precautions even after container is emptied. Storage: Keep in a tightly closed container. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Do not store above 48 C. Exercise caution to prevent leakage from the container. 8. Exposure Controls/Personal Protection Engineering Controls: Ventilation is normally required when handling or using this product. Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Personal Protective Equipment: Eye/Face - Wear safety glasses with side shields (or goggles) and a face shield. Respiratory If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. If workers are exposed to concentrations above the exposure limit, they must use a NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister. When using respirator cartridges or canisters, they must be changed frequently (following each use or at the end of the work shift) to assure breakthrough exposure does not occur. Skin/Body Skin contact with the product should be prevented through the use of suitable clothing, gloves and footwear selected with regard for use condition exposure potential. Use neoprene or nitrile rubber gloves. Other Precautions - Safety shower and eye wash station should be located in exposure area. Reduce exposure by proper use of personal protective equipment. Wash hands and face before eating, drinking, or smoking. Occupational Exposure Limits: No exposure limits established for this product, or individual components. January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 3 of 6

4 9. Physical and Chemical Properties Physical state...: Liquid Color...: Yellow Odor...: Ammoniacal Specific gravity (water = 1.0)...: Solubility (in water)...: Slightly soluble in cold water ph...: 7-14 Vapor pressure (mmhg)...: No information Vapor density (air = 1)...: No information Boiling point ( F/ C)...: 220 C Percent volatile...: 1% 10. Stability and Reactivity Conditions to Avoid: Stability...: Conditions to Avoid...: Materials to Avoid...: Hazardous Decomposition Products...: Hazardous Polymerization...: Stable High temperatures Oxidizing agents, acids Oxides of carbon and nitrogen may be emitted if product burns Will not occur 11. Toxicological Information Acute toxicity: LD/LC50 values that are relevant for classification: Oral... LD mg/kg (rat) (OECD 401) Dermal... LD50 > 2000 mg/kg (rat) (OECD 402) Inactive... LD50 > ppm (rat) (OECD 403) Primary irritant effect: On the skin: Strong caustic effect on skin and mucous membranes On the eye: Strong caustic effect Sensitization: No sensitizing effects known Other information (about experimental toxicology): Oral... NOAEL (Repr. Tox.) 12.5 mg/kg (rat) (OECD 421)... AMES-Test negativ (bacterium) (OECD 471) Additional toxicological information: Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. 12. Ecological Information January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 4 of 6

5 Information about elimination (persistence and degradanility): Easily biodegradable Ecotoxical effects: Acquatic toxicity: EC mg/l (algae) (OECD 201) mg/l (daphnia) (OECD 202) LC mg/l (fish) (OECD 203) LOEC (Long term) mg/l (daphnia) (OECD 211) Additional ecological information: General notes: Water hazard class 2 (Assessment by list): hazardous for water Do not allow product to reach ground water, water course or sewage system. Also poisonous for fish and plankton in water bodies. 13. Disposal Considerations As originally offered, this product if disposed of, is not considered a hazardous waste under current Resource Conservation and Recovery Act (RCRA) regulations (40CFR 261). State and local regulations should also be consulted regarding proper disposal. 14. Transport Information Land Department of Transportation (DOT) UN 2735, Amines, liquid, corrosive, N.O.S., (fatty acid derived amines), 8, PG III Air International Air Transport Association (IATA) UN 2735, Amines, liquid, corrosive, N.O.S., (fatty acid derived amines), 8, PG III Sea International Maritime Organization (IMO) UN 2735, Amines, liquid, corrosive, N.O.S., (fatty acid derived amines), 8, PG III 15. Regulatory Information U.S. Federal Regulations: Toxic Substances Control Act (TSCA) Information The component(s) of this product are listed on the TSCA Chemical Substances Inventory. Superfund Amendments and Reauthorization Act (SARA Title III) Section 311/312 Hazard Category Immediate Health Hazard. Section 313 Listed Chemical Components Chemical Name or Category...: CAS#...: Concentration...: None NA NA International Regulations: Canadian Environmental Protection Act (CEPA) January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 5 of 6

6 Listed in the Domestic Substance List 16. Other Information MSDS Revision Status: MSDS Date... : November 20, 2008 Last Revision Date... : January 9, 2012 Reason for Revision... : Date Revision Only Freight Classification (National Motor Freight Classification): Organic Fatty Amine Compounds, Item , Class 65 Hazardous Materials Information System (HMIS) Rating: Health... : 4 Reactivity... : 0 Flammability... : 1 January 9, 2012 MSDS: DISTILLED OLEYL AMINE Page 6 of 6