Version: 3.0. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax
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1 Revised edition: Version: 3.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Dioxazine Violet Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring component Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards 2
2 Composition/Information on Ingredients Substance Mixture Page 2 This product is capable of dust explosion under certain circumstances. Chemical Characterization: Dioxazine, C.I. Pigment Violet 37 Information on Components / Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air. Consult physician if symptoms persist. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Extingishing powder, foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Carbon dioxide (CO2) Special hazards: In case of fire: hazardous vapors may be released. Development 3
3 of fumes/aerosol Advice for Firefighters Page 3 Protective equipment: Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid formation of dust: risk of dust explosion. Dispose of fire debris and contaminated extinguishing water in accordance with local regulations Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Contain with dust binding material and dispose accordingly. Avoid dust formation. Protective clothing, see Section 8. See Section 13 for information on disposal. Respiratory protection when handling without exhaust system Hygienic measures: Conditions for Safe Storage, including any Incompatibilities No special measures required. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and cool room. No special measures necessary. Avoid dust formation. Dust explosion class 1 (Kst-value > bar m/s). 4
4 11; Combustible solids Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TRGS 900 TLV: 1.25 mg/m3 air-borne fraction (general dust limit) TLV: 10 mg/m3 inhalable fraction (general dust limit) Peak limit Category: 2 (II) Category II: substances with a resorptive effect. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: The usual precautionary measures are to be adhered to when handling chemicals. Protective clothing recommended due to the coloring effects of the product. Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). Protective gloves (EN 374) Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Body protection: 5
5 Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 Avoid contamination of sewage system, open water ways and ground water. Form: Color: Odor: Odor threshold: powder violet odorless ph-value: Melting temperature: > 300 C Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: not available This product is a non-volatile solid. 410 C (BAM) not easily flammable no information available no information available 1.35 g/cm3 (20 C) insoluble no information available Product is not auto-ignitable. Decomposition temperature: > 180 C Viscosity, dynamic: Explosive properties: Product is not explosive. 6
6 Oxidizing properties: not oxidizing Page Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: 345 kg/m3 (20 C) Particle size: 16 µm Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: No further information. Stable if used according to specifications. Stable if used according to specifications. Risk of dust explosion. Avoid formation of dust. Avoid electrostatic discharge. Avoid ignition sources. No further information available. Strong acids, strong bases and strong oxidizing agents. None if stored and handled according to specifications. > 5000 mg/kg (rat) > 2000 mg/kg (rat) Primary effects 7
7 Irritant effect on skin: Non irritating Page Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Non-irritating to eyes No information available Not sensitizing. Product does not show a mutagenic effect in a test with bacteria. No data available. No negative effects. Single exposure: no organospecific toxicity expected. Repeated exposure: no information available. Aspiration hazard: Not hazardous for aqueous organisms. not determined EC50: > 100 mg/l (0.5h, active sludge) The product in virtually insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plants. Controlled release of small amounts of product in biological sewage system do not cause disorders of the biodegradablity of activated sludge. No bioaccumulation expected due to the distribution coefficient n- 8
8 Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Octanol/water (logpow). Page 8 According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. Water hazard class: Behaviour in sewage systems: Further ecological effects: 1 (German Regulation) (Assessment by list): slightly hazardous. Treatment and discharge of waste water into biological treatment plant should be carried out according to official national and local regulations. Do not discharge product uncontrolled into the environment. The data refer to the properties of the individual components AOX Value: Disposal Considerations Waste Treatment Methods Product: In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. Uncontaminated packaging may be recycled Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. ADR Class: 9
9 Page 9 Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation, Assessment by list) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not yet been carried out for this product. Regulation (EC) 2037/ Substances that Deplete the Ozone Layer: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be 10
10 Page 10 therefore not be construed as guaranteeing specific properties.
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