Safety Data Sheet. according to Regulation (EC) No 1907/2006. KaVo Kalkloeser. Print date: Page 1 of 7

Transcription

1 Print date: Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product code: Product group: Verkaufsprodukt 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Lime-Solvent 1.3. Details of the supplier of the safety data sheet Company name: Street: Place: Bismarckring 39 D Biberach Telephone: +49 (0) Telefax:+ 49 (0) Internet: 1.4. Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Indications of danger: Xi - Irritant R phrases: Irritating to eyes (0) (24 h) Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Hazard Statements: 2.2. Label elements Signal word: Pictograms: Warning GHS07 Hazard statements H319 Precautionary statements P264 Wash hands thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention Other hazards

2 Print date: Page 2 of 7 SECTION 3: Composition/information on ingredients 3.2. Mixtures Hazardous components EC No Index No REACH No Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity Citric acid <= 99 % Xi - Irritant R Eye Irrit. 2; H319 Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures After inhalation Provide fresh air. After contact with skin Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an ophthalmologist immediately. After ingestion Rinse mouth immediately and drink plenty of water Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. Water spray, Powder, Foam, Carbon dioxide (CO2) 5.2. Special hazards arising from the substance or mixture Non-flammable. In case of fire: Formation of: Gases/vapours, irritant Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Avoid generation of dust. Do not breathe dust. Avoid contact with skin,

3 Print date: Page 3 of 7 eyes and clothes. Use personal protection equipment Environmental precautions Do not allow to enter into surface water or drains Methods and material for containment and cleaning up Take up mechanically. Treat the recovered material as prescribed in the section on waste disposal Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling No special measures are necessary. Advice on protection against fire and explosion No special fire protection measures are necessary Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed. Advice on storage compatibility No special measures are necessary Specific end use(s) Lime-Solvent SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective and hygiene measures Remove contaminated, saturated clothing immediately. Draw up and observe skin protection programme. Wash hands and face before breaks and after work and take a shower if necessary. When using do not eat or drink. Eye/face protection Suitable eye protection: goggles. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection.

4 Print date: Page 4 of 7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value (at 25 C): solid (Powder ) white odourless 1,8 (5 % in aqueous solution) Test method Changes in the physical state Melting point: Initial boiling point and boiling range: Flash point: Flammability Solid: Gas: Explosive properties Lower explosion limits: Upper explosion limits: Auto-ignition temperature Solid: Gas: 153 C not determined Decomposition temperature: > 170 C Oxidizing properties Not oxidizing. Vapour pressure: Density (at 20 C): Bulk density: Water solubility: Solubility in other solvents 38,3 %, 25 C Ethanol Partition coefficient: Viscosity / dynamic: Viscosity / kinematic: Vapour density: Evaporation rate: 9.2. Other information Solid content: 1,665 g/cm³ kg/m³ easily soluble not determined Odour threshold: SECTION 10: Stability and reactivity Reactivity Possibility of hazardous reactions. Reference to other sections: Chemical stability

5 Print date: Page 5 of 7 The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions Conditions to avoid none Exothermic reaction with: Base, Peroxide, Oxidising agent Incompatible materials Keep away from: Oxidising agent, Peroxide. Alkali (lye) Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Acute toxicity Exposure routes Method Dose Species Source Citric acid dermal LD50 > 2000 mg/kg Rat IUCLID Irritation and corrosivity Irritant Irritant Sensitising effects STOT-single exposure Severe effects after repeated or prolonged exposure Carcinogenic/mutagenic/toxic effects for reproduction Aspiration hazard Additional information on tests This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. SECTION 12: Ecological information Toxicity The product is not: Ecotoxic. Aquatic toxicity Method Dose [h] [d] Species Source Citric acid Acute fish toxicity LC50 >100 mg/l 96 h Pimephales promelas IUCLID (fathead minnow) Algea toxicity NOEC 425 mg/l 8 d Scenedesmus quadricauda IUCLID

6 Print date: Page 6 of Persistence and degradability Readily biodegradable (according to OECD criteria). Method Evaluation Citric acid Bioaccumulative potential Value d Source CO2 formation (% of the theoretical value). 97 % 28 OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C Readily biodegradable (according to OECD criteria). No indication of bioaccumulation potential. Partition coefficient n-octanol/water Log Pow Citric acid -1, Mobility in soil The product has not been tested Results of PBT and vpvb assessment The product has not been tested Other adverse effects Further information Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation. Contaminated packaging Wash with plenty of water. Completely emptied packages can be recycled. SECTION 14: Transport information Land transport (ADR/RID) UN number: No dangerous good in sense of this transport regulation UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards ENVIRONMENTALLY HAZARDOUS: Special precautions for user No dangerous good in sense of this transport regulation. No dangerous good in sense of this transport regulation. No dangerous good in sense of this transport regulation Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information no Safety, health and environmental regulations/legislation specific for the substance or mixture

7 Print date: Page 7 of 7 National regulatory information Employment restrictions: Water contaminating class (D): Chemical safety assessment Observe employment restrictions for young people. 1 - slightly water contaminating For the following substances of this mixture a chemical safety assessment has been carried out: Citric acid SECTION 16: Other information Changes This data sheet contains changes from the previous version in section(s): 1,3,6,7,10,12,13,14,15. Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Relevant R-phrases (Number and full text) 36 Irritating to eyes. Relevant H- and EUH-phrases (Number and full text) H319 Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)