03 Hazards identification R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Transcription

1 01 Identification of the substance / preparation and of the company Product: Use: Company: Phone: Fax: Homepage: Emergency phone: 02 Composition / Information on ingredients Substance KERATHERM TYP Wärmeleitpasten - Silikonfrei (Keratherm KP12) Heatled paste Stegenthumbach Eschenbach +4 (0) (0) info@kerafol.com +4 (0) EINECS/ ELINCS CAS INDEX Range [%] Symbol / R-phr. Zinc oxide < 25 N-50/53 aluminium powder (pyrophoric) < 20 F Hazards identification R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 04 First aid measures General information: Inhalation: Skin contact: Eye contact: Ingestion: Advice to doctor: 05 Fire-fighting measures Suitable extinguishing media: Extinguishing media that must not be used: Special exposure hazards arising from the substance or preparation itself or combustion products: Special protective equipment for firefighters: Additional information: Change soaked clothing. When in contact with the skin, clean with soap and water. Consult a doctor if skin irritation persists. In case of contact with eyes rinse thoroughly with water. In the event of symptoms seek for medical treatment. Treat symptomatically. Foam. Dry powder. Water spray jet. Carbon dioxide. Full water jet. Risk of formation of toxic pyrolysis products. Use self-contained breathing apparatus. Fire residues and contaminated firefighting water must be disposed of in accordance within the local regulations. Page 1 / 5

2 06 Accidental release measures Personal precautions: Environmental precautions: Methods for cleaning up: High risk of slipping due to leakage/spillage of product. Do not discharge into the drains/surface waters/groundwater. Dispose of absorbed material in accordance within the regulations. Take up mechanically. 07 Handling and storage Advice on safe handling: Advice on protection against fire and explosion: Requirements for storage rooms and vessels: Advice on storage compatibility: Further information on storage conditions: No special measures necessary. No special measures necessary. Keep only in original container. Store in a dry place. Protect from sun. 08 Exposure controls / personal protection Additional advice on system design: Ensure adequate ventilation on workstation. Ingredients with occupational exposure limits to be monitored: Respiratory protection: Hand protection: Eye protection: Skin protection: General protective measures: Hygiene measures: Delimitation and monitoring of the environmental exposition: Butyl rubber, >120 min (EN 374). Safety glasses. Wash hands before breaks and after work. Use barrier skin cream. Page 2 / 5

3 0 Physical and chemical properties Form: pasty Color: silver-grey Odor: characteristic ph-value: ph-value (1 %): Boiling point [ C]: Flash point [ C]: > 260 Flammability [ C]: Lower explosion limit: Upper explosion limit: Combustible properties: no Vapour pressure [kpa]: Density [g/ml]: 1,4 Bulk density [kg/m³]: Solubility in water: insoluble Partition coefficient: n- octanol/water: Viscosity: Relative vapour density determined in air: Evaporation speed: Melting point [ C]: Autoignition temperature [ C]: Decomposition temperature [ C]: 10 Stability and reactivity Hazardous reactions: Hazardous decomposition products: 11 Toxicological information Acute oral toxicity OECD 401: Experiences made in practice: General remarks: 12 Ecological information Fish toxicity: Daphnia toxicity: Behaviour in environment compartments: Behaviour in sewage plant: Bacteria toxicity: Biological degradability: COD: If product is heated above decomposition temperature toxic vapours may be released. Possible in traces: Formaldehyde. Toxicological data are not available. The product was classified on the basis of the calculation procedure of the preparation directive. Page 3 / 5

4 BOD 5: AOX-advice: No dangerous components. 2006/11/EC: yes General information: The product is insoluble in water. 13 Disposal considerations Disposal / Product: Waste no. (recommended): Disposal / Contaminated packaging: 14 Transport information ADR: Factor (ADR ): LQ (ADR 3.4.6): Hazard-no.: Vapour pressure [kpa]: IMDG: LQ [l, kg]: EmS: IATA: In according to RoHS Disposal in an incineration plant in accordance with the regulations of the local authorities. Uncontaminated packaging may be taken for recycling. UN 3082 Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide),, III UN 3082 Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide) 1 LQ7 0 Class: UN 3082, Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide), Class:, PG: III Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide), UN 3082, Class: 5 F-A, S-F III Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide), Class: UN 3082 III Environmentally hazardous substance, liquid, n.o.s. (contains Zinc oxide) UN 3082 Miscellaneous Page 4 / 5

5 15 Regulatory information Hazard symbols: Dangerous for the environment. The product is classified and labelled in accordance within EC-directives. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 60: This material and its container must be disposed of as hazardous waste. S 61: Avoid release to the environment. Refer to special instructions/safety data sheets Special labelling for certain preparations 15.2 Sources of documentation EEC: 1/155 (2001/58); 67/548 (2004/73, 2. ATP); 1/45 (2006/8); 1/68 (2001/118); 8/542; 1/13; 2004/42 Transport information: ADR (2007); IMDG-Code (33. Amdt.); IATA-DGR (2007) 15.3 National regulations () EH40/2002 Occupational Exposure Limits Supplement Other informations (Information on ingredients - position 02) R 15: Contact with water liberates extremely flammable gases. R 17: Spontaneously flammable in air. R 50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Additional information: Observe employment restrictions for people: VOC (1/13/EG): Customs Tariff: no 16.2 Information on ingredients 2004/42/EG: UBA-Registration: 648/2004/EG, Contains: 16.3 Modified position Page 5 / 5