Scientific Evaluation of Contact Water from an Organics Compost Demonstration Site

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1 Scientific Evaluation of Contact Water from an Organics Compost Demonstration Site 1

2 Source Separated Organic Material Minnesota rules revision process will: 1. Move organics management up waste hierarchy; 2. Define SSOM and clarify facility engineering; 3. Provide regulatory relief without jeopardizing environmental protection. 2

3 Project Objectives Evaluate surface and ground water contamination: soil type distance from water table volume and chemical composition of contact water facility pad engineering

4 University of Minnesota Landscape Arboretum Operated by Specialized Environmental Technologies 2.5 acre site on well drained loam soils The site accepts residential cocollected & limited commercial organics PHASE I & II PHASE III 4

5 Phase I ( )

6 Phase I ( ) Surface water Surface water 6

7 Phase I & II 4-9 of rain over 3-5 hrs small surface sample volumes did not produce sub-surface volumes low moisture in compost piles 7

8 Phase III (Liner Study) Class 1 12 sand liner soil 8

9 Base/ liner Phase III Compacting Gravel Test Surface Sub Soil Collection Sump surface Liner subsurface 9

10 Phase III Surface Sub Surface 10

11 Feedstock Test Piles Mixing Loading Test Cells Test Piles 11

12 Phase III Day 1: Mixing Day 38: Process to Further Reduce Pathogens (PFRP) Day 72: Solvita Maturity 12

13 Compost Moisture Moisture Before After Water Holding Capacity Rain Rain Pile 1 Pile 2 Pile 3 Day Day Day

14 Rain Fall Totals Time (hours) Rain (inches) Day 1 Mixing Day 38 PFRP Day 72 Maturity ~ equivalent of three 500-year rain events 14

15 503 Metals (ug/l) 1 Day 1 Day 38 Day 72 HRL Municipal Drinking Water Arsenic Barium 2,643 10,123 1,446 2,000 Boron 3,340 1, ,000 Cadmium Chromium Copper 1, ,300* Lead * Selenium Silver 100 (S) Mercury Molybdenum Nickel Potassium 226,333 1,616, ,666 Zinc <25.0 ND 5,000 (S) 1 Averages are 3 data points or less. *MDH action levels

16 Biological Parameters Day 1 Day 38 Day 72 HRL Municipal Drinking Water Nitrate as N mg/l NO2&NO3 mg/l Nitrite mg/l TKN mg/l Phosphorous mg/l TDS mg/l 19, , , TSS mg/l Total Coliform MPN/100/mL 242, , , E-Coli MPN/100/mL 242, , , cbod mg/l 5, , BOD mg/l 5, , COD mg/l 28, , ,910.00

17 Test Cell #1 Pile Creation Day (alpha-bhc) (delta-bhc) (Lindane) **Pesticides (ug/l) PFRP (Day 32) Solvita Maturity (Day 72) (delta-bhc) (Lindane) (alpha- Chlordane) HRL Municipal Drinking Water Lindane* 0.2 Test Cell # (Lindane).135 (alpha-chlordane) (delta-bhc) (alpha-chlordane) Alpha- Chlordane 2,000 Test Cell # (delta-bhc) (delta-bhc) *Lindane was taken off EPA registration in2006; BHC is a breakdown product of Lindane and essentially the same chemical structure. **17 Pesticides ND (not detected at reporting limit)

18 Herbicides (2,4-D) Herbicides (ug/l) Day 1 Day 38 Day72 HRL Municipal Drinking Water Test Cell # Test Cell # Test Cell # Non-Detect 2,4,5-T 2,4,5-TP (Silvex) 18

19 PFC & BPA ppt Aqueous Day 1 Day 38 Day 72 HBV (Health Based Value) PFBA *NQ NQ NQ 7,000 PFPeA PFHxA PFHpA 18 PFOA PFNA PFDA PFUnA PFDoA PFBS ,000 PFHxS PFOS 300 PFOSA 300 BPA *NQ (non-quantifiable) due to matrix complications laboratory analysis was unable to generate results. 19

20 SAND CLAY Adsorption of Pb 2+ by quartz, gibbsite, and kaolinite as a function of ph Nature Education Adapted from Essington All rights reserved. 20

21 Nature Education Adapted from Essington All rights reserved.

22 Soil Organic Matter 2012 Nature Education All rights reserved. 22

23 Soil Microbes urbanext.illinois.edu 23

24 Provided by SourcEd, an ECDF service at the University of Edinburgh. 24

25 25

26 26

27 27

28 Application Right tool (science) Constructed properly (research) Applied in the right way, in the right context (decision making processes) 28

29 Source Separated Organic Material Minnesota rules revision process will: 1. Move organics management up waste hierarchy; 2. Define SSOM and clarify facility engineering; 3. Provide regulatory relief without jeopardizing environmental protection. 29

30 Project Objectives Evaluate surface and ground water contamination: soil type distance from water table volume and chemical composition of contact water facility pad engineering

31 Conclusions Move organics management up waste hierarchy; Define SSOM and clarify facility engineering; regulatory relief without jeopardizing environmental protection.

32 Questions? Questions? Marcus Zbinden Carver County Environmental Services Or Sarah Braman Carver County Environmental Services Or Tim Farnan Minnesota Pollution Control Agency Or Mike Mondloch Minnesota Pollution Control Agency (651)

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