Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet WHMIS WHMIS (Classification) Protective Clothing Not controlled under WHMIS (Canada). Section 1. Chemical Product and Company Identification Product Name/ Trade name Supplier Debro Chemicals 11 Automatic Drive Brampton (Ontario) L6S 4K6 (95) Code CAS # Synonym Chemical Name Chemical Family Chemical Formula Manufacturer Material Uses 255 Hymus Blvd Dorval (Quebec) H9P 1J8 (514) stannic oxide SnO2 DSL CI# Print Date In Case of Emergency CEPA DSL: Tin Oxide Validation Date 22/4/212 14/7/212 CHEMTREC: Section 2. Composition and Information on Ingredients Name CAS # % by Weight No hazardous ingredient. Exposure Limits LC 5/LD 5 Section 3. Hazards Identification Potential Acute Health Effects Slightly hazardous in case of eye contact (irritant), of inhalation (lung irritant). Potential Chronic Health Effects Slightly hazardous in case of inhalation (lung irritant). CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4. First Aid Measures Eye Contact Skin Contact NO known EFFECT on eye contact, rinse with water for a few minutes. If irritation develops, seek medical attention. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. If irritation persists, seek medical attention.

2 Inhalation Ingestion Page: 2/6 If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear. NO known EFFECT according to our data base. If ingested in large amounts, seek immediate medical attention. Section 5. Fire Fighting Measures Products of Combustion Fire Fighting Media and Instructions Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Use extinguishing media suitable for surrounding materials. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Personal Protection in Case of a Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions Incompatibility Storage Do not ingest. Do not breathe dust. If ingested, seek medical advice immediately and show the container or the label. Chlorine trifluoride Keep container tightly closed. Keep container in a cool, well-ventilated area. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Eyes Safety glasses. Body Lab coat. Respiratory Dust respirator. Be sure to use an approved/certified respirator or equivalent. Hands Gloves (impervious). Feet

3 Protective Clothing Page: 3/6 Exposure Limits STEL: 4 (mg/m 3 ) from ACGIH (TLV) [United States] Inhalation Total. TWA: 2 (mg/m 3 ) from NIOSH Inhalation Total. Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Solid. (Powdered solid.) Odor Odorless. Molecular Weight 15.7 g/mole Taste ph (1% Soln/Water) Color White. Boiling/Condensation Point Melting/Freezing Point 163 C (2966 F) Critical Temperature Instability Temperature Specific Gravity 6.95 (Water = 1) Vapor Pressure Vapor Density Volatility Evaporation Rate Odor Threshold Viscosity LogK ow Ionicity (in Water) Dispersion Properties Solubility Insoluble in cold water, hot water, methanol. The Product is: Non-flammable. Auto-ignition Temperature Flash Points Flammable Limits Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge:

4 Section 1. Stability and Reactivity Page: 4/6 Stability Conditions of Instability Incompatibility with Various Substances Corrosivity Hazardous Decomposition Products Special Remarks on Reactivity Special Remarks on Corrosivity The product is stable. Chlorine trifluoride Reacts violently with chlorine trifloride. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Acute oral toxicity (LD5): >2 mg/kg [Rat]. Acute Effects on Humans Eyes Slightly hazardous in case of eye contact (irritant). Skin Inhalation Slightly hazardous in case of inhalation (lung irritant). Ingestion Chronic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans Slightly hazardous in case of inhalation (lung irritant). CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic.

5 Section 13. Disposal Considerations Page: 5/6 Waste Information Waste Stream Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14. Transport Information TDG Classification Not controlled under TDG (Canada). PIN Maritime Transportation Special Provisions for Transport Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) Not controlled under WHMIS (Canada). Regulatory Lists Other Regulations CEPA DSL: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications HCS (U.S.A.) USA Regulatory Lists Class: Target organ effects. DSCL (EEC) International Regulations Lists This product is not classified according to the EU regulations. No products were found. Hazardous Material Information System (U.S.A.) Health Flammability Reactivity * 1 National Fire Protection Association (U.S.A.) Health 1 Flammability Reactivity Personal Protection e Specific Hazard DOT (U.S.A) DSCL (Europe)

6 ADR (Europe) Page: 6/6 Section 16. Other Information References Other Special Considerations -Manufacturer's Material Safety Data Sheet. Validated by Regulatory affairs on 22/4/212. Information Contact Debro Chemicals 11 Automatic Drive Brampton (Ontario) L6S 4K6 (95) Verified by Regulatory affairs. Printed 14/7/ Hymus Blvd Dorval (Quebec) H9P 1J8 (514) Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.