Material Safety Data Sheet 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 Name: EPY compound page:1/6 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade name: EPY General use: 2-Components casting resin, basis resin. After curing, the product is not hazardous. Chemical family: Epoxy resin-mixture Manufakturer: Marine Service Jaroszewicz s.c., Szczecin, Poland Deliverer: Marine Service Jaroszewicz s.c., Szczecin, Poland Emergency telephone number: (+48 42) COMPOSITION/INFORMATION ON INGREDIENTS Substance Range % No CAS No EINECS Bisfenol A z epoxy resin (mw <700) Quartz 3. HAZARDS IDENTIFICATION Trade secret Trade secret Warning symbols: Xi N Irritant, Dangerous for the environment

2 Name: EPY compound page:2/6 Hazards identification: R36/38 Irritating to eyes and skin, R43 May cause sensitisation by skin contact, R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety symbols: S28 In case of contact with skin wash immediatelly with large quantity of water S37/39 Gloves and eye/face protection required. S61 Avoid release to the environmental. Refer to special instructions / safety data sheets 4. FIRST AID MEASURES Inhalation: 1. Ensure supply of fresh air. 2. In the event of symptoms refer for medical treatment. Ingestion: 1. Rinse out mouth and give plenty of water to drink. Do not induce vomiting. 2. Summon a doctor immediately. Eye contact: 1. Flush eye with clean water for at least minutes while gently holding eyelids open, lifting upper and lower lids. Get immediate medical attention. Skin contact: 1. In case of contact with skin Immediately remove contaminated clothing and excess contaminant next wash off immediately with soap and water. 2..Consult a doctor if skin irritation persists.

3 Name: EPY compound page:3/6 5. FIRE FIGHTING MEASURES Special exposure hazards arising from the substance: Suitable extinguishing media: Special protective equipment for firefighters: Risk of formation of toxic pyrolysis products. Foam. Carbon dioxide. Dry powder. Water spray jet. Firefighters should wear self-contained breathing apparatus and protective clothing. 6. ACCIDENTAL RELEASE MEASURES Spill control:: Protective equipment: Environmental precautions: Cleanup: Avoid personal contact. Eliminate ignition sources. Ventilate area. The personnel should wear protective clothing, safety glasses and protectiwe gloves. Do not discharge into the drains/ surface waters/ groundwater. For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand, or other suitable material and dispose of properly. Flush area with water to remove trace residue. 7. HANDLING AND STORAGE Handling: Storage: The product should be stored in original packing. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before eating, drinking, smoking. Use protective clothing. Handle in well ventilated work space. Keep container tightly closed. Store in a dry place. Do not store together with another flamable products. Keep away from high temperatures and flames. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Although good general mechanical ventilation is usually adequate for most industrial applications, local exhaust ventilation is preferred. Have emergency shower and eye wash available.

4 Name: EPY compound page:4/6 Personal protection: Respiratory protection: Hand protection: Eye protection: Skin protection: Remarks: None needed in normal use with proper ventilation. In poorly ventilated areas use vapor respirator. Use suitable protective gloves. Splash-proof eye goggles. In emergency situations, use eye goggles with full face shield. Use protective clothing and shoes. Wash thoroughly with soap and water after using. Danger concentration i work area not applicable. 9. PHISICAL AND CHEMICAL PROPERTIES Form, colour, odour: Thick gray liquid with weak characteristic epoxy odour. Melting point: --- Boiling point: --- Specific gravity: 1,6g/cm 3 Vapour density: --- Vapour pressure: --- Solubility in water and another solvents : Ignition point: In water: non-soluble, in organic solvents: soluble in ketones, esteres, alkohols and aromatic hydrocarbons. >148,8 o C 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Hazardous products of decomposition: The material is chemically stable in normal conditions, Extreme heat and open flame. Amines and amides, oxidizers. Oxides of carbon and toxic fumes.

5 Name: EPY compound page:5/6 11. TOXICOLOGICAL INFORMATION General information: product isn t carcinogenic or potential carcinogenic. Toxicological threats: product can be iritant and allergenic in case of contact in skin and eyes. Potential healt effect: inhalation, ingestion, skin contact, eye contact. Deadly and toxic concentration: LD50 (rat, ingestion): LC50 (rat, inhalation): LD50 (rabbir, skin): 11,5 g/kg n/a >20 g/kg 12. EKOLOGICAL INFORMATION Menace to enviroment: Dangerous for the environment. Can be toxic for aquatic organism, may cause long-term adverse effects in the aquatic environment, Do not discharge into the drains,surface waters and groundwater. Ecotoxity: No data available. 13. DISPOSAL CONSIDERATIONS Waste management: If this resin becomes a waste, it would not be a hazardous waste. Dispose of according to applicable federal, state, and local regulations. Incineration is the preferred method of disposal. Waste no: (recomended) 14. TRANSPORT REGULATION Classification according to ADR: Number UN: 3082 Enviromentally hazardous substancje, liquid, n.o.s. (Bisphenol A Epoxy resin) Class: 9 Packaging group: III Label: 9

6 Name: EPY compound page:6/6 15. REGULATORY INFORMATION The product is classified and labelled in accordance with polish law and UE directives 16. OTHER INFORMATION

7 Name: EPY hardener page:1/6 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade name: EPY hardener General use: Hardening of epoxy resin-mixture Chemical family: Aliphatic amine Manufakturer: Marine Service Jaroszewicz s.c., Szczecin, Poland Deliverer: Marine Service Jaroszewicz s.c., Szczecin, Poland Emergency telephone number: (+48 42) COMPOSITION/INFORMATION ON INGREDIENTS Substance Range % No CAS No EINECS Triethylenetetramine (TETA) HAZARDS IDENTIFICATION Warning symbols: C N Corrosive Dangerous for the environment Hazards identification: R21 R34 Harmful in contact to skin, Causes burns.

8 Name: EPY hardener page:2/6 R43 May cause sensitisation by skin contact. R52/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety symbols: S2 S26 S36/37/39 S45 S61 Protect against children In case of contact with eyes wash immediatelly with large quantity of water. Get immediate medical attention. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environmental. Refer to special instructions / safety data sheets. 4. FIRST AID MEASURES Inhalation: 1. Ensure supply of fresh air. 2. Give oxygen or artificial respiration if needed. Prevent aspiration of vomit. Turn victims head to side. Seek medical advice. Ingestion: 1. Rinse out mouth and give plenty of water or milk to drink. Do not induce vomiting. 2. Summon a doctor immediately. Eye contact: 1. Immediately flush with clean water for at least 15 minutes while gently holding eyelids open. Get medical help as soon as possible. Skin contact: 1. Immediately remove contaminated clothing and excess contaminant. Flush skin with water. Wash thoroughly with soap and warm water. 2..Consult a doctor if skin irritation persists.

9 Name: EPY hardener page:3/6 5. FIRE FIGHTING MEASURES Special exposure hazards arising from the substance: Suitable extinguishing media: Special protective equipment for firefighters: Hazardous products of combustion: Remarks: Product is tha flammable liquid, in the high temperature vapour can be flamable and explosive; vapour and smoke are toxic. Foam. Carbon dioxide. Dry powder. Water spray jet. Firefighters should wear self-contained breathing apparatus and sufficient protective gear (butyl rubber) to prevent allskin and eye contact with this material. Acrid and toxic fumes with organic amines, ammonia, oxides of carbon and nitrogen.. Retain liquids from fire fighting for later disposal. 6. ACCIDENTAL RELEASE MEASURES Spill control:: Protective equipment: Environmental precautions: Cleanup: Avoid personal contact. Eliminate ignition sources. Ventilate area. The personnel should wear protective clothing, safety glasses and protectiwe gloves. Do not discharge into the drains/ surface waters/ groundwater. For large spills, pump to storage/salvage vessels. Soak up residue with an absorbent such as clay, sand, or other suitable material and dispose of properly. Flush area with water to remove trace residue. 7. HANDLING AND STORAGE Handling: Storage: The product should be stored in original packing. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after using and particularly before eating, drinking, smoking. Use protective clothing. Handle in well ventilated work space. Keep container tightly closed. Store in a dry place. Do not store together with another flamable products. Keep away from high temperatures and flames. Keep away from acids and oxidizers.

10 Name: EPY hardener page:4/6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Although good general mechanical ventilation is usually adequate for most industrial applications, local exhaust ventilation is preferred. Have emergency shower and eye wash available. Personal protection: Respiratory protection: Hand protection: Eye protection: Skin protection: Remarks: None needed in normal use with proper ventilation. In poorly ventilated areas use vapor respirator. Use chemical-resistant rubber (for example, neoprene, butyl rubber or nitrile) gloves. Splash-proof eye goggles. In emergency situations, use eye goggles with full face shield. Use protective clothing and shoes. Wash thoroughly with soap and water after using. Explosive limits in air: Lower: n/d Upper: n/d 9. PHISICAL AND CHEMICAL PROPERTIES Form, colour, odour: Melting point: Boiling point: Lightyellow liquid with characteristic amine odour. -35 o C o C Specific gravity: 0,98g/cm 3 Vapour density: 5,04 Vapour pressure: Solubility in water: Flash point: <0,01 hpa completely >148,8 o C

11 Name: EPY hardener page:5/6 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Hazardous products of decomposition: The material is chemically stable in normal conditions, Extreme heat and open flame. Reactive metals, oxidizers, mineral and organic acids, epoxides, ketones Acrid and toxic fumes including organic amines, ammonia, oxides of nitrogen and carbon, nitric acid, nitrosamines. Aldehydes. 11. TOXICOLOGICAL INFORMATION General information: product isn t carcinogenic or potential carcinogenic. Toxicological threats: product corrosive and allergenic in case of contact in skin and eyes, causes burns. Potential healt effect: inhalation, ingestion, skin contact, eye contact. Deadly and toxic concentration: LD50 (rat, ingestion): LC50 (rat, inhalation): LD50 (rabbir, skin): 2500 mg/kg n/a 805 mg/kg Permissible concentration: 30 min.: 20 µm/m 3 24 hours.: 10 µm/m 3 Other chronic effects: It has been generally observed in animal studies that aliphatic amines can cause changes in the lungs and heart. TETA has been found to produce liver and kidney damage and brain congestion in dermally exposed animals. Sensitization has occurred in laboratory animals after repeated exposures. 12. EKOLOGICAL INFORMATION Menace to enviroment: Dangerous for the environment. Can be toxic for aquatic organism, may cause long-term adverse effects in the aquatic environment, Do not discharge into the drains,surface waters and groundwater.

12 Name: EPY hardener page:6/6 Ecotoxity: In relation to fish: In relation to evertebrates: 330 mg/dm 3 /96 godz., 40 mg/dm 3 /48 godz. 13. DISPOSAL CONSIDERATIONS Waste management: If this product becomes a waste, dispose of as hazardous waste. Disposal in an incineration plant in accordance with the regulations of the local authorities. Waste no: * (recomended) 14. TRANSPORT REGULATION Proper shipping name: Triethylenetetramine (TETA) Un number: 2259 Hazard class: 8 Packing group: II Hazard-no: 80 Hazards identification (R): 21, 34, 43, 52/53 Safety identification (S): 1/2, 26, 36/37/39, 45, REGULATORY INFORMATION The product is classified and labelled in accordance with polish law and UE directives. 16. OTHER INFORMATION