SAFETY DATA SHEET APEX HD RINSE ADDITIVE

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Rinse Additive Restrictions on use : Reserved for industrial and professional use. Product dilution information :.18 % -.88 % Company : Ecolab Co. 515 Tomken Road Mississauga, Ontario Canada L4W 2X Emergency health information : (US/Canada), (outside US) Issuing date : 3/3/216 Section: 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. Not a hazardous substance or mixture. GHS Label element Precautionary Statements Precautionary Statements : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. : Prevention: Wash hands thoroughly after handling. Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture / 9

2 Chemical Name CAS-No. Concentration: (%) oxirane, methyl-, polymer with oxirane Sodium Xylenesulfonate Phosphonates glutaraldehyde No hazardous ingredients Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed In case of eye contact In case of skin contact If swallowed If inhaled : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : No special precautions are necessary for first aid responders. : No specific measures identified. : See Section 11 for more detailed information on health effects and symptoms. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus : Use personal protective equipment / 9

3 Specific extinguishing methods Risk of explosion. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Sweep up and shovel into suitable containers for disposal. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Section: 7. HANDLING AND STORAGE Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : C to 5 C Advice on safe handling : Wash hands after handling. For personal protection see section 8. Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers. Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Permissible concentration glutaraldehyde C.1 ppm.41 mg/m3 (c).5 ppm.2 mg/m3 Basis OEL (QUE) CAD AB OEL / 9

4 C.5 ppm CAD BC OEL glutaraldehyde Ceiling.2 ppm NIOSH REL.8 mg/m3 Ceiling.5 ppm ACGIH Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : No personal respiratory protective equipment normally required. : Wash hands before breaks and immediately after handling the product. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No personal respiratory protective equipment normally required. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : solid liquid Colour : dark green colourless Odour : odourless odourless ph : 7., 1 % 8.5 Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure : Not applicable / 9

5 Relative vapour density Relative density Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC Section: 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : None known. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Eyes Skin Ingestion / 9

6 Inhalation Chronic Exposure Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Acute inhalation toxicity : Acute toxicity estimate : > 5, mg/kg : : oxirane, methyl-, polymer with oxirane 4 h LD5 rat: 1 mg/l glutaraldehyde 4 h LC5 rat: >.5 mg/l / 9

7 Acute dermal toxicity : Phosphonates LD5 rabbit: > 1,65 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish Toxicity to daphnia and other aquatic invertebrates : Harmful to aquatic life. : oxirane, methyl-, polymer with oxirane 96 h LC5 Fish: > 1 mg/l : Phosphonates 48 h EC5 Daphnia: 167 mg/l glutaraldehyde 48 h EC5 Daphnia:.35 mg/l Toxicity to algae : Sodium Xylenesulfonate 96 h EC5: 23 mg/l Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re / 9

8 use empty containers. Dispose of in accordance with local, state, and federal regulations. Disposal methods Disposal considerations : Diluted product can be flushed to sanitary sewer. : Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Section: 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR. NPRI : hydrochloric acid methanol The components of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China Inventory of Existing Chemical Substances : / 9

9 Health Health Instability Instability SAFETY DATA SHEET Section: 16. OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 3/3/216 version : 1. Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 9