1 Identification of the substance/mixture and of the company/undertaking. 2 Composition/information on ingredients. 3 Hazards identification

Transcription

1 Page 1/7 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: L323IU Details of the supplier of the safety data sheet Manufacturer/Supplier: Integrated Coating and Seed Technology, Inc Harkins Road Salinas, CA USA Phone: Fax: Further information available from: msds@incotec.com Emergency telephone number: IPR Department Telephone: Fax: Or consult a local intoxication information center. 2 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of non-hazardous substances with the hazardous substances listed below. Dangerous components: Poly(oxy-1,2-ethanediyl), a-isotridecyl-w-hydroxy- 1-10% H318; H411; H303; H401 3 Hazards identification Classification of the substance or mixture GHS07 H319 Causes serious eye irritation. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Information concerning particular hazards for human and environment: Classification system: The product does not have to be labelled due to the calculation procedure of international guidelines. The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. (Contd. on page 2)

2 Page 2/7 Label elements (Contd. of page 1) Labelling according to EU guidelines: Classification system: NFPA ratings (scale 0-4) The product is not subject to identification regulations according to directives on hazardous materials Health = 1 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE 1 1 REACTIVITY 0 Other hazards Results of PBT and vpvb assessment PBT: vpvb: 4 First aid measures Health = 1 Fire = 1 Reactivity = 0 Description of first aid measures General information: After inhalation: After skin contact: After eye contact: After swallowing: 5 Firefighting measures Extinguishing media Suitable extinguishing agents: For safety reasons unsuitable extinguishing agents: Special hazards arising from the substance or mixture Advice for firefighters Protective equipment: 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions: Methods and material for containment and cleaning up: Supply fresh air; consult doctor in case of complaints. Generally the product does not irritate the skin. Rinse opened eye for ten minutes under running water. If symptoms persist consult doctor. CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Not applicable Not required. Do not allow to enter sewers/ surface or ground water. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). (Contd. on page 3)

3 Page 3/7 Reference to other sections 7 Handling and storage No dangerous substances are released. (Contd. of page 2) Handling: Precautions for safe handling Information about protection against explosions and fires: Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and containers: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: Additional information: Exposure controls Personal protective equipment: General protective and hygienic measures: Breathing equipment: Protection of hands: Eye protection: Body protection: 9 Physical and chemical properties The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. The lists that were valid during the creation were used as basis. The usual precautionary measures for handling chemicals should be followed. Not required. Rubber gloves Safety glasses Light weight protective clothing Information on basic physical and chemical properties General Information Appearance: Form: Liquid Color: Off-white Odor: Mild ph-value at 20 C (68 F): 6.9 (Contd. on page 4)

4 Page 4/7 Change in condition Melting point/melting range: Boiling point/boiling range: Flash point: Flammability (solid, gaseous): Auto igniting: Danger of explosion: Explosion limits: Oxidizing properties Vapor pressure at 20 C (68 F): Undetermined. 100 C (212 F) 100 C (212 F) Product is not flammable. Product is not selfigniting. Product does not present an explosion hazard. Product is not oxidative. 23 hpa (17 mm Hg) Density at 20 C (68 F): 1.17 g/cm³ (9.764 lbs/gal) Relative density 1.17 Solubility in / Miscibility with Water: Viscosity: Dynamic at 20 C (68 F): Fully miscible. 700 mpas Solvent content: Organic solvents: 0.0 % VOC content: 0.0 lb/gl 10 Stability and reactivity (Contd. of page 3) Reactivity Chemical stability Thermal decomposition / conditions to be avoided: Possibility of hazardous reactions Incompatible materials: Hazardous decomposition products: 11 Toxicological information No decomposition if used according to specifications. No dangerous reactions known. No dangerous decomposition products known. Information on toxicological effects Acute toxicity: No acute toxic effects known. LD/LC50 values that are relevant for classification: Poly(oxy-1,2-ethanediyl), a-isotridecyl-w-hydroxy- Oral LD50 >2000 mg/kg (Rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritant effect. Sensitization: No sensitizing effects known. (Contd. on page 5)

5 Page 5/7 Subacute to chronic toxicity: Additional toxicological information: Most likely routes of exposure 12 Ecological information (Contd. of page 4) The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information vailable to us. Toxicity Acquatic toxicity: Poly(oxy-1,2-ethanediyl), a-isotridecyl-w-hydroxy- EC50 / 48 h 4.7 mg/l (Daphnia magna) EC50 / 72 h >10 mg/l (Alg) LC50 / 96 h 5-10 mg/l (Fis) 12 mg/l (Zeb) Behavior in environmental systems: Bioaccumulative potential No data available. Ecotoxical effects: Other information: Additional ecological information: General notes: No data available. Results of PBT and vpvb assessment PBT: vpvb: 13 Disposal considerations Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Waste treatment methods Recommendation: Uncleaned packagings: Recommendation: Recommended cleansing agent: 14 Transport information Disposal must be done according to official regulations. Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Disposal must be done according to official regulations. Packaging can be reused or recycled after cleaning. Water, if necessary with cleansing agents. DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - (Contd. on page 6)

6 Page 6/7 Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - UN "Model Regulation": - Special precautions for user 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: (Contd. of page 5) Carcinogenic categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) titanium dioxide 2B NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) titanium dioxide A4 NIOSH-Ca (National Institute for Occupational Safety and Health) titanium dioxide OSHA-Ca (Occupational Safety & Health Administration) (Contd. on page 7)

7 Page 7/7 Product related hazard informations: Chemical safety assessment: (Contd. of page 6) The product is not subject to identification regulations according to directives on hazardous materials. A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases Department issuing : Contact for questions about content: Abbreviations and acronyms: H303 May be harmful if swallowed. H318 Causes serious eye damage. H401 Toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. Incotec Holding BV Enkhuizen, The Netherlands Department ITR msds@incotec.com ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent mortality of exposed population LD50: Lethal dose, 50 percent mortality of tested population EC50: half of the concentration at which the maximum immobilization is reached in the given time. IC50: half of the maximum growth inhibiting concentration in the given time GHS: The Globally Harmonized System of Classification and Labelling of Chemicals * Data compared to the previous version altered. Change into new format / company style.