SAFETY DATA SHEET. Emergency Assistance Chemtrec Serious eye damage/eye irritation

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code 722 Recommended use Recommended restrictions HYDROCHLORIC ACID, SOLUTION, 0.1 N professional, scientific and technical activities: other professional, scientific and technical activities None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name GFS Chemicals, Inc. Address P.O. Box 245 Powell, OH United States Telephone Phone Toll Free Fax Website service@gfschemicals.com Emergency phone number Emergency Assistance Chemtrec Hazard(s) identification Physical hazards Not classified. Health hazards Skin corrosion/irritation Serious eye damage/eye irritation Environmental hazards Not classified. OSHA defined hazards Not classified. Category 2 Category 2 Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Causes skin irritation. Causes serious eye irritation. Wash thoroughly after handling. Wear protective gloves. Wear eye/face protection. IF ON SKIN: Wash with plenty of soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Store away from incompatible materials. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. None known. None. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % WATER HYDROGEN CHLORIDE *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 1 / 7

2 4. First-aid measures Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards Do not use water jet as an extinguisher, as this will spread the fire. None known. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. This product is miscible in water. Should not be released into the environment. Large Spills: Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Neutralize small amounts with sodium bicarbonate or lime and flush to sewer with large amounts of water. Clean up in accordance with all applicable regulations. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). 2 / 7

3 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Type Value HYDROGEN CHLORIDE (CAS ) US. ACGIH Threshold Limit Values Ceiling Type 7 mg/m3 5 ppm Value HYDROGEN CHLORIDE (CAS ) Ceiling US. NIOSH: Pocket Guide to Chemical Hazards Type 2 ppm Value HYDROGEN CHLORIDE (CAS ) Biological limit values Appropriate engineering controls Ceiling 7 mg/m3 5 ppm No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph 1 Clear. Liquid. Aqueous solution. Colorless. Odorless. Melting point/freezing point 32 F (0 C) estimated Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 212 F (100 C) estimated Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure 3 / 7

4 Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Completely miscible. Decomposition temperature Viscosity Other information Density Molecular formula Molecular weight Percent volatile Specific gravity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 1.00 g/cm3 estimated HCl g/mol g/mol 100 % estimated 1.00 estimated This product may react with reducing agents. Material is stable under normal conditions. Hazardous polymerization does not occur. Do not mix with other chemicals. Contact with incompatible materials. Bases. 11. Toxicological information Hydrogen chloride. Information on likely routes of exposure Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Product Prolonged inhalation may be harmful. Causes skin irritation. Causes serious eye irritation. Expected to be a low ingestion hazard. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. HYDROCHLORIC ACID, SOLUTION, 0.1 N (CAS Mixture) Acute Dermal Oral Rat Acute Dermal Rabbit mg/kg mg/l mg/l mg/kg 1449 mg/kg 1108 ppm, 1 Hours 1108 mg/l, 1 Hours 4 / 7

5 Oral Other Rat Rabbit 3124 mg/l, 1 Hours 3124 ppm, 1 Hours 900 mg/kg 1449 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Causes skin irritation. Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes serious eye irritation. May irritate eyes. None known. May cause irritation. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity Product 3 Not classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects. Not classified. Not classified. Prolonged inhalation may be harmful. This product has no known adverse effect on human health. Because of the low ph of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. HYDROCHLORIC ACID, SOLUTION, 0.1 N (CAS Mixture) Aquatic Fish Aquatic Fish Fish * Estimates for product may be based on additional component data not shown. Persistence and degradability None known. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code No data available. No data available. Western mosquitofish (Gambusia affinis) mg/l, 96 hours estimated 282 mg/l, 96 hours No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Dispose of contents/container in accordance with local/regional/national/international regulations. Dilute waste in large quantities of water and flush into sewer connected to wastewater treatment system in compliance with applicable laws and regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. 5 / 7

6 Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Not established. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification Listed LBS Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Chemical name CAS number Reportable quantity HYDROGEN CHLORIDE SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations lbs No Threshold planning quantity Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Threshold planning quantity, lower value Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) Not regulated. Threshold planning quantity, upper value Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR (b) and (f)(2) and Chemical Code Number 6545 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR (c)) DEA Exempt Chemical Mixtures Code Number 20 %WV / 7

7 US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 June No No Disclaimer Revision Information GFS Chemicals cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Product and Company Identification: Product Codes Hazards Identification: US Hazard Categories Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Regulatory Information: United States GHS: Classification 7 / 7