MATERIAL SAFETY DATA SHEET

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1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name Gel Tabs () CAS # Mixture Product Use Condensate drain pan treatment Manufacturer Nu-Calgon 2008 Altom Court St. Louis, MO US Phone: / Emergency Phone: (CHEMTREC) 2. Hazards Identification Emergency overview DANGER Causes severe skin burns and eye damage. Potential short term health effects Routes of exposure Eye, Skin contact,, Ingestion. Eyes Causes chemical burns. May cause blindness. Skin Causes chemical burns. Prolonged inhalation may be harmful. Ingestion Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Target organs Eyes. Skin. Signs and symptoms The product causes burns of eyes, skin and mucous membranes. Potential environmental effects See section Composition/Information on Ingredients Components CAS # Percent Urea Quaternary ammonium compounds, benzyl-c12-18-alkyldimethyl, chlorides First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Obtain medical advice immediately. If inhaled: Remove person to fresh air and keep comfortable for breathing. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. If swallowed: Rinse mouth. Do NOT induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Treat patient symptomatically. Chemical burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Not flammable by WHMIS criteria. #18768 Page: 1 of 6 Issue date 29-August-2014

2 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Water spray. Foam. Dry chemical powder. Carbon dioxide (CO2). None known. During fire, gases hazardous to health may be formed. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of nitrogen. Ammonia. Hydrogen chloride. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Do not discharge into lakes, streams, ponds or public waters. Use water spray to reduce vapours or divert vapour cloud drift. Prevent entry into waterways, sewers, basements or confined areas. Large Spills: Wet down with water and dike for later disposal. Following product recovery, flush area with water. Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. After removal flush contaminated area thoroughly with water. 7. Handling and Storage Handling Storage DANGER -- CORROSIVE Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid prolonged exposure. Do not taste or swallow. Keep container tightly closed. Wear appropriate personal protective equipment. When using, do not eat, drink or smoke. Wash thoroughly after handling. Observe good industrial hygiene practices. Store in a closed container away from incompatible materials. Keep out of the reach of children. 8. Exposure Controls/Personal Protection Exposure limits Engineering controls Personal protective equipment Eye/Face protection Hand protection Skin and body protection Respiratory protection General hygiene considerations Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH. General ventilation normally adequate. Wear safety glasses with side shields (or goggles) and a face shield. Wear appropriate chemical resistant gloves. As required by employer code. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Solid Various Solid until mixed with water to form gel Fresh #18768 Page: 2 of 6 Issue date 29-August-2014

3 Physical state Solid. ph Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Heat of combustion Vapour pressure Vapour density Specific gravity Partition coefficient (n-octanol/water) Solubility (Water) 100 % Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products 10. Stability and Reactivity Do not mix with other chemicals. No dangerous reaction known under conditions of normal use. Stable under recommended storage conditions. Contact with incompatible materials. Strong oxidising agents. May include and are not limited to: Oxides of nitrogen. Hydrogen chloride. Ammonia. 11. Toxicological Information Toxicological data Components Species Test results Quaternary ammonium compounds, benzyl-c12-18-alkyldimethyl, chlorides (CAS ) Acute Dermal LD50 Rat 2000 mg/kg LC50 Oral LD50 Mouse Rat 1420 mg/kg 150 mg/kg 240 mg/kg Urea (CAS ) Acute Dermal LD50 Rabbit mg/kg #18768 Page: 3 of 6 Issue date 29-August-2014

4 Components LC50 Oral LD50 Species Cattle Mouse Rat Sheep Test results 510 mg/kg mg/kg 8471 mg/kg 510 mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitisation Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Causes chemical burns. May cause blindness. Causes chemical burns. Prolonged inhalation may be harmful. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. 12. Ecological Information Ecotoxicity Ecotoxicological data Components Urea (CAS ) Crustacea Aquatic Crustacea Fish See below EC50 EC50 LC50 Species Daphnia Water flea (Daphnia magna) Giant gourami (Colisa fasciata) Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Urea Chemical fate information Test results mg/l, 48 Hours 3910 mg/l, 48 hours 5 mg/l, 96 hours 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. #18768 Page: 4 of 6 Issue date 29-August-2014

5 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: UN number Proper shipping name Hazard class Packing group Marine pollutant Special provisions TDG 14. Transport Information UN1759 Corrosive solid, n.o.s. (Quaternary ammonium compounds, benzyl-c12-18-alkyldimethyl, chlorides) Limited Quantity - Canada III D Regulatory Information Canadian federal regulations WHMIS status WHMIS Classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Controlled Class E - Corrosive Material Inventory status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) Yes *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information LEGEND Severe 4 Serious 3 Moderate 2 Slight 1 Minimal 0 Disclaimer Issue date Effective date Expiry Date HEALTH / 2 FLAMMABILITY 0 PHYSICAL HAZARD 0 PERSONAL PROTECTION X Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 29-August August August-2017 #18768 Page: 5 of 6 Issue date 29-August-2014

6 Prepared by Nu-Calgon Technical Service Phone: (314) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z Standard. #18768 Page: 6 of 6 Issue date 29-August-2014

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