On-purpose Olefins through CATOFIN -CATADIENE Technologies

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1 On-purpose Olefins through CATOFIN -CATADIENE Technologies Global Propylene & Derivatives Summit Sunil Panditrao Technology Manager CB&I

2 Agenda Cracker Feedstock Trends Commercial Routes to Propylene CATOFIN/CATADIENE Technology CATOFIN PDH Technology CATADIENE Technology Conclusions 1

3 Price $/MMBtu Diverging Oil and Gas Prices $30 US Oil & Gas Price History $25 $20 $15 $10 $5 $0 Source: EIA US Oil Price US Gas Price 2

4 ...are Lightening Global Cracker Feedstocks Ethane 2005 Gas Oil 5% Others 2% 27% Naphtha 55% Propane 7% Butane 4% 2010 Gas Oil 3% Naphtha 50% Others 2% Ethane 33% Propane 8% Butane 4% Gas Oil 3% Other 3% Ethane 35% 2015 Naphtha 45% Propane 9% Butane 5% 3

5 Feedstock Determines Product Slate 4

6 Ethylene Market is Healthy, but Global Ethylene Supply & Demand, Capacity Utilization Global utilization moving towards peak in Million Metric Tons Forecast Operating Rate 100% 95% 90% 85% 80% 75% 70% Regional Ethylene Capacity Trends 200 Million Metric Tons by 2020 Regional Capacity Million Metric Tons World Capacity Million Metric Tons World NAM MDE WEP Asia Other (% AAGR = 07-12/12-22) Demand (2.5/3.8) Total Capacity (3.5/3.6) Forecast Operating Rate 2012, IHS Inc. No portion of this presentation may be reproduced, reused, or otherwise distributed in any form without prior written consent. Asia leading the way in capacity additions 65% 60% 55% 2012, IHS Inc. No portion of this presentation may be reproduced, reused, or otherwise distributed in any form without prior written consent. Charts provided with permission of IHS Chemical 5

7 Co-product Capacity not Keeping Pace Propylene Production from Steam Crackers Million Metric Tons P/E Ratio 42% Forecast 40% Americas Europe, CIS, & Baltics Middle East / Africa Total Asia 38% 36% 34% 32% 30% 28% 26% 24% , IHS Inc. No portion of this presentation may be reproduced, reused, or otherwise distributed in any form without prior written consent. Charts provided with permission of IHS Chemical Cracker co-product capacity growth relatively flat Refinery FCC units represent the other conventional source of propylene Flat gasoline demand growth a constraint there 6

8 Co-product Pricing Strengthening 600 Ethylene, Propylene, Butadiene Prices (2000 = 100) Ethylene Propylene Butadiene Average annual prices provided by Global Data 7

9 Propylene Growth Regions and Usage Patterns Announced Propane Dehydrogenation Production Capacity of Propylene 8

10 Commercial Routes to Propylene Steam Cracker FCC Traditional Technologies MTO Propane Dehydrogenation PDH Propylene New Technologies Olefins Conversion Technology OCT 9 9

11 On-Purpose Propylene Filling the Gap 20% of the global propylene market by 2016 Propylene Market View Million MetricTons Forecast Percent Propane Dehydro Metathesis Others Olefin Cracking Methanol-to-Olefins HS FCC % Total Production , IHS Inc. No portion of this presentation may be reproduced, reused, or otherwise distributed in any form without prior written consent. 4 Charts provided with permission of IHS Chemical 10

12 Price $/ton Favorable Feed/Product Pricing Differential Propane/Propylene Differential USGC Source: ICIS Information provided from ICIS Pricing, a member of the Reed Elsevier plc group 11

13 Propylene Selectivity Comparison 100 By-product Technologies On-purpose Technologies % Propylene Yield

14 What is CATOFIN /CATADIENE Technology? Proven technology platform licensed by CB&I for singlestage, fixed bed dehydrogenation of paraffins CATOFIN for propane and isobutane dehydrogenation Propane to Propylene (C 3 CATOFIN) Isobutane to Isobutylene (ic 4 CATOFIN) CATADIENE for n-butane dehydrogenation n-butane to Butadiene and Butylenes Catalyst supplied by Clariant 13

15 Why CATOFIN Propane Dehydrogenation (PDH)? CATOFIN technology is a high selectivity process for propylene production propane propylene + hydrogen < 1.15 ton propane required per ton propylene Fixed bed reactor system Largest single train capacities (up to 850 kta) Highest reliability (> 97%) 14 CATOFIN units licensed to date Several operating units are integrated with polypropylene Total propylene capacity: > 7000 kta 14

16 CATOFIN Process Flowsheet Charge Heater Air Heater Air Reactor on Purge Reactor on Stream Reactor on Reheat Waste Heat Boiler (WHB) Fresh Propane Steam Byproduct Recovery/Fuel gas Cooler Low Temp. Section Propylene Product Cooler Flash Drum Product Compressor Propane Recycle 15

17 Flowsheet Options for CATOFIN Plant Low CAPEX design Optimal for areas of the world where low-cost energy is available Heat-pumped product splitter Common waste heat boiler for hot exhaust streams Low OPEX design Patented Low-energy Scheme Optimization of energy use around product compressor and reboilers Optimization of air heating Best application for high energy cost regions 16

18 Continuous CATOFIN Improvements Latest CATOFIN catalyst breakthrough in commercial operation 2 3% increase in olefin selectivity 5 10% energy savings Up to $30 million profit boost over conventional catalyst units Improves return on investment 17

19 What About Butadiene? New butadiene extraction opportunities limited due to tightening raw C 4 supply from liquids crackers Few liquids crackers remain without BD extraction from crude C 4 s Butadiene a key profit driver for Asian crackers Recent pricing exceeded $US 4,000 per ton Supply limitations continue to be forecasted on back of strong demand for synthetic rubbers Asian Ethylene, Propylene, Butadiene Prices (US$/t) Ethylene Propylene Butadiene Average annual prices provided by Global Data 18

20 Price $/ton Butadiene/Butane Pricing Butane mix BD USGC BD NE Asia Source: ICIS /10/06 2/22/08 7/6/09 11/18/10 4/1/12 8/14/13 Information provided from ICIS Pricing, a member of the Reed Elsevier plc group 19

21 Commercial Routes to Butadiene Steam Cracker By-product Technologies Butylene Oxidative Dehydrogenation Butadiene Butane Dehydrogenation On-purpose Technologies 20

22 Butadiene Block Flow Scheme CATADIENE one-step dehydrogenation of butane to butadiene n-butane + Heat n-butenes + Butadiene + Hydrogen Butene recovery for OCT or Alkylation feed n-butene / n-butane Recycle n-butane CATADIENE Butadiene n-butenes n-butane Butadiene Extraction Butadiene 21

23 CATADIENE On-purpose BD Technology Only on-purpose technology available for production of 1,3 butadiene and/or n-butenes by dehydrogenation of n-butane First CATADIENE dehydrogenation unit started up in 1944 to meet demand for synthetic rubber during World War II 19 more units built in 1950s to 1980s Most plants discontinued in 1970s/1980s due to abundance of butadiene as co-product from naphtha crackers Three plants remain in operation in Russia Decade Units Built Olefins Capacity KMTA Pre s s s After Units currently operating

24 Conclusions Proven higher selectivity of the process with the implementation of HGM Large design capacities are possible to take advantage of the economy of scale CATOFIN technology improved flowsheets meet local utility constraints at various locations around the world CATOFIN productivity and profitability maximized with latest improvements CATADIENE proven technology for on-purpose butadiene production 23

25 "This paper and Program may contain confidential or proprietary information. The information, observations, and data presented in this paper and Program are intended for educational purposes only and do not identify, analyze, evaluate, or apply to actual, specific engineering or operating designs, applications, or processes. The comments and opinions are those of the author and not CB&I, are based on available information, and in all cases reference shall be made to the actual wording and meaning of applicable codes and standards. The use of or reliance on any information, observations, or data provided is solely at your own risk." 24

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