: EKP-50 Weld Cleaning Solution

Transcription

1 EKP-50 Weld Cleaning Solution Safety Data Sheet SECTION 1: Identification of the substance/mixture and of the company/undertaking Supersedes: Version: Product identifier Product form Product name. Product code : Mixture : EKP-50 Weld Cleaning Solution : EKP-102-1, EKP102-5 & EKP Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial use only Details of the supplier of the safety data sheet Metal Science Technologies Pty Ltd 43 Shelley Road, Moruya NSW, 2537, Australia T info@metalscience.com.au 1.4. Emergency telephone number Emergency number: or SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS classification Skin Corr. 1C H314 Eye Dam. 1 H Label elements GHS labeling : Hazard pictograms (GHS) Signal word (GHS) Hazard statements (GHS) Precautionary statements (GHS) : Danger GHS05 : H314 - Causes severe skin burns and eye damage : P264 - Wash exposed skin thoroughly after handling P280 - Wear protective gloves, protective clothing, eye protection, face protection P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER/doctor/ P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations

2 2.3. Other hazards Other hazards not contributing to the classification : None Unknown acute toxicity (GHS) No data available SECTION 3: Composition/information on ingredients 3.1. Substances Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification Water (CAS No) <45 Not classified Phosphoric Acid, 85% w/w (CAS No) <55 Skin Corr. 1B, H314 Eye Dam. 1, H318 Citric Acid (CAS No) <5 Eye Irrit. 2A, H319 Proprietary Ingredient N/A <10 Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. : Assure fresh air breathing. Allow the victim to rest. Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after eye contact : Causes severe skin burns and eye damage. : Causes serious eye damage Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection.

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures 6.2. Environmental precautions : Safety glasses. Protective clothing. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe mist, vapours, spray. : Wash exposed skin thoroughly after handling. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep container closed when not in use. Incompatible products Incompatible materials : Strong bases. Strong acids. : Sources of ignition. Direct sunlight Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ingredient Phosphoric Acid, 85% w/w ( ) TWA (mg/m³) 1 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation. : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing.

4 Respiratory protection Other information : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : Colourless. : None. : Soluble in water Other information SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates: Corrosive vapours Chemical stability Not established.

5 10.3. Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases. metals Hazardous decomposition products Phosphorus oxides. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Phosphoric Acid, 85% w/w ( ) LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after eye contact mg/kg : Causes severe skin burns and eye damage. : Causes serious eye damage. : Based on available data, the classification criteria are not met. : Causes serious eye damage. SECTION 12: Ecological information Toxicity Phosphoric Acid, 85% w/w ( ) LC50 fishes 1 LC50 other aquatic organisms 1 LC50 fish 2 LC50 other aquatic organisms 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms mg/l (96 h; Pisces; PURE SUBSTANCE) mg/l (96 h; Protozoa; PURE SUBSTANCE) mg/l (Pisces; PURE SUBSTANCE) 240 mg/l (PURE SUBSTANCE) 138 ppm (24 h; Gambusia affinis; PURE SUBSTANCE) ,96 h; Protozoa; PURE SUBSTANCE 240 mg/l (PURE SUBSTANCE)

6 12.2. Persistence and degradability Phosphoric Acid, <55% v/v Persistence and degradability Not established. Phosphoric Acid, 85% w/w ( ) Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. No (test)data on mobility of the components of the mixture available Bioaccumulative potential Phosphoric Acid, <55% v/v Bioaccumulative potential Not established. Phosphoric Acid, 85% w/w ( ) Bioaccumulative potential Not bioaccumulative Mobility in soil Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment UN number UN-No. : 3264 NA no. : UN UN proper shipping name Proper Shipping Name Department of Transportation Hazard Classes Hazard labels : Phosphoric acid solution : 8 - Class 8 - Corrosive material 49 CFR : 8 - Corrosive substances Packing group : III - Minor Danger

7 14.3. Additional information Other information : No supplementary information available. Overland transport Transport by sea Vessel Stowage Location : Air transport Quantity Limitations Passenger aircraft/rail (49 CFR ) Quantity Limitations Cargo aircraft only (49 CFR ) SECTION 15: Regulatory information A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel. : 5 L : 60 L Health, safety and environmental regulations and legislations Labeling according to 67/548/EEC Directive Poison Schedule Classification Risk Phrases Safety Phrases Product Name 6: Poison Substances with a moderate potential for causing harm, the extent of which can be reduced through the use of distinctive packaging with strong warnings and safety directions on the label. C; Corrosive R34: Causes Burns S1/2: Keep locked up and out of the reach of children. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). EKP-50 Weld Cleaning Solution SECTION 16: Other information Other information None Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Corr. 1C Skin corrosion/irritation, Category 1C H314 Causes severe skin burns and eye damage H318 Causes serious eye damage

8 NFPA health hazard NFPA fire hazard NFPA reactivity : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given : 0 Minimal Hazard : 0 Minimal Hazard : H SDS US (GHS HazCom 2012) Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and Sunland Chemical assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his or her application.