Safety Data Sheet 1. PRODUCT IDENTIFICATION

Transcription

1 Safety Data Sheet Safety Data Sheet (in compliance with Regulation (EC) 1907/2006, Regulation (EC) 1272/2008 and Regulation (EC) 453/2010) Date Issued: 22 June 2009 Document Number: 21301MS Date Revised: 09 April 2012 Revision Number: 2 1. PRODUCT IDENTIFICATION Trade Name (as labeled): Tin (IV) Oxide Chemical Name/Classification: Tin (IV) Oxide Product Identifier (Part/Item Number): 21301, U.N. Number: U.N. Dangerous Goods Classification: Recommended Use: Preparation of dental materials Restrictions on Use: For professional use only Manufacturer/Supplier Name: Sultan Healthcare Manufacturer/Supplier Address: 411 Hackensack Avenue, 9 th Floor Hackensack, NJ Manufacturer/Supplier Telephone Number: or (Product Information) Emergency Contact Telephone Number: (INFOTRAC) (Outside the United States Call Collect) address: customer.service@sultanhc.com 2. HAZARD(s) IDENTIFICATION Hazard/Danger Classification (Regulation EC) No. 1272/2008 [CLP]: Health Environmental Physical EU Classification (67/548/EEC as amended): EU Risk (R) and Safety (S) Phrases: Refer to Section 16 for the full text of the EU Classifications and R Phrases. Tin (IV) Oxide Page 1 of 7

2 3. COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Components C.A.S. # EC# Tin (IV) Oxide / IUPAC Name Substance Classification WT % tin dioxide Not classified as hazardous FIRST-AID MEASURES Routes of Exposure Eye Skin Inhalation First Aid Instructions Do not rub eyes. Flush eyes with water, holding the eyelids apart. Get medical attention if irritation persists. Wash exposed area with soap and water. Get medical attention if irritation persists. Remove contaminated clothing and launder before reuse. Remove to fresh air. Get medical attention if symptoms develop, or irritation persists. Ingestion Most important symptoms of exposure Other Get medical attention if symptoms develop. Dust may cause abrasive eye and skin irritation. Prolonged inhalation may result in stannosis, a mild benign form of pneumoconiosis. known. Note to Physicians (Treatment, Testing, and Monitoring): Treatment of overexposure should be directed at the control of symptoms and clinical conditions. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Use media appropriate for the surrounding fire. Fire Fighting Procedures: Cool fire exposed containers and structures with water. Specific Hazards Arising from the Chemical: expected Precautions for Fire Fighters: Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for all fires involving chemicals. Recommended Protective Equipment for Fire Fighters: EYES/FACE SKIN RESPIRATORY THERMAL Tin (IV) Oxide Page 2 of 7

3 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, PPE and Emergency Procedures: For large spills, wear protective clothing, eye protection and gloves. For small spills, wear eye protection and gloves. Environmental Precautions: Prevent spill from entering sewers and water courses. Report releases as required by local and national authorities. Methods and Materials for Containment and Clean-up: Collect material and place in appropriate containers for disposal. Avoid generating dust. Recommended Personal Protective Equipment for Containment and Clean-up: EYES/FACE SKIN RESPIRATORY THERMAL 7. HANDLING AND STORAGE Precautions for Safe Handing: Avoid contact with the eyes, and skin. Use with adequate ventilation. Avoid breathing dust. Wash thoroughly after handling. Keep containers closed when not in use. Empty containers retain product residues and can be hazardous. Follow all SDS precautions when handling empty containers. Conditions for Safe Storage: Store in a cool dry well ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits: Tin Oxide United States 2 mg/m3 TWA OSHA PEL (As tin) 2 mg/m3 TWA ACGIH TLV Germany United Kingdom France Spain Italy European Union Tin (IV) Oxide Page 3 of 7

4 Biological Exposure Limits: Established Appropriate Engineering Controls: Use with adequate general or local exhaust ventilation to maintain exposure levels below the occupational exposure limits. Individual Protection Measures (PPE) Specific Eye/face Protection: Safety glasses or safety goggles recommended. Specific Skin Protection: Wear impervious gloves are recommended for prolonged skin contact.. Specific Respiratory Protection: required under normal use conditions. Specific Thermal Hazards: Not applicable Recommended Personal Protective Equipment: EYES/FACE SKIN RESPIRATORY THERMAL Environmental Exposure Controls: required for normal use. General Hygiene Considerations and Work Practices: Avoid contact with the eyes, skin and clothing. Wash thoroughly with soap and water after handling. Protective Measures During Repair and Maintenance of Contaminated Equipment: Not applicable for product. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White to slightly grey powder Explosive limits: Not applicable Odor: Odorless Vapor pressure: Not applicable Odor threshold: Not applicable Vapor density: Not applicable ph: Neutral Specific Gravity: (H 2 O = 1) 6.95 Melting/freezing point: >2552 F (>1400 C) Solubility: Insoluble Initial boiling point and range: Sublimes Partition coefficient: n- octanol/water: Not available Flash point: Not flammable Auto-ignition temperature: Not available Evaporation rate: Not applicable Decomposition temperature: Not available Flammability: Not flammable Viscosity: Not available Tin (IV) Oxide Page 4 of 7

5 Explosive Properties: Not applicable Oxidizing Properties: 10. STABILITY AND REACTIVITY Reactivity: No unusual reactivity. Chemical Stability: Stable. Possibility of Hazardous Reactions: Hazardous reactions are unlikely. Conditions to Avoid:. Incompatible materials: Avoid strong oxidizing agents and magnesium Hazardous Decomposition Products:. 11. TOXICOLOGICAL INFORMATION Potential Health Effects: Eyes: Dust may cause mechanical eye irritation. Skin: Dust may cause skin irritation. Ingestion: Considered non toxic by ingestion. Inhalation: Dust may cause eye and skin irritation. Inhalation may result in stannosis, a mild benign form of pneumoconiosis. Chronic Health Effects: Long term exposure to dust may result in stannosis, a mild benign form of pneumoconiosis. Carcinogenicity: This product is not listed as carcinogens by OSHA, IARC, ACGIH, NTP or EU Directives. Mutagenicity: No mutagenic data available. Medical Conditions Aggravated by Exposure: known. Acute Toxicity Data: Tin Oxide: Oral rat LD50 >20,000 mg/kg Reproductive Toxicity Data: No reproductive or teratogenic data available. Specific Target Organ Toxicity (STOT): Single Exposure: known. Repeated Exposure: Prolonged exposure to tin(iv) oxide dust & fumes can produce the benign form of pneumoconiosis termed stannosis. The condition develops after at least 3-5 yr of exposure & is characterized by small dense shadows in the pulmonary X-ray picture without impairment of pulmonary function. Fibrosis of the lung does not develop, provided that other agents such as silica are not present. Tin (IV) Oxide Page 5 of 7

6 12. ECOLOGICAL INFORMATION Toxicity: No data available. Persistence and Degradability: No data available. Bio-accumulative Potential: No data available. Mobility in Soil: No data available. Other Adverse Effects: No data available. Results of PBT/vPvB Assessment: Not required. 13. DISPOSAL CONSIDERATIONS Regulations: Dispose in accordance with local and national environmental regulations. Properties (Physical/Chemical) Affecting Disposal: known. Waste Treatment Recommendations: needed for normal anticipated use. 14. TRANSPORT INFORMATION UN Number: ADR/RID: IMDG: IATA: DOT: UN proper shipping name: Transport hazard class(es): ADR/RID: Not regulated for transport IMDG: Not regulated for transport IATA: Not regulated for transport DOT: Not regulated for transport ADR/RID: IMDG: IATA: DOT: Packaging group: ADR/RID: IMDG: IATA: DOT: Environmental hazards: ADR/RID: No IMDG: No IATA: No DOT: No Special precautions for user: Not applicable U.S. Federal Regulations 15. REGULATORY INFORMATION Comprehensive Environmental Response and Liability Act of 1980 (CERCLA): This product is not subject to Tin (IV) Oxide Page 6 of 7

7 CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. Toxic Substances Control Act (TSCA): All of the ingredients in this product are listed on the EPA TSCA Inventory. OSHA Hazard Classification: Hazardous (Exposure limit) Clean Water Act (CWA): Not Listed Clean Air Act (CAA): Not Listed Superfund Amendments and Reauthorization Act (SARA) Title III Information: SARA Section 311/312 (40 CFR 370) Hazard Categories: Immediate Hazard: No Pressure Hazard: No Delayed Hazard: No Reactivity Hazard: No Fire Hazard: No This product contains the following toxic chemical(s) subject to reporting requirements of SARA Section 313 (40 CFR 372): Components C.A.S. # WT % State Regulations California: This product contains the following chemicals(s) known to the State of California to cause cancer, birth defects or reproductive harm: Components C.A.S. # WT % International Regulations Canadian Workplace Hazardous Materials Information System (WHMIS): Not a controlled product. EU REACH: The substances in this product comply with the EU REACH regulation as applicable. 16. OTHER INFORMATION Full text of Classification abbreviations used in Section 2 and 3: Date of SDS Preparation/Revision: April 09, 2012 Data Sources: US NLM ChemID Plus and HSDB, Substance SDS for components, IUCLID Dataset EU Chemical Bureau, ESIS, Country websites for occupational exposure limits. Tin (IV) Oxide Page 7 of 7