RAID OUTDOOR ANT NEST DESTROYER 1 (REG. NO P.C.P. ACT)

Transcription

1 1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : RAID OUTDOOR ANT NEST DESTROYER 1 (REG. NO Use of the : Insecticide Substance/Mixture Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone number : 24 Hour Transport & Medical Emergency Phone (866) Hour International Emergency Phone (952) Hour Canadian Transport Emergency Phone (CANUTEC) (613) HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : opaque / aerosol / solvent-like Immediate Concerns : Caution MAY CAUSE IRRITATION. Avoid contact with skin, eyes and clothing. Keep away from heat, sparks and flame. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Avoid breathing vapors, mist or gas. Contents under pressure. Also harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause eye irritation. Skin : May cause skin reactions in rare cases. May cause systemic effects. Harmful if absorbed through skin. Inhalation : May be harmful if inhaled. 1/9

2 May cause nose, throat, and lung irritation. Ingestion : Harmful if swallowed. May cause irritation to mouth, throat and stomach. Aggravated Medical Condition : None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR or the Canadian Controlled Products Regulations are listed in this table: Chemical Name CAS-No. Weight percent Isobutane Naphtha (petroleum), hydrotreated heavy Propane n-octyl bicycloheptene dicarboximide Permethrin D-trans allethrin For additional information on product ingredients, see 4. FIRST AID MEASURES Eye contact : Remove contact lenses. Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention immediately. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. If not breathing, give artificial respiration. Get medical attention immediately. Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. 2/9

3 5. FIREFIGHTING MEASURES Suitable extinguishing media Specific hazards during firefighting : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. : Aerosol Product - Containers may rocket or explode in heat of fire. Do not allow run-off from fire fighting to enter drains or water courses. Further information : Fight fire from maximum distance or protected area. Cool and use caution when approaching or handling fire-exposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes. Flash point : < -7 C < 19.4 F Note: Propellant Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available NFPA Classification : NFPA Level 1 Aerosol 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Wear personal protective equipment. Environmental precautions : Do not flush into surface water or sanitary sewer system. Use appropriate containment to avoid environmental contamination. Outside of normal use, avoid release to the environment. Methods for cleaning up : If damage occurs to aerosol can: Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13). Use only non-sparking equipment. Clean residue from spill site. 3/9

4 7. HANDLING AND STORAGE Handling Advice on safe handling : Avoid contact with skin, eyes and clothing. Do not puncture or incinerate. Do not enter places where used or stored until adequately ventilated. Avoid breathing vapors, mist or gas. For personal protection see section 8. Do not spray toward face. Do not use in areas without adequate ventilation. Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Smoking, eating and drinking should be prohibited in the application area. Advice on protection against fire and explosion Storage Requirements for storage areas and containers : Keep away from heat and sources of ignition. : Keep away from food, drink and animal feedingstuffs. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Nonstandard Basis units Isobutane ,000 ppm - ACGIH TWA Naphtha ,200 mg/m3 171 ppm - SUPPLIER (petroleum), hydrotreated heavy Propane ,000 ppm - ACGIH TWA Personal protective equipment 4/9

5 Respiratory protection Industrial setting : Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Do not spray in enclosed areas. Household setting : Use only with adequate ventilation. Hand protection : Rubber gloves Eye protection Industrial setting : Safety glasses with side-shields Household setting : Avoid contact with eyes. Skin and body protection : No special requirements. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Smoking, eating and drinking should be prohibited in the application area. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol Color : opaque Odor : solvent-like ph : not applicable Melting point : not determined Boiling point : no data available Flash point : < -7 C < 19.4 F Propellant Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : not applicable 5/9

6 Density : g/cm3 at 21 C Water solubility : partly soluble Partition coefficient: n- octanol/water : not applicable Viscosity, kinematic : not applicable 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Do not mix with oxidizing agents. Hazardous decomposition products : Thermal decomposition can lead to release of irritating gases and vapours. Hazardous reactions : Stable under recommended storage conditions. 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : LC50 estimated > 5,000 mg/l Acute dermal toxicity : LD50 estimated > 2,000 mg/kg Chronic effects Carcinogenicity : no data available 6/9

7 Mutagenicity : None Anticipated Reproductive effects : no data available Teratogenicity : no data available Sensitisation : Not known to be a sensitizer. 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Ecotoxicity effects : Toxic to bees. 13. DISPOSAL CONSIDERATIONS PESTICIDAL WASTE: Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN number 1950 Packaging group: Note: None. Limited quantities derogation may be applicable to this product, please check transport documents. Sea transport IMDG: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2 7/9

8 UN number: 1950 Packaging group: None. EmS: F-D, S-U Note: Limited quantities derogation may be applicable to this product, please check transport documents. Air transport ICAO/IATA: Proper shipping name UN 1950 AEROSOLS, Flammable, 2.1 Class: 2.1 UN/ID No.: UN 1950 Packaging group: Note: 15. REGULATORY INFORMATION None. SC Johnson typically does not ship products via air, therefore it has not been determined if the product container meets current IATA/ICAO package criteria. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). California Prop. 65 : : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 2 Flammability 4 Reactivity 0 NFPA Ratings Health 2 8/9

9 Fire 4 Reactivity 0 Special - Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 9/9