Production of Biofuels using thyssenkrupp Gasification Technologies

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1 Production of Biofuels using thyssenkrupp Gasification Technologies 12 th Feb, 2016 Dr. Dobrin Toporov Mathias Sonntag (presenter) thyssenkrupp Industrial Solutions

2 1. The Company Profile 2. The Gasification Portfolio 3. Technological Routes 4. Summary & Outlook 2 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

3 Working for our customers Sector examples Mastering challenges together Minerals & Mining Construction Aerospace Automotive Chemicals Energy 3 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

4 thyssenkrupp Business Areas Key indicators fiscal year 2014/ Components Technology Elevator Technology Industrial Solutions Materials Services Steel Americas Steel Europe Sales [million ] EBIT² [million ] Employees 6,753 7,208 6,256 14,254 1,773 8, (138) ,627 51,335 19,388 20,226 3,725 27,601 thyssenkruppag Sales: 42,778 [million ] EBIT adj.²: 1,676 [million ] Employees: 154, Continuing operations (after reclassification of Steel Americas) 2. Adjusted before consolidation 4 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

5 Diversified industrial group: Our business areas Transition from UHDE to ThyssenKrupp Industrial Solutions (TKIS) Components Technology Elevator Technology Industrial Solutions Materials Services Steel Americas Steel Europe UHDE chemical plants POLYSIUS cement plants, coal mills FÖRDERTECHNIK escavators, conveyor belts 5 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

6 Industrial Solutions The new dimension in Plant Engineering Business Area Business Unit Marine Systems Process Technologies Industrial Solutions Resource Technologies System Engineering Regional Organisations Submarines Surface Vessels Services II Americas Fertilizer/ Coke Plant Technologies Chemicals/Oil & Gas Services V MENA Mining Cement Services I Europe/CIS III India Asia Pacific Assembly Systems Car Body Technology Lightweight Solutions Forming Dies Testing Solutions Services VI Sub-Saharan Africa 6 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

7 Industrial Solutions Joint EPC-S business model with aspiration to grow Engineering (E) Procurement (P) Construction (C) Services (S) ~45% Engineers Employees wordwide ~30% Others ~25% Technicians Leading technologies & engineering skills Global network & efficiency Local know-how & presence Reliability & customer proximity 7 12.Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

8 From the idea to operation of a chemical plant Research phase Bid phase Project implementation phase Operation and service phase Concept development and assessment Execution of R&D projects Acquisition of technologies / companies Project development / market study Feasibility study Project financing Licence award or procurement Basic / detail engineering Procurement / inspection / shipping Project execution Construction Commissioning Training of operating personnel Plant maintenance and operation Materials management and spare parts Plant optimisation and upgrading 8 12.Feb 2016 Biofuels Mathias Sonntag

9 Process Technologies at a glance Fertilizer/Coke Plant Technologies Chemicals/Oil & Gas Services Ammonia/Urea Hydrogen/Nitrates Coke plant technologies Technical services Electrolysis Gasification technology De-Hydrogenation Oil & Gas Polymers Technical services Plant optimization Spare parts management Repair Operation & Maintenance Consulting/Studies Training Life-cycle services 9 12.Feb 2016 Biofuels Mathias Sonntag

10 Process Technologies More than 2,000 plants around the globe engineered, built and brought into operation Fertilizers 130 plants Nitric acid Refineries Aromatics 185 plants 380 plants 75 plants Hydrogen, Ammonia, Methanol 120 plants Organic chemicals, Petrochemicals 375 plants Plastics, Synthetic fibers 115 plants Polyester, Polyamides 400 plants Electrolysis 150 plants Coke plants Gasification Industrial plants 500 plants 100 plants 150 plants Feb 2016 Biofuels Mathias Sonntag

11 Gasification Technologies Technologies from ThyssenKrupp 550 C C C Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

12 TKIS Proprietary Gasification Technologies t > ash-melting temperature Steam Boiler Gasifier Chamber t < ash-melting temperature Gasifier Chamb er Water Quench Gasifier system Pressure: up to 40 bar PSG PDQ PRENFLO Entrained-Flow Pressure: up to 40 bar HTW Fluidised Bed Pressure: up to 30 bar Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

13 Biomass-to-Biofuels Technology Routes Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

14 Gasification Biomass Pre-treatment Routes Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

15 Gasification Technology Portfolio Broad flexibility for the entire Syngas product slate Feedstocks Pretreatment Gasification Gas Treatment Synthesis Brown Coal Waste Biomass Hard Coal Petcoke Grinding, Milling Torrefaction Milling HTW PRENFLO TM PDQ PRENFLO TM PSG Purification of Syngas (CO + H 2 ) Methanol (MTO, MTG) Ammonia (Urea) F-T (Diesel, Lubes) H 2 SNG IGCC (Power) Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

16 Concepts & Projects/Plants Example 1: Entrained Flow PRENFLO PDQ Integrated Process Chain for the Production of Synthetic Biofuels Feedstocks Pretreatment Gasification Gas Treatment Synthesis Wood Straw, etc. Coal Torrefaction CO-shift AGR Gasel TM Fischer- Tropsch (F-T) Synthesis and product upgrading Petcoke Milling Bio-diesel, Bio-kerosene Liquid Residues PRENFLO TM PDQ - The BioTfueL demonstration project objectives are to develop, demonstrate and commercialize an integrated B-XTL chain for the production of biodiesel and biokerosene - Joint project by IFP/Axens, Total, TKIS, Sofiproteol and CEA Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

17 The BioTfueL Project EPC Phase has started Dunkirk (Total) site overview Milling and Storage Gasification Unit Gas treatment - EPC contracts signed and effective in September Comissioning starts in EPC for Gasification and Overall site integration by TKIS Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

18 Concepts & Projects/Plants Example 2: Fluidised Bed HTW Integrated Process Chain for the Production of Methanol Feedstocks Pretreatment Gasification Gas Treatment Synthesis Domestic Forest Residues Grinding, Drying, Pelletising CO-Shift Methanol Synthesis Fuel Grade Methanol AGR HTW Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

19 Solid Feedstocks operated in HTW Gasification Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

20 HTW Plants for a wide Range of Feedstocks High-ash coal HTW-Plant Berrenrath/Germany Source: RWE Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

21 HTW Plants for a wide Range of Feedstocks Biomass HTW Syngas Anlage Kemira Oy Oulu / Finland 30 t/h Peat 300 t/d NH3 Start: Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

22 HTW Plants for a wide Range of Feedstocks Municipal waste HTW-Precon-Gasification Niihama / Japan 48 t/d Municipal Waste Start: 1999 Sumitomo Heavy Industries Ltd Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

23 Advantages of thyssentrupp HTW Gasification Technology Simple design lowers maintainance costs Taylor-made gasifier size according the project requirements Flexible feedstock (coal, biomass, waste etc) Oxygen-blown or Air-blown design possible Proven and reliable technology Processing of high-ash Indian coal (< 45wt% ash) possible Feb 2016 Biofuels Dr. Dobrin Toporov / Mathias Sonntag

24 The integrated Solution Typical Process Chain for an End-to-End Coal-to-Gasoline Solution MASTER LICENSE & INTEGRATED BASIC ENGINEERING for the entire process chain by Feb 2016 Biofuels Mathias Sonntag

25 Summary Gasification is a proven technology, a vast number of gasifiers are operating since decades successfully on commercial basis Gasification allows flexibility in feedstock and polygeneration of products, even for biomass projects Gasification is environmental friendly TK Industrial Solutions has more than 70 years of experience in gasification based on 8 different gasification technologies received more than 100 contract awards for gasifiers has proven single sourcing capability is a process oriented EPC contractor and not only licensor has built the world s largest solid fuel based, single train IGCC has built more than 2,000 plants worldwide Feb 2016 Biofuels Mathias Sonntag

26 Summary TK Industrial Solutions Gasifiers robust & commercially proven PRENFLO entrained-flow technology more than years of operation at commercial scale at Elcogas plant in Puertollano, Spain HTW TM fluidised-bed technology more than years of operation at commercial scale at RWE s plant in Berrenrath, Germany Feb 2016 Biofuels Mathias Sonntag

27 Summary Site -Seeing: Plants built by TK Industrial Solutions Koppers-Totzek gasification Modderfontein, South Africa coal-to-ammonia/fertilisers HTW coal gasification Berrenrath, Germany coal-to-methanol GE (Texaco) coal gasification Oberhausen, Germany coal-to-hydrogen & oxochemicals PRENFLO coal gasification Fürtenhausen, Germany coal-to-methanol HTW MSW gasification Niihama, Japan waste-to-energy PRENFLO IGCC Puertollano, Spain petcoke/coal-to-power Feb 2016 Biofuels Mathias Sonntag

28 Thank You for Your Attention! for further questions: Mathias Sonntag Senior Sales Manager Gasification Technology Division ThyssenKrupp Industrial Solutions AG

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