The Latest in Odor Control Issues and Solutions

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1 The Latest in Odor Control Issues and Solutions FWEA Air Quality Seminar Feb 2017 Philip Wolstenholme, P.E. 1

2 Agenda Vapor Phase Technologies Comparison of Technologies Collect before Treating Dispersion 2

3 Air Treatment Technologies Activated Carbon Chemical Scrubbing Biotrickling Filter Bulk Media Biofilter Ionization 3

4 Activated Carbon and other dry media 4

5 Activated Carbon Adsorber Clean Air Fan Foul Air

6 Activated Carbon Extruded Carbon Granular Carbon Adsorption in pores 6

7 Various Vessel Configurations

8 Mobile Carbon Vessel

9 Pros/Cons of Carbon Can treat most odors Minimal maintenance Stack discharge increases dilution No chemical usage High-capacity carbons available Chemically impregnated media for polishing Heavily loaded carbons can produce foul odors Removal of media can be difficult

10 Chemical Scrubbing 10

11 Typical Packed Bed Wet Scrubber Countercurrent Flow Key use factors: Very common control technology Very effective Somewhat complicated process Caustic Soda Bleach Treated Air Metering Pumps Plant Drain NaOCl NaOH ORP ph Spray Nozzle Sump Mist Eliminator Packed Bed Foul Air 11

12 Sulfide Species as a Function of ph H S 2 HS - = S 60 Percent ph

13 Single Stage Scrubber

14 Pros/Cons of Chemical Scrubbing Can treat most odors but needs significant maintenance Fast Response to changing conditions Stack discharge increases dilution Chemical requirement adds capital and operating costs and operator safety issues

15 Packed Bed Chemical Scrubbers Low profile scrubbers Two-stage scrubbing

16 Biotrickling Filter aka Bioscrubber aka Biotower aka Biofilter

17 Typical Biotrickling Filters 17

18 Sacramento Regional Wastewater Treatment Plant Bioscrubber, 1982 Bioscrubber Carbon Towers

19 Use a Trickling Filter as a Biotrickling Filter

20 Biofiltration 20

21 Typical Bulk Media Biofilter Sprinkler system Treated Air Foul air Bulk media Blower Drip irrigation Pea gravel Coarse Gravel Header pipe Distribution pipes Liner Leachate collection (to drain or sump for recirculation) 21

22 Biofilter in concrete vessel 22

23 Enable Access to Media 23

24 Small Biofilter at Siphon 24

25 Coronado, CA Soil Biofilter 25

26 Colorado Park Biofilter 26

27 Pros/Cons of Biological treatment Familiar biology to WWTP operators Sustainable solution No chemicals required Operating cost not a function of concentration New higher capacity media Biofiltration can blend with landscaping Biology can be upset Biofiltration needs large area Biofiltration can blend with landscaping

28 Ionization (a.k.a. Electro-Oxygenated Odor Control non-thermal plasma, bipolar ionization, cold plasma, ozonation, free radicals) 28

29 Electro-Oxygenated Odor Control Creates free radicals, ionized particles Very short particle life Can treat supply or exhaust air In-situ or ex-situ Inappropriate for high concentrations 29

30 In-situ Exhaust Ionizers In-situ treatment places ionizers in odorous air stream Two known vendors: IonO2x and Schenk (APP) Explosion-proof may be required Corrosion potential 30

31 Ex-situ Exhaust Ionizers Ex-situ places ionizers outside odorous air stream Two known vendors: Uniqair and Aerox 31

32 Ex-Situ Supply Ionizers Ex-situ supply systems place ionizers in clean outside supply side airstream Two known vendors: Aerisa and Transtech

33 Photocatalytic ionization + Carbon Produces free radicals using UV light Second stage carbon Used in supply or exhaust air 33

34 Hydroxyl Radical Fogging Creates hydroxyl radicals Injected into unoccupied unventilated wet well or channel Also provides grease removal Be aware of ozone corrosion issues

35 Pros/Cons of Electro-Oxygenated Systems Contact Material 304 SS Maximum temperature 170 deg F Upstream dust removal/particulate filter required Some humidity in air stream preferred Maximum modular capacity 60,000 cfm Emits some ozone; ozone sensor can provide control Small footprint Low equipment and operating cost VOC reduction somewhat established Minimal speciated compound data Has sometimes failed to perform Pilot testing essential to confirm odor reduction 35

36 Technology Comparison Carbon Adsorption Chemical Scrubber Footprint Complexity Capital Cost Operating Cost Medium Simple Medium Medium to Large Medium to Small Complex Medium to Large Biofiltration Large Medium Large Low Biotrickling Filter Medium to Small Simple Medium to Large Medium Low Ionization Small Medium Medium Low 36

37 Rule of Thumb Selection based on Average Hydrogen Sulfide Concentration Low Concentration < 10 ppm Medium Concentration ppm High Concentration >100 ppm Low Flow <10,000 cfm Adsorber Ionization Adsorber Biofilter Biofilter Medium Flow 10-50,000 cfm Adsorber Ionization Biofilter Biotrickling filter Chemical scrubber Biofilter Biotrickling filter High Flow >50,000 cfm Adsorber Biofilter Chemical scrubber Biofilter Biotrickling filter Chemical scrubber Biotrickling filter 37

38 Two-stage Odor Control Chemical Scrubbers Activated Carbon + Many such combinations

39 Wastewater Plant Odor Sources-Ranking Headworks Solids Handling Primary Clarifiers Aeration Vessels Secondary Clarifiers Disinfection 39

40 But before you treat, Collect the odors! 40

41 Covers and Enclosures 41

42 Extreme Covering Methods

43 Collect before Treating -Covered Process Infiltration Air Aluminum Cover Negative Pressure Exhaust Air to Foul Air treatment 43

44 Rooms: To contain odors exhaust must be greater than supply Infiltration Air 12,000 CFM Exhaust Air to Foul Air Treatment or Atmosphere 10,000 CFM NEGATIVE PRESSURE ROOM Infiltration Air Infiltration Air 44

45 Fugitive emissions can defeat an odor strategy The Design Total Emission = 20,000 cfm.ppb 1, ppb =20,000 cfm.ppb 1,000 cfm 99.9% Removal 20 PPM 45

46 Fugitive emissions can defeat an odor strategy The Potential Reality 1, ppb = 20,000 cfm.ppb Total Emission = 1,020,000 cfm.ppb 50 20,000 ppb =10 6 cfm.ppb 1,000 cfm 99.9% Removal 20 PPM 46

47 Fugitive emissions can defeat an odor strategy The DESIGN Discharged Air cfm x ppb Emission Rate cfm.ppb Dilution to Fence Line Offsite Impact 1,000 x 20 = 20,000 / 500 [stack] = 40 The REALITY 1,000 x 20 = 20,000 / 500 [stack] = x 20,000 = 1,000,000 / 20 [tank] = 50,000 The IMPACT 51 times greater 1,000 times greater 47

48 Sequence of Design: Pump Station Control Foul Air Treatment of occupied wet well 1. Determine wet well size 2. Calculate Supply air flow (S) 3. Increase by approx 10% for exhaust air flow (E=S+10%) 4. Calculate air from influent (I) 5. Total air flow (V = E + I) 6. Calculate H 2 S concentration 7. Select appropriate control system 8. Non-occupied: ignore outside supply air 48

49 Balancing Odor Control Solutions Chemical dosing Fan and odor control Force Main (Full) Gravity Sewer Pump Station Wet Well

50 After Treatment-Dispersion 50

51 Optimum Dispersion with High Stack 51

52 Disguised Dispersion 52

53 A simple wall can be effective nasally and visually 53

54 Questions? 54

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