Dry Acid Special. Issue Date: 03-Oct-2007 Revision Date: July 15, 2015 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Dry Acid Special Issue Date: 03-Oct-2007 Revision Date: July 15, 2015 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # UN/ID No Dry Acid Special CCH-003 UN1759 Recommended use of the chemical and restrictions on use Recommended Use Cleaning agent. Details of the supplier of the safety data sheet Supplier Address Cotey Chemical Corporation 4410 M.L.K. Blvd. Lubbock, TX Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance White to off-white crystals Physical State Solid Odor Odorless Classification Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 1 Sub-category C Serious eye damage/eye irritation Category 1 Signal Word Warning Hazard Statements Harmful if swallowed Causes skin burns and eye damage Page 1 / 8

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Immediately call a poison center or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Take off contaminated clothing and wash it before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Sulfamic acid >50 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES General Advice Eye Contact Skin Contact Inhalation Provide this SDS to medical personnel for treatment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a poison center or doctor/physician. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. Page 2 / 8

3 Ingestion IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. Most important symptoms and effects Symptoms Harmful if swallowed. Causes skin burns and eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Suitable Extinguishing Media Carbon dioxide (CO2). Water spray or fog. Dry chemical. Foam. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Corrosive material. 5. FIRE-FIGHTING MEASURES Hazardous Combustion Products Smoke, fumes or vapors, and oxides of carbon. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Wash small spills to sanitary sewer. For large spills-recover and segregate product for reuse; shovel product into approved containers for disposal. Dispose of contents/container to an approved waste disposal plant. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves/protective clothing and eye/face protection. Wash face, hands, and any exposed skin thoroughly after handling. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Protect container from physical damage. Protect from extreme temperatures. Page 3 / 8

4 Incompatible Materials Strong oxidizers. Strong acids. hypochlorous acid. Hypochlorites. Cyanides. Sulfides. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Showers. Eyewash stations. Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Goggles or safety glasses with side shields. Neoprene or rubber gloves with cuffs. Coveralls, apron or other equipment should be worn to minimize skin contact. None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, NIOSH approved respirator must be worn. Respiratory protection must be provided in accordance with OSHA regulations (29 CFR ) or European Standard EN 149, as applicable. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Solid Appearance White to off-white crystals Odor Odorless Color White to off white Odor Threshold Property Values Remarks Method ph <1 Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity >2.0 (Water = 1) Water Solubility Appreciable Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Page 4 / 8

5 Reactivity Not reactive under normal conditions. Chemical Stability Stable. Possibility of Hazardous Reactions None under normal processing. 10. STABILITY AND REACTIVITY Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Avoid generating airborne dust. Incompatible Materials Strong oxidizers. Strong acids. hypochlorous acid. Hypochlorites. Cyanides. Sulfides. Hazardous Decomposition Products Decomposition will not occur if handled and stored properly. In case of fire, oxides of carbon, hydrocarbons, fumes or vapors, and smoke may be produced. Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes eye damage. Causes skin burns. Do not inhale. Harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sulfamic acid = 1450 mg/kg ( Rat ) - - Sodium Chloride = 3 g/kg ( Rat ) > 10 g/kg ( Rabbit ) > 42 g/m 3 ( Rat ) 1 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Page 5 / 8

6 Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Sulfamic acid 14.2: 96 h Pimephales promelas mg/l LC50 static Sodium Chloride : 96 h Lepomis macrochirus mg/l LC50 flow-through 12946: 96 h Lepomis macrochirus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 static 7050: 96 h Pimephales promelas mg/l LC50 semi-static : 96 h Pimephales promelas mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 flow-through Crustacea 1000: 48 h Daphnia magna mg/l EC : 48 h Daphnia magna mg/l EC50 Static Persistence/Degradability. Bioaccumulation. Mobility Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1759 Proper Shipping Name Corrosive Solid, n.o.s. (Sulfamic Acid) Hazard Class 8 Packing Group III IATA UN/ID No UN1759 Page 6 / 8

7 Proper Shipping Name Corrosive Solid, n.o.s. (Sulfamic Acid) Hazard Class 8 Packing Group III IMDG UN/ID No UN1759 Proper Shipping Name Corrosive Solid, n.o.s. (Sulfamic Acid) Hazard Class 8 Packing Group III International Inventories 15. REGULATORY INFORMATION Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Sulfamic acid Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Sulfamic acid X Page 7 / 8

8 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards 1 Flammability Flammability 0 Instability Physical Hazards 0 Special Hazards Personal Protection Issue Date: 03-Oct-2007 Revision Date: July 15, 2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8