Changing US Crude Oil Imports are Driving Refinery Upgrades, Creating Opportunities

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1 1 Changing US Crude Oil Imports are Driving Refinery Upgrades, Creating Opportunities Christopher Buehler, Ph.D., P.E. Praveen Gunaseelan, Ph.D. Crude Oil Quality Association October 22, 2009 Meeting Houston, Texas 00M25HS CB01

2 2 Overview US Crude Oil Imports: Trends & Drivers Infrastructure Developments Impact on US Refining Opportunities for Gasification Summary

3 3 US Crude Oil Imports: Trends & Drivers

4 4 US Consumption, Production & Import Trends Chart based on Energy Information Administration (EIA) data. Petroleum products supplied is used as an approximation for consumption.

5 5 US Crude Oil Import Trends by Country of Origin Chart based on EIA data.

6 6 Origin of US Crude Oil Imports Average import flows for Nov in thousands of barrels per day Figure from vesseltrax.com, Dec

7 7 Historical US Imports of Crude Oil by Area of Entry Chart based on EIA data.

8 8 US Crude Oil Imports in 2007 by Area of Entry From Canada by Pipeline Saudi Arabia Iraq Ecuador Nigeria Saudi Arabia Venezuela Import flows in thousands of barrels per day 5515 Mexico Venezuela Saudi Arabia Nigeria Figure based on EIA data, July 2008.

9 9 Lower Quality of Crude Oil Feedstock Crude oil becoming: Heavier More sour Increasingly stringent sulfur specifications for refined fuels Refining heavy sour crude oils consumes more energy and hydrogen Chart based on EIA data.

10 10 Drivers for Increasing Crude Oil Imports to US Declining domestic oil production Long term US demand growth for products Foreign producers looking to monetize reserves Heavy light price differentials Expanding infrastructure for imports US refinery expansions

11 Infrastructure Developments 11

12 12 Key Infrastructure for Canadian Crude Imports Existing, Under Construction & Planned Existing (2.3 MBPD) Enbridge System (1.7 MBPD) KM Trans Mountain (300 KBPD) KM Express (280 KBPD) Ongoing Projects (+1.1 MBPD) TCPL Keystone (435 KBPD, 2009) TCPL Keystone Ext. (155 KBPD, 2010) Enbridge Clipper (450 KBPD, 2010) Proposed Projects Enbridge Southern Access Extension Enbridge Southern Lights (Diluent) Enbridge Gateway Project data from Canadian Association of Petroleum Producers (CAPP) Forecast, June Figure from Alberta Energy Resources Conservation Board, June 2009.

13 13 Existing and Planned Infrastructure for Crude Imports into US Gulf Coast TOPS Planned Terminals Figure adapted vesseltrax.com, Dec

14 Impact on US Refining 14

15 15 Crude Oil Price Comparison Chart based on EIA data.

16 16 Western Canada Oil Sands & Conventional Crude Oil Production Chart from CAPP Forecast, June 2009.

17 Major Ongoing and Proposed US Refinery Expansion Projects based on Heavy Crude BP, Whiting $3.8B, On stream 2011 (+)260 Kbpd bitumen capacity 102 Kbpd Coker 2x100 MMSCFD H 2 Plants Gas Oil Hydrotreater Sulfur Recovery Hyperion, South Dakota $8 10 B 400 Kbpd Greenfield Refinery COP/Encana JV, Wood River Phase 1, $1.9B, 2010 (+)60 Kbpd bitumen capacity 65 Kbpd Coker Phase 2, $2B, 2013 (+)100 Kbpd bitumen Crude, Coker Expansion COP/Encana JV, Borger 3 Phases, $1.4B, 2012 (+)75 Kbpd bitumen capacity 25 Kbpd Coker Debottlenecking Crude Expansion 17 Marathon, Detroit HOUP $2.2B, On stream 2012 Q3 (+) 115 Kbpd (+80 Kbpd bitumen) 28 Kbpd Coker 12 Kbpd Coker NHT 33 Kbpd DHT 35 MMSCFD H2 2x140 Sulfur Plant BP, Husky JV Toledo Refinery $2.5B, On stream Kbpd (+120 Kbpd heavy) Coker Expansion Marathon, Garyville $3.5B, On stream 2009 Q4 (+)180 Kbpd heavy crude CDU, Coker, Hydrocracker Kero HT, Naphtha HT, Sulfur Plant Motiva, Port Arthur $7B, On stream KBPD Refinery Expansion

18 18 Refinery Configuration Changes required for Processing of DilBit New Capacity Required Diluent Recovery Crude Distillation (Atmospheric/Vacuum) Bitumen Upgrading Delayed Coking / Resid Hydroprocessing Hydrocracking / Solvent Deasphalting Sulfur Plants Expanded Capacity Required Naphtha Hydrotreating Distillate Hydrotreating Optional Capacity Gasification of Residuals (Petroleum Coke or Asphaltenes)

19 19 Typical Refinery Configuration Changes Required for Processing DilBit Recovered Diluent DilBit Diluent Recovery Bitumen Crude Crude Distillation Naphtha Hydrotreater Gas Oil Hydrotreater Catalytic Reformer FCC Unit Gasoline Hydrotreater Legend Distillate Hydrotreater Existing Unit Expanded Unit Vacuum Distillation Heavy Gas Oil Hydrocracker New Unit Optional Unit Delayed Coker Pet-Coke H 2 Gasifier Sulfur Plant Power, Steam

20 20 Opportunities for Integrated Gasification Units Drivers Increased volume of residuals (pet coke, asphaltenes) Increasing requirements for Hydrogen, Power, Steam, Heat Favorable economics vs. NG Efficiency, waste reduction Refinery integration synergies Potential for CO 2 capture Process Residual oxidation to Syngas Syngas H 2, power Heat Recovery Steam Power Major Technology Providers Shell GE ConocoPhillips Sasol/Lurgi Examples of Integrated Gasifiers at US Refineries Valero, Delaware City, DE ExxonMobil, Baytown, TX Frontier, El Dorado, KS

21 21 Summary Increasing US reliance on foreign crude oil Domestic declines, long term product demand growth, discounts for heavy crude, infrastructure developments Decreasing quality of crude imports Canada is leading exporter of crude to US Investments in oil sands production, pipelines US refinery expansions based on heavy Canadian crude Extensive refinery modifications needed Crude distillation capacity Bitumen upgrading capacity: primary, secondary Hydrotreating, sulfur recovery, etc. Opportunities for integrated gasification of residuals

22 22 Questions? Christopher Buehler, Ph.D., P.E. Praveen Gunaseelan, Ph.D. Phone: (832) Phone: (713) energy.com

23 23 References 1. Gunaseelan, P. and C. Buehler, Changing US crude imports are driving refinery upgrades, Oil & Gas J. 2009, Aug Gunaseelan, P. and C. Buehler, U.S. crude oil imports Recent trends and their impact on refining, 2009 NPRA National Meeting, San Antonio, TX, March 24, Energy Information Administration, Official Petroleum Statistics, US Dept. of Energy, Oct Map of average daily crude oil imports to the US in Nov. 2007, vesseltrax.com, Dec Map of average daily crude oil imports to the US Gulf Coast in Nov. 2007, vesseltrax.com, Dec Crude Oil Forecast, Markets, and Pipeline Expansions, Canadian Association of Petroleum Producers, June Alberta's Energy Reserves 2008 and Supply/Demand Outlook , Figure 2.16, page 2 26, Energy Resources Conservation Board, June Website for Marathon Detroit Heavy Oil Upgrader Project (HOUP). 9. BP press release on Whiting refinery modernization project. 10. Information on Wood River and Borger refinery expansions, Encana website. 11. Website for Marathon Garyville refinery expansion.

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