Safety Data Sheet. Not classified as hazardous

Transcription

1 Page: 1 of 1. Identification GHS Product Identifier Product Code Product Type Company Name Address Telephone/Fax Number Emergency phone number Recommended use of the chemical and restrictions on use 2. Hazard Identification GHS classification of the substance/mixture Signal Word (s) Hazard Statement (s) General Precautionary Statement (s) Pictogram (s) SUPERNOVA 20SC Fungicide 204 NUL 2206 Group 11 Fungicide Crop Care Australasia Pty Ltd (ABN ) Unit 17/16 Metroplex Avenue Murarrie Queensland 4172 Australia Tel: Fax: (24hr Australia) For the control of various diseases of avocados, grapes, mangoes, passionfruit, cucurbits, poppies, potatoes and tomatoes as per the Directions for Use table on the label. This Safety Data Sheet describes the properties of the concentrated product. The physical properties and the assessments may not apply to the properties of the product once it has been diluted for application. AC1 Hazardous to the Aquatic Environment - Long-Term Hazard: Category 1 WARNING H410 Very toxic to aquatic life with long lasting effects. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. Environment, The below pictograms are GHS Hazard symbols for workplace use only. See SECTION 14 for Dangerous Goods information. Poisons Schedule S under the GHS criteria. 3. Composition/information on ingredients Chemical Characterization Ingredients 4. First-aid measures Ingestion Liquid Name CAS Proportion Azoxystrobin g/l Propylene glycol % fatty alcohol % ethoxylate Other ingredients (considered non-hazardous) Balance Remove affected person to fresh air until recovered. If symptoms develop or persist, seek medical advice. Rinse mouth and then drink plenty of water. Obtain medical advice. Wash affected areas thoroughly with soap and water. Remove contaminated clothing and launder before re-use.

2 Page: 2 of Eye contact First Aid Facilities Advice to Doctor. Fire-fighting measures Suitable extinguishing media Special Protective Equipment for fire fighters 6. Accidental release measures Spills & Disposal Personal Protection 7. Handling and storage Precautions for Safe Handling Conditions for safe storage, including any incompatabilities If irritation persists, seek medical advice. If in eyes, hold eyelids open and wash with copious amounts of water for at least 1 minutes. Seek medical advice immediately. If poisoning occurs, contact a doctor or the Poisons Information Centre (Australia) on Treat symptomatically. Water fog, foam, carbon dioxide or dry chemical. Breathable air apparatus may have to be worn if material is involved in fires especially in confined spaces. STOP FIRE WATER FROM ENTERING DRAINS OR WATER BODIES. Contain spill and absorb with clay, sand, soil or proprietary absorbent (such as vermiculite). Collect in sealed open top containers for disposal. For appropriate personal protective equipment (PPE), refer Section 8. Do NOT contaminate dams, rivers or streams, or any other water bodies with pesticide or used containers. Store in the closed, original container in a dry, cool well ventilated area out of direct sunlight. Keep container tightly sealed and do not store with seed, fertilisers or foodstuffs. Always read the label and any attached leaflet before use. SUPERNOVA 20SC is extremely phytotoxic to certain apple varieties and extreme care must be used to prevent injury to apple trees. DO NOT spray SUPERNOVA 20SC where spray drift may reach apple trees. DO NOT use spray equipment that has been previously used to apply SUPERNOVA 20SC to spray apple trees. Even trace amounts can cause unacceptable damage. 8. Exposure controls/personal protection Occupational exposure limit values Appropriate engineering controls Respiratory Protection Personal Protective Equipment Hygiene Measures Requirements Concerning Special Training An exposure standard has been set for propylene glycol at (TWA) 474 mg/m3. Handle in well ventilated areas, generally natural ventilation is adequate. Do not inhale spray mist. 9. Physical and chemical properties Liquid Form Appearance Solubility in Water Specific Gravity When opening the container, preparing spray and using the prepared spray wear cotton overalls buttoned to the neck and wrist and a washable hat, elbow-length PVC gloves and goggles. After use and before eating, drinking or smoking, wash hands, arms and face thoroughly with soap and water. After each day's use, wash contaminated clothing and safety equipment. Check State or Territory regulations that require people who use pesticides in their job or business to have training in the application of the materials. Off-white liquid Disperses in water. 1.09

3 Page: 3 of ph Partition Coefficient: n-octanol/water Flammability 7-8 in 1% solution Kow Log P is 2. for 20 C Not flammable 10. Stability and reactivity Stable under normal conditions. Chemical Stability Hazardous Decomposition Products Hazardous Polymerization 11. Toxicological Information Toxicology Information Oral Dermal Ingestion Eye Sensitisation Carcinogenicity Reproductive Toxicity Serious eye damage/irritation Mutagenicity corrosion/irritation 12. Ecological information Persistence and degradability Known Harmful Effects on the Environment Other Precautions Environmental Protection Fish Daphnia Combustion or thermal decomposition will evolve toxic and irritant vapours. Hazardous polymerisation is not possible. No harmful effects are expected if the precautions on the label and this MSDS are followed. LD0 (rat >2,000 mg/kg for the formulated product LD0 (rat) >4,000 mg/kg for the formulated product LC0 (rat) (4hr) mg/l for the formulated product (maximum attainable - aerosol concentration) Early symptoms, shortly after exposure, are mainly gastro intestinal (nausea, diarrhoea, vomiting and abdominal pain). Not a likely route of exposure. Mildly irritating to the skin. A mild eye irritant. Product is not a skin sensitiser. The weight of the evidence is that azoxystrobin technical is not carcinogenic. Data indicates no teratogenic effects. Mild eye irritant. Data indicates no mutagenic effects. Mild skin irritant. The Australian Acceptable Daily Intake (ADI) for azoxystrobin for a human is 0.1 mg/kg/day, set for the public for daily, lifetime exposure. This is based on the NOEL of 10 mg/kg/day, the level determined to show no effects during long term exposure for the most sensitive indicators and the most sensitive species. (Ref: Comm. Dept. of Health and Ageing, Office of Chemical Safety, 'ADI List', December 2014). Rapidly degrades in soil. The product is a marine pollutant for sea transport. Harmful to fish. Do not contaminate streams, rivers or waterways with the chemical or used containers. Spray drift can cause damage, read the label for more information. Toxic to fish. LC0 (96hr) for rainbow trout is 0.47 mg/l. LC0 (48hr) for daphnia magna is 0.23 mg/l for azoxystrobin.

4 Page: 4 of Algae Other Organisms 13. Disposal considerations Product Disposal Container Disposal 14. Transport information Transport Information Storage and Transport UN Number (Sea Transport) IMO Class/Packing Group IMO Marine Pollutant IMO Proper Shipping Name EC0 for Selenastrum capricornutum is 0.36 mg/l. Bees: Not toxic to bees. LD0 >200 µg/bee. LD0 for bobwhite quail is >1,000 mg/kg for azoxystrobin On site disposal of the concentrated product is not acceptable. Ideally, the product should be used for its intended purpose. If there is a need to dispose of the product, approach local authorities who hold periodic collections of unwanted chemicals. Do not use this container for any other purpose. Triple rinse containers, add rinsate to the spray tank, then offer the container for recycling/reconditioning, or puncture top, sides and bottom and dispose of in landfill in accordance with local regulations. If recycling, replace cap and return clean containers to recycler or designated collection point. If not recycling, break, crush or puncture and deliver empty packaging for appropriate disposal at an approved waste management facility. If an approved waste management facility is not available, bury the empty packaging 00mm below the surface in a disposal pit specifically marked and set up for this purpose clear of waterways, desirable vegetation and tree roots, in compliance with relevant local, state or territory government regulations. Empty containers and product should not be burnt. drummuster is the national program for the collection and recycling of empty, cleaned, non returnable crop production and on-farm animal health chemical containers. If the label on your container carries the drummuster symbol, triple rinse the container, ring your local Council, and offer the container for collection in the program. It is good practice not to transport agricultural chemical products with food, food related materials and animal feedstuffs. Considered non dangerous for road and rail transport (in packaging, including IBCs not greater than 3000 Lt each) by the Australian Code for the Transport of Dangerous Goods by Road and Rail. Ref: ADG7; SP No. AU01. For bulk shipments as Class 9, use UN 3082, HazChem code 2Z Class 9 1. Regulatory information S Poisons Schedule Packaging & Labelling 16. Date of preparation or last revision of SDS Contact Person/Point Marine Pollutant ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains azoxystrobin) CAUTION KEEP OUT OF REACH OF CHILDREN READ SAFETY DIRECTIONS BEFORE OPENING OR USING This product is registered with the Australian Pesticides and Veterinary Medicines Authority (APVMA). APVMA product number: Revised 08/03/2016 This SDS replaces document dated May Normal Hours: Mrs Kathleen Marsh Phone: After Hours: Shift Supervisor Phone:

5 Page: of Revisions Highlighted The SDS was reviewed to include GHS requirements....end Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code of the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd. Copyright in the layout, presentation and appearance of each Infosafe MSDS displayed is the intellectual property of Acohs Pty Ltd. The compilation of MSDS's displayed is the intellectual property of Acohs Pty Ltd. Copying of any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose of sale or licence or for inclusion as part of a collection of MSDS without the express written consent of Acohs Pty Ltd.