Material Safety Data Sheet

Transcription

1 MSDS-VJMP11INKCY950-01US 1. Product and Company Identification Product name Solvent Pigment Ink VJ-MP11INK-CY950 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKCY950-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients CAS No. Weight % Remark Pigment Polymer Listed 1-10 Ethylene glycol monobutyl ether acetate Ethyl lactate First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage.

2 MSDS-VJMP11INKCY950-01US Release Date 2012/4/16 Page 2/4 Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: In case of small quantity, absorb the leakage with dry soil, sand, and incombustible-material or collect it into a container that can be covered tightly for later disposal. In case of small quantity, use clean and anti-static tools to collect absorbed materials. In case of large quantity, prevent the spills from spreading with embankment to lead them to a safe place for collection. Collect the material into a disposal container by sucking up or sweeping up. Methods and equipment for containment and cleaning up: All devices to handle spills must be grounded. If not dangerous, stop the leak. Small amount: Prevent the material from wetting by rain. Cover with dry soil, dry sand, or non-combustibles and store under a plastic sheet cover to avoid scattering and wetting. Cleansing the contaminated area thoroughly with water after removal. Prevention measures for secondary accidents: Removes all ignition sources promptly. (Prohibition of smoking, sparks, and flames in the surrounding area) Prevent flowing into drain, sewage, basement, and closed area. 7. Handling and Storage Handling Technical measures: Provide ventilation system and Use necessary personal protective equipment as described in "Section 8. Exposure Controls and Personal Protection". Local and general ventilation: Provide local ventilations and a full ventilation system as described in "Section 8. Exposure Controls and Personal Protection". Precautions for safe handling: Prohibit the use of heat, sparks, and fire in the surrounding area. Wash hands thoroughly after handling. Avoid swallowing. Avoid the contact with the skin. Prevents Handling of incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage Precautionary Statements Technical measures: The storage facility should be designed with fire-proof construction and beams should use a noncombustible material. The roof of a storage facility should be made of a non-combustible material and use metals or other lightweight non-combustible materials. No ceiling should be installed. The storage floor should be protected from water penetration, or should have water-proof construction. The storage floor should have penetration-proof construction against dangerous goods and be inclined adequately. A proper sump should be provided to catch any spills. The storage facility should be provided with necessary lighting, lighting equipment, and ventilator to store and handle dangerous goods. Incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage conditions: Store away from oxidants. Have containers keep away from direct sunlight and heat. Store in a wellventilated and cool place keeping container tightly closed. Store locked up. Material used in packaging/containers: Use containers prescribed in the "UN Transport Regulations". 8. Exposure Controls and Personal Protection Level/Exposure limit: ACGIH OSHA Ethylene glycol monobutyl ether acetate 20ppm not establish Engineering controls: Use Local exhaust ventilation. Personal protective equipment Respiratory protection: Respirator to avoid breathing organic solvent vapor. Hand protection: Ware chemical resistant gloves. Eye protection: Use safety glasses or goggles. Skin and body protection: Wear working clothes. Specific hygiene measures: Wash hands thoroughly after handling. 9. Physical and Chemical Properties Appearance physical state: Liquid Color: Blue Odor: Mild odor ph: No data

3 MSDS-VJMP11INKCY950-01US Release Date 2012/4/16 Page 3/4 Flash point: 63 C (Tag closed cup) Auto ignition temperature : >340 C (Ethylene glycol monobutyl ether acetate) Specific gravity: g/cm 3 (25 C) VOC: g/L Vapor density: No information available. Solubility in water: Insoluble in water. 10. Stability and Reactivity Stability: Stable. Possibility of hazardous reaction: Acids and oxidizing agents. Conditions to avoid: Extremely high temperature. Incompatible substances or mixtures: Not occur. Hazardous decomposition products: No data. 11. Toxicological Information Acute toxicity: No information available. Mutagenicity: No information available. Other toxicity information: No information available. 12. Ecological Information Environmental hazards: This product is partially soluble in water. Treat using the best available techniques to avoid environmental contamination. Ecotoxicity: No information available. 13. Disposal Considerations Residual waste: For disposal, conform with the standards provided by related laws and local public bodies. When commissioning the disposal to a disposal company, notify the danger and toxicity thoroughly to the company. Contaminated container and packaging: Recycle containers after cleansing, or carry out the disposal under the related laws and regulations and the standards of the local governments. In case of disposal of empty containers, remove the content thoroughly. 14. Transportation Information Not classified as hazardous for transport. Follow all regulations in your country. 15. Regulatory Information All ingredients in this product are listed on the TSCA Inventory. Follow all regulations in your country. SARA Title Ⅲ: This product contain the following toxic chemicals subject to the reporting requirements of section 313 of title Ⅲ of the superfund amendment and reauthorization act of 1986 and 40 CFR Part 372. Substance or Category Content (%) Glycol ether Glycol ether is contained as a part of Ethylene glycol monobutyl ether acetate. California Prop.65: None of the chemicals in this product are listed on the state of California to cause cancer, birth defects or other reproductive harm. 16. Other Information HMIS (the Hazardous Material Identification System) Rating Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: H 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe NFPA (National Fire Protection Association) Rating Health: 1

4 MSDS-VJMP11INKCY950-01US Release Date 2012/4/16 Page 4/4 Flammability: 2 Instability: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe This Material Safety Data Sheet contains health, safety, and environmental information. It does not replace any precautionary language or use and disposal information which accompanies the product. The information contained herein is believed to be accurate at the time of preparation, but should only be used as a guide. It is subject to revision from time to time. MUTOH does not warrant the completeness or accuracy of the information contained herein.

5 MSDS-VJMP11INKMA950-01US 1. Product and Company Identification Product name Solvent Pigment Ink VJ-MP11INK-MA950 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKMA950-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients CAS No. Weight % Remark Pigment Listed 1-10 Polymer Listed 1-10 Ethylene glycol monobutyl ether acetate Ethyl lactate First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage.

6 MSDS-VJMP11INKMA950-01US Release Date 2012/4/16 Page 2/4 Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: In case of small quantity, absorb the leakage with dry soil, sand, and incombustible-material or collect it into a container that can be covered tightly for later disposal. In case of small quantity, use clean and anti-static tools to collect absorbed materials. In case of large quantity, prevent the spills from spreading with embankment to lead them to a safe place for collection. Collect the material into a disposal container by sucking up or sweeping up. Methods and equipment for containment and cleaning up: All devices to handle spills must be grounded. If not dangerous, stop the leak. Small amount: Prevent the material from wetting by rain. Cover with dry soil, dry sand, or non-combustibles and store under a plastic sheet cover to avoid scattering and wetting. Cleansing the contaminated area thoroughly with water after removal. Prevention measures for secondary accidents: Removes all ignition sources promptly. (Prohibition of smoking, sparks, and flames in the surrounding area) Prevent flowing into drain, sewage, basement, and closed area. 7. Handling and Storage Handling Technical measures: Provide ventilation system and Use necessary personal protective equipment as described in "Section 8. Exposure Controls and Personal Protection". Local and general ventilation: Provide local ventilations and a full ventilation system as described in "Section 8. Exposure Controls and Personal Protection". Precautions for safe handling: Prohibit the use of heat, sparks, and fire in the surrounding area. Wash hands thoroughly after handling. Avoid swallowing. Avoid the contact with the skin. Prevents Handling of incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage Precautionary Statements Technical measures: The storage facility should be designed with fire-proof construction and beams should use a noncombustible material. The roof of a storage facility should be made of a non-combustible material and use metals or other lightweight non-combustible materials. No ceiling should be installed. The storage floor should be protected from water penetration, or should have water-proof construction. The storage floor should have penetration-proof construction against dangerous goods and be inclined adequately. A proper sump should be provided to catch any spills. The storage facility should be provided with necessary lighting, lighting equipment, and ventilator to store and handle dangerous goods. Incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage conditions: Store away from oxidants. Have containers keep away from direct sunlight and heat. Store in a wellventilated and cool place keeping container tightly closed. Store locked up. Material used in packaging/containers: Use containers prescribed in the "UN Transport Regulations". 8. Exposure Controls and Personal Protection Level/Exposure limit: ACGIH OSHA Ethylene glycol monobutyl ether acetate 20ppm not establish Engineering controls: Use Local exhaust ventilation. Personal protective equipment Respiratory protection: Respirator to avoid breathing organic solvent vapor. Hand protection: Ware chemical resistant gloves. Eye protection: Use safety glasses or goggles. Skin and body protection: Wear working clothes. Specific hygiene measures: Wash hands thoroughly after handling. 9. Physical and Chemical Properties Appearance physical state: Liquid Color: Red Odor: Mild odor ph: No data

7 MSDS-VJMP11INKMA950-01US Release Date 2012/4/16 Page 3/4 Flash point: 63 C (Tag closed cup) Auto ignition temperature : >340 C (Ethylene glycol monobutyl ether acetate) Specific gravity: g/cm 3 (25 C) VOC: g/L Vapor density: No information available. Solubility in water: Insoluble in water. 10. Stability and Reactivity Stability: Stable. Possibility of hazardous reaction: Acids and oxidizing agents. Conditions to avoid: Extremely high temperature. Incompatible substances or mixtures: Not occur. Hazardous decomposition products: No data. 11. Toxicological Information Acute toxicity: No information available. Mutagenicity: No information available. Other toxicity information: No information available. 12. Ecological Information Environmental hazards: This product is partially soluble in water. Treat using the best available techniques to avoid environmental contamination. Ecotoxicity: No information available. 13. Disposal Considerations Residual waste: For disposal, conform with the standards provided by related laws and local public bodies. When commissioning the disposal to a disposal company, notify the danger and toxicity thoroughly to the company. Contaminated container and packaging: Recycle containers after cleansing, or carry out the disposal under the related laws and regulations and the standards of the local governments. In case of disposal of empty containers, remove the content thoroughly. 14. Transportation Information Not classified as hazardous for transport. Follow all regulations in your country. 15. Regulatory Information All ingredients in this product are listed on the TSCA Inventory. Follow all regulations in your country. SARA Title Ⅲ: This product contain the following toxic chemicals subject to the reporting requirements of section 313 of title Ⅲ of the superfund amendment and reauthorization act of 1986 and 40 CFR Part 372. Substance or Category Content (%) Glycol ether Glycol ether is contained as a part of Ethylene glycol monobutyl ether acetate. California Prop.65: None of the chemicals in this product are listed on the state of California to cause cancer, birth defects or other reproductive harm. 16. Other Information HMIS (the Hazardous Material Identification System) Rating Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: H 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe NFPA (National Fire Protection Association) Rating Health: 1

8 MSDS-VJMP11INKMA950-01US Release Date 2012/4/16 Page 4/4 Flammability: 2 Instability: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe This Material Safety Data Sheet contains health, safety, and environmental information. It does not replace any precautionary language or use and disposal information which accompanies the product. The information contained herein is believed to be accurate at the time of preparation, but should only be used as a guide. It is subject to revision from time to time. MUTOH does not warrant the completeness or accuracy of the information contained herein.

9 MSDS-VJMP11INKYE950-01US 1. Product and Company Identification Product name Solvent Pigment Ink VJ-MP11INK-YE950 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKYE950-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients CAS No. Weight % Remark Pigment Listed 1-10 Polymer Listed 1-10 Ethylene glycol monobutyl ether acetate Ethyl lactate First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage.

10 MSDS-VJMP11INKYE950-01US Release Date 2012/4/16 Page 2/4 Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: In case of small quantity, absorb the leakage with dry soil, sand, and incombustible-material or collect it into a container that can be covered tightly for later disposal. In case of small quantity, use clean and anti-static tools to collect absorbed materials. In case of large quantity, prevent the spills from spreading with embankment to lead them to a safe place for collection. Collect the material into a disposal container by sucking up or sweeping up. Methods and equipment for containment and cleaning up: All devices to handle spills must be grounded. If not dangerous, stop the leak. Small amount: Prevent the material from wetting by rain. Cover with dry soil, dry sand, or non-combustibles and store under a plastic sheet cover to avoid scattering and wetting. Cleansing the contaminated area thoroughly with water after removal. Prevention measures for secondary accidents: Removes all ignition sources promptly. (Prohibition of smoking, sparks, and flames in the surrounding area) Prevent flowing into drain, sewage, basement, and closed area. 7. Handling and Storage Handling Technical measures: Provide ventilation system and Use necessary personal protective equipment as described in "Section 8. Exposure Controls and Personal Protection". Local and general ventilation: Provide local ventilations and a full ventilation system as described in "Section 8. Exposure Controls and Personal Protection". Precautions for safe handling: Prohibit the use of heat, sparks, and fire in the surrounding area. Wash hands thoroughly after handling. Avoid swallowing. Avoid the contact with the skin. Prevents Handling of incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage Precautionary Statements Technical measures: The storage facility should be designed with fire-proof construction and beams should use a noncombustible material. The roof of a storage facility should be made of a non-combustible material and use metals or other lightweight non-combustible materials. No ceiling should be installed. The storage floor should be protected from water penetration, or should have water-proof construction. The storage floor should have penetration-proof construction against dangerous goods and be inclined adequately. A proper sump should be provided to catch any spills. The storage facility should be provided with necessary lighting, lighting equipment, and ventilator to store and handle dangerous goods. Incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage conditions: Store away from oxidants. Have containers keep away from direct sunlight and heat. Store in a wellventilated and cool place keeping container tightly closed. Store locked up. Material used in packaging/containers: Use containers prescribed in the "UN Transport Regulations". 8. Exposure Controls and Personal Protection Level/Exposure limit: ACGIH OSHA Ethylene glycol monobutyl ether acetate 20ppm not establish Engineering controls: Use Local exhaust ventilation. Personal protective equipment Respiratory protection: Respirator to avoid breathing organic solvent vapor. Hand protection: Ware chemical resistant gloves. Eye protection: Use safety glasses or goggles. Skin and body protection: Wear working clothes. Specific hygiene measures: Wash hands thoroughly after handling. 9. Physical and Chemical Properties Appearance physical state: Liquid Color: Yellow Odor: Mild odor ph: No data

11 MSDS-VJMP11INKYE950-01US Release Date 2012/4/16 Page 3/4 Flash point: 63 C (Tag closed cup) Auto ignition temperature : >340 C (Ethylene glycol monobutyl ether acetate) Specific gravity: g/cm 3 (25 C) VOC: g/L Vapor density: No information available. Solubility in water: Insoluble in water. 10. Stability and Reactivity Stability: Stable. Possibility of hazardous reaction: Acids and oxidizing agents. Conditions to avoid: Extremely high temperature. Incompatible substances or mixtures: Not occur. Hazardous decomposition products: No data. 11. Toxicological Information Acute toxicity: No information available. Mutagenicity: No information available. Other toxicity information: No information available. 12. Ecological Information Environmental hazards: This product is partially soluble in water. Treat using the best available techniques to avoid environmental contamination. Ecotoxicity: No information available. 13. Disposal Considerations Residual waste: For disposal, conform with the standards provided by related laws and local public bodies. When commissioning the disposal to a disposal company, notify the danger and toxicity thoroughly to the company. Contaminated container and packaging: Recycle containers after cleansing, or carry out the disposal under the related laws and regulations and the standards of the local governments. In case of disposal of empty containers, remove the content thoroughly. 14. Transportation Information Not classified as hazardous for transport. Follow all regulations in your country. 15. Regulatory Information All ingredients in this product are listed on the TSCA Inventory. Follow all regulations in your country. SARA Title Ⅲ: This product contain the following toxic chemicals subject to the reporting requirements of section 313 of title Ⅲ of the superfund amendment and reauthorization act of 1986 and 40 CFR Part 372. Substance or Category Content (%) Glycol ether Glycol ether is contained as a part of Ethylene glycol monobutyl ether acetate. California Prop.65: None of the chemicals in this product are listed on the state of California to cause cancer, birth defects or other reproductive harm. 16. Other Information HMIS (the Hazardous Material Identification System) Rating Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: H 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe NFPA (National Fire Protection Association) Rating Health: 1

12 MSDS-VJMP11INKYE950-01US Release Date 2012/4/16 Page 4/4 Flammability: 2 Instability: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe This Material Safety Data Sheet contains health, safety, and environmental information. It does not replace any precautionary language or use and disposal information which accompanies the product. The information contained herein is believed to be accurate at the time of preparation, but should only be used as a guide. It is subject to revision from time to time. MUTOH does not warrant the completeness or accuracy of the information contained herein.

13 MSDS-VJMP11INKBK950-01US 1. Product and Company Identification Product name Solvent Pigment Ink VJ-MP11INK-BK950 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKBK950-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients Carbon black Polymer Ethylene glycol monobutyl ether acetate Ethyl lactate CAS No Listed Weight % Remark 4. First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage.

14 MSDS-VJMP11INKBK950-01US Release Date 2012/4/16 Page 2/4 Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: In case of small quantity, absorb the leakage with dry soil, sand, and incombustible-material or collect it into a container that can be covered tightly for later disposal. In case of small quantity, use clean and anti-static tools to collect absorbed materials. In case of large quantity, prevent the spills from spreading with embankment to lead them to a safe place for collection. Collect the material into a disposal container by sucking up or sweeping up. Methods and equipment for containment and cleaning up: All devices to handle spills must be grounded. If not dangerous, stop the leak. Small amount: Prevent the material from wetting by rain. Cover with dry soil, dry sand, or non-combustibles and store under a plastic sheet cover to avoid scattering and wetting. Cleansing the contaminated area thoroughly with water after removal. Prevention measures for secondary accidents: Removes all ignition sources promptly. (Prohibition of smoking, sparks, and flames in the surrounding area) Prevent flowing into drain, sewage, basement, and closed area. 7. Handling and Storage Handling Technical measures: Provide ventilation system and Use necessary personal protective equipment as described in "Section 8. Exposure Controls and Personal Protection". Local and general ventilation: Provide local ventilations and a full ventilation system as described in "Section 8. Exposure Controls and Personal Protection". Precautions for safe handling: Prohibit the use of heat, sparks, and fire in the surrounding area. Wash hands thoroughly after handling. Avoid swallowing. Avoid the contact with the skin. Prevents Handling of incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage Precautionary Statements Technical measures: The storage facility should be designed with fire-proof construction and beams should use a noncombustible material. The roof of a storage facility should be made of a non-combustible material and use metals or other lightweight non-combustible materials. No ceiling should be installed. The storage floor should be protected from water penetration, or should have water-proof construction. The storage floor should have penetration-proof construction against dangerous goods and be inclined adequately. A proper sump should be provided to catch any spills. The storage facility should be provided with necessary lighting, lighting equipment, and ventilator to store and handle dangerous goods. Incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage conditions: Store away from oxidants. Have containers keep away from direct sunlight and heat. Store in a wellventilated and cool place keeping container tightly closed. Store locked up. Material used in packaging/containers: Use containers prescribed in the "UN Transport Regulations". 8. Exposure Controls and Personal Protection Level/Exposure limit: Ethylene glycol monobutyl ether acetate Carbon black Engineering controls: Use Local exhaust ventilation. Personal protective equipment Respiratory protection: Respirator to avoid breathing organic solvent vapor. Hand protection: Ware chemical resistant gloves. Eye protection: Use safety glasses or goggles. Skin and body protection: Wear working clothes. Specific hygiene measures: Wash hands thoroughly after handling. ACGIH 20ppm 3.5mg/m 3 OSHA not establish 3.5mg/m 3 9. Physical and Chemical Properties Appearance physical state: Liquid Color: Black Odor: Mild odor

15 MSDS-VJMP11INKBK950-01US Release Date 2012/4/16 Page 3/4 ph: No data Flash point: 63 C (Tag closed cup) Auto ignition temperature : >340 C (Ethylene glycol monobutyl ether acetate) Specific gravity: g/cm 3 (25 C) VOC: g/L Vapor density: No information available. Solubility in water: Insoluble in water. 10. Stability and Reactivity Stability: Stable. Possibility of hazardous reaction: Acids and oxidizing agents. Conditions to avoid: Extremely high temperature. Incompatible substances or mixtures: Not occur. Hazardous decomposition products: No data. 11. Toxicological Information Acute toxicity: Oral toxicity LD50 (Rat) 15,400mg/kg as Carbon black IARC monographs: Carbon black is classified as a substance which is possibly carcinogenic to humans (IARC Group 2B). Mutagenicity: No information available. Other toxicity information: No information available. 12. Ecological Information Environmental hazards: This product is partially soluble in water. Treat using the best available techniques to avoid environmental contamination. Ecotoxicity: No information available. 13. Disposal Considerations Residual waste: For disposal, conform with the standards provided by related laws and local public bodies. When commissioning the disposal to a disposal company, notify the danger and toxicity thoroughly to the company. Contaminated container and packaging: Recycle containers after cleansing, or carry out the disposal under the related laws and regulations and the standards of the local governments. In case of disposal of empty containers, remove the content thoroughly. 14. Transportation Information Not classified as hazardous for transport. Follow all regulations in your country. 15. Regulatory Information All ingredients in this product are listed on the TSCA Inventory. Follow all regulations in your country. SARA Title Ⅲ: This product contain the following toxic chemicals subject to the reporting requirements of section 313 of title Ⅲ of the superfund amendment and reauthorization act of 1986 and 40 CFR Part 372. Substance or Category Content (%) Glycol ether Glycol ether is contained as a part of Ethylene glycol monobutyl ether acetate. California Prop.65: None of the chemicals in this product are listed on the state of California to cause cancer, birth defects or other reproductive harm. 16. Other Information HMIS (the Hazardous Material Identification System) Rating Health: 1 Flammability: 2 Physical hazard: 0 Personal protection: H

16 MSDS-VJMP11INKBK950-01US Release Date 2012/4/16 Page 4/4 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe NFPA (National Fire Protection Association) Rating Health: 1 Flammability: 2 Instability: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe This Material Safety Data Sheet contains health, safety, and environmental information. It does not replace any precautionary language or use and disposal information which accompanies the product. The information contained herein is believed to be accurate at the time of preparation, but should only be used as a guide. It is subject to revision from time to time. MUTOH does not warrant the completeness or accuracy of the information contained herein.

17 MSDS-VJMP11INKWH500-01US 1. Product and Company Identification Product name Solvent Pigment Ink VJ-MP11INK-WH500 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKWH500-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients CAS No. Weight % Remark Titanium dioxide Polymer Listed 1-10 Ethylene glycol monobutyl ether acetate Ethyl lactate First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage.

18 MSDS-VJMP11INKWH500-01US Release Date 2012/4/16 Page 2/4 Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: In case of small quantity, absorb the leakage with dry soil, sand, and incombustible-material or collect it into a container that can be covered tightly for later disposal. In case of small quantity, use clean and anti-static tools to collect absorbed materials. In case of large quantity, prevent the spills from spreading with embankment to lead them to a safe place for collection. Collect the material into a disposal container by sucking up or sweeping up. Methods and equipment for containment and cleaning up: All devices to handle spills must be grounded. If not dangerous, stop the leak. Small amount: Prevent the material from wetting by rain. Cover with dry soil, dry sand, or non-combustibles and store under a plastic sheet cover to avoid scattering and wetting. Cleansing the contaminated area thoroughly with water after removal. Prevention measures for secondary accidents: Removes all ignition sources promptly. (Prohibition of smoking, sparks, and flames in the surrounding area) Prevent flowing into drain, sewage, basement, and closed area. 7. Handling and Storage Handling Technical measures: Provide ventilation system and Use necessary personal protective equipment as described in "Section 8. Exposure Controls and Personal Protection". Local and general ventilation: Provide local ventilations and a full ventilation system as described in "Section 8. Exposure Controls and Personal Protection". Precautions for safe handling: Do not handle until all safety precautions have been read and understood. Prohibit the use of heat, sparks, and fire in the surrounding area. Wash hands thoroughly after handling. Avoid swallowing. Avoid the contact with the skin. Do not breathe gas,mist,vapors and spray. Avoid excessive heat. Prevents Handling of incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage Precautionary Statements Technical measures: The storage facility should be designed with fire-proof construction and beams should use a noncombustible material. The roof of a storage facility should be made of a non-combustible material and use metals or other lightweight non-combustible materials. No ceiling should be installed. The storage floor should be protected from water penetration, or should have water-proof construction. The storage floor should have penetration-proof construction against dangerous goods and be inclined adequately. A proper sump should be provided to catch any spills. The storage facility should be provided with necessary lighting, lighting equipment, and ventilator to store and handle dangerous goods. Incompatible substances or mixtures: Refer to "Section 10. Stability and Reactivity". Storage conditions: Store away from oxidants. Have containers keep away from direct sunlight and heat. Store in a wellventilated and cool place keeping container tightly closed. Store locked up. Material used in packaging/containers: Use containers prescribed in the "UN Transport Regulations". 8. Exposure Controls and Personal Protection Level/Exposure limits: ACGIH(TWA) OSHA Titanium Dioxide 10mg/m 3 10mg/m 3 Ethylene glycol monobutyl ether acetate 20ppm Not Established Engineering controls: Use Local exhaust ventilation. Personal protective equipment Respiratory protection: Respirator to avoid breathing organic solvent vapor. Hand protection: Ware chemical resistant gloves. Eye protection: Use safety glasses or goggles. Skin and body protection: Wear working clothes. Specific hygiene measures: Wash hands thoroughly after handling. 9. Physical and Chemical Properties Appearance physical state: Liquid

19 SDS-VJMP11INKWH500-01US M Color: White Odor: Mild odor ph: No data Flash point: 63 C (Tag closed cup) Specific gravity: g/cm 3 (25 C) Vapor density: No information available. Solubility in water: Insoluble in water. Release Date 2012/4/16 Page 3/4 10. Stability and Reactivity Stability: Stable. Possibility of hazardous reaction: Acids and oxidizing agents. Conditions to avoid: Extremely high temperature. Incompatible substances or mixtures: Acids and oxidizing agents. Hazardous decomposition products: No data. 11. Toxicological Information Acute toxicity: Titanium dioxide LD 50 (rat) 12000mg/kg Carcinogenicity Titanium dioxide :IARC Group 2B Mutagenicity: No information available. Other toxicity information: No information available. 12. Ecological Information Environmental hazards: This product is insoluble in water. Treat using the best available techniques to avoid environmental contamination. Ecotoxicity: No information available. 13. Disposal Considerations Residual waste: For disposal, conform with the standards provided by related laws and local public bodies. When commissioning the disposal to a disposal company, notify the danger and toxicity thoroughly to the company. Contaminated container and packaging: Recycle containers after cleansing, or carry out the disposal under the related laws and regulations and the standards of the local governments. 14. Transportation Information Not classified as hazardous for transport. Follow all regulations in your country. 15. Regulatory Information All ingredients in this product are listed on the TSCA Inventory. Follow all regulations in your country. SARA Title Ⅲ: This product contain the following toxic chemicals subject to the reporting requirements of section 313 of title Ⅲ of the superfund amendment and reauthorization act of 1986 and 40 CFR Part 372. Substance or Category Content (%) Glycol ether California Prop.65: None of the chemicals in this product are listed on the state of California to cause cancer, birth defects or other reproductive harm. 16. Other Information HMIS (the Hazardous Material Identification System) Rating Health: 1 Flammability: 2 Physical hazard: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe Personal protection: H NFPA (National Fire Protection Association) Rating

20 MSDS-VJMP11INKWH500-01US Release Date 2012/4/16 Page 4/4 Health: 1 Flammability: 2 Instability: 0 0 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe This Material Safety Data Sheet contains health, safety, and environmental information. It does not replace any precautionary language or use and disposal information which accompanies the product. The information contained herein is believed to be accurate at the time of preparation, but should only be used as a guide. It is subject to revision from time to time. MUTOH does not warrant the completeness or accuracy of the information contained herein.

21 MSDS-VJMP11INKCL950-01US 1. Product and Company Identification Product name Cleaner VJ-MP11INK-CL950 Company name MUTOH INDUSTRIES LTD. Address Ikejiri, Setagaya-Ku, Tokyo , Japan Contact Section International Sales Department Phone Fax MSDS No. MSDS-VJMP11INKCL950-01US Release Date 2012/4/16 Page 1/4 Material Safety Data Sheet 2. Hazards Identification Classification: Harmful and irritant preparation. Routes of entry: Inhalation, Ingestion, and Skin. Harm to health: Contact with eyes may result in irritation. Contact with skin may result in irritation. Ingestion may result in gastric disturbance. Prolonged or repeated inhalation of vapor may cause headaches, dizziness or nausea. Harm to ecological: No information available. Risk of combustion and explosion: The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Vapor/air mixtures is explosive. 3. Composition/Information on Ingredients Single or Blend: Blend Ingredients CAS No. Weight % Remark Ethylene glycol monobutyl ether acetate Ethyl lactate First Aid Measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air area. Call a physician. In case of contact, immediately wash skin with soap and plenty of water. If irritation develops, get medical attention. Remove contaminated clothing and shoes. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If irritation develops, get medical attention. If swallowed, seek medical advice immediately. 5. Fire Fighting Measures Extinguishing media: Small fire: Dry chemicals, carbon dioxide, water, sprinkling, and alcohol-resistance foam extinguishing agent. Large fire: Dry chemicals, carbon dioxide, and alcohol-resistance foam extinguishing agent. Unsuitable extinguishing media: Jet water. Specific hazards: Irritant, corrosive and/or toxic gas may be generated by a fire. Container may explode when heated. Specific fire fighting: Carry out fire-fighting at the safe and effective distance from the fire, or use a unattended hoseholding unit, or a nozzle with a monitor. Protection of fire fighters: In fire-extinguishing activity, wear an appropriate air breathing apparatus and full protective clothing for chemicals. 6. Accidental Release Measures Personal precautions, protective: Do not touch the leakage, and do not walk on it. Equipment and emergency procedures: Prohibit unauthorized entry into the area. Wear appropriate personal protective equipment (Refer to "Section 8. Exposure Controls and Personal Protection") and avoid inhalation or contact with eyes and skin. If not wearing an appropriate personal protective clothing, do not touch the damaged container and leakage. Environmental precautions: Do not release into the environment. Pay attention not to cause the influence on the environment by discharging into rivers. Decontamination/Absorption/Sweeping/Vacuuming/Neutralization: