Processing Swedish lignocellulosic residual material to furan pre-cursors. Furu2Furan
|
|
- Alberta Quinn
- 6 years ago
- Views:
Transcription
1 Processing Swedish lignocellulosic residual material to furan pre-cursors Furu2Furan Dennis Jones, Bror Sundqvist SP Wood Technology / EcoBuild Sune Wännström SP Energy Technology William Mackintosh, Johan Malmberg, Anna Stenemyr SP Process Development
2 Furu2Furan Consortium comprising whole value chains Companies members of EcoBuild Competence Center (Competence centre for eco-efficient and innovative wood-based materials)
3 SP A uniting hub in Bioeconomy Vision SP shall be a uniting force and a central resource contributing with knowledge, research resources and management, test facilities and coordination of bioeconomy initiatives in Sweden BIO- ECONOMY SP PROCESS DEVELOPMENT
4 Why are we doing this? Today: too much focus on biofuel production (which may not be the optimal use of the whole biomass) The furanic route to platform chemicals and high-value commodities is almost neglected in current biorefinery development There are some potential winners for the future biobased economy but need to secure that enough chemicals for these is produced in future biorefineries
5 The biorefinery concept Jan van Dam, COST FP1205 presentation 2013
6 The biorefinery concept Furu2Furan High value chemicals Jan van Dam, COST FP1205 presentation 2013
7 Furu2Furan concept
8 Softwoods yield hexoses
9 Hardwoods and agri-fibres yield pentoses
10 Some pathways
11 Conversion of HMF 2-hydroxymethylfuran Platform chemical 2,5-Furandicarboxylic acid Monomer for polymer production 2,5-Dimethylfuran Bio-fuel Methylfuran Bio-fuel 5-hydroxymethylfurfural (HMF) 2,5-Dimethyltetrahydrofuran Solvent 2,5-bis(hydroxymethyl)furan Monomer for polymer production Levulinic acid Bulk chemical Formic acid Bulk chemical
12 High-value end products of the F2F project Furfurylated wood (Kebony) with aesthetic appearance and performance similar to durable tropical timbers (and preservative treated timbers) - European market for durable hardwood (tropical timber): 6 million m³/year => value: 6 billion Euro - European market for preservative treated wood: 6 million m³/year => value: 1.5 billion Euro Coil Coatings (currently 99.9% fossil resource based). BioCoilCoat aims at 60% biobased. SSAB alone use 4 kton/year (?): worth 20 million Euro European market: 100 kton/year (?): worth 550 million Euro Thermoset composites today 99% fossil based European market: 10 billion Euro worth? bioderived resins can replace fossil based resins for many products
13 Possible high-value bulk chemicals from the F2F project Maleic anhydride (currently 100% fossil based) - Global production: worth 550 million Euro Thermoset polyesters & polymerisat. catalyst Adipic acid (currently 100% fossil based) Global annual production: 2.3 million ton Worth: 845 million Euro Caprolactone (currently 100% fossil based Perstorp production (largest producer globally): 12 kton/year? Perstorp caprolactone sales worth 60 million Euro/year Hexane diol (currently 100% fossil based) BASF production (largest producer globally): 50 kton/year Worth: 310 million Euro Polyamide (Nylon) Aviation fuel (currently 100% fossil based). Possibly DMFu Global annual prod of Jet fuel: 5 million barrels worth 500 million Euro e.g. Shoe soles, Medical plastics Polymer building block for e.g. PUR and PE ( Green aromatic solvents ) Global prod. of BTX: 87 Mton worth 91 billion Euro (BTX means Benzene, Toluene, Xylenes)
14 Starting materials A. Under-utilized forest products streams Saw dust Residuals from forest harvesting (stubs, tops and branches) Prehydrolysate from dissolving pulp production TMP and CTMP process water
15 Starting materials B. Under-utilized agricultural byproduct streams Wheat straw Wheat bran Straw and bran from other Lantmännen crops
16 Lab scale work: SP-PD Chemical Processes: Xylose to Furfural Furfural From Hemicellulose Furfuryl alcohol Furfural: Extracted from hydrolysate or transformed from isolated sugar Industrial production in China, South Africa, Dominican republic
17 Lit review from C5, xylose and furfural Showed that furfural is currently being produced commercially from bagasse and/or corn stover Inexpensive, high yields, tuned catalysts and conditions However not from wheat straw. Patents and publications containing furfural and wheat straw Conclusions from literature More severe conditions, time, temp, acid: more furfural Milder conditions: more xylose to then produce furfural in a 2nd step.
18 Experimental Step 1: Wheat straw and dilute sulfuric acid added to a microwave vial (10-20 ml) run under mild conditions. The slurry was filtered, the filtrate analyzed, then used in step 2. Microwave reactor Step 2: Filtrate & methyl isobutyl ketone (MIBK) combined in microwave vial (2-5 ml) High temps and short reaction time Analysis of furfural yield by HPLC and/or LCMS RP-HPLC
19 Results- mild prehydrolysis of wheat straw on the lab scale Step 1: From mild conditions: A range of results is observed in furfural and xylose content The filtrate was then further reacted in step 2
20 Filtration:Processum Pilot Park - Örnsköldsvik Liquid-liquid extraction Filter press Reactor system for synthesis Spinning unit
21 Results step 2-Conversion of xylose to furfural Higher temperatures: Highest yields of furfural were achieved from the mildest hydrolysis runs from step 1. 72% yield obtained (78% in total, Aq phase included) Yield in organic phase
22 Literature Study of C6 sugars to HMF Glucose is a sugar from cellulose and hemicellulose Similar to mannose found in hemicellulose Fructose to HMF Vast amount of information in literature- 8 k items in scifinder. Little in terms of Scaling up and production processes Many catalysts for fructose to HMF Not much reported regarding glucose to HMF Fewer catalysts to convert glucose to HMF Lower yields from glucose
23 Experimental Work Flow for C6 sugars Conditions and catalysts screened on a small scale Via microwave in 2-5 ml vials Analysis of HMF performed by HPLC and/or LCMS Reaction of fructose to HMF first investigated Higher yields and much broader range of possibilities Catalysts screened Then glucose to HMF investigated With use of knowledge obtained from fructose trials
24 Outline of the Experimental Parameters Considered Catalyst Soluble or insoluble Reaction phase biphasic (both water and solvent) vs. single phase Ratio of water to solvent in biphasic system Aqueous Phase Ionic Strength Agitation Solvent type Concentration of sugar in the water phase Temperature Time Replacing the solvent at intervals
25 Screening of Catalysts Less than desirable yields from: Zeolites, Ag and Cs based polyacids, phosphorylated niobium oxide, sulphuric acid 2 Best performers with fructose: Phosphorylated Tantalum hydroxide vs. Calcium phosphate (CaP 2 O 6 ) Next in trials with glucose: Only 20% yield compared to 27% yield w same conditions Glucose to HMF, 190 o C, 20 min, 3 ml MIBK to 2 ml H 2 O *Daorattanachai, P. et al. Conversion of fructose, glucose, and cellulose to 5-hydroxymethylfurfural by alkaline earth phosphate catalysts in hot compressed water, Carbohydrate Research, 363 (2012) * Yang, F. et al. Tantalum compounds as heterogeneous catalysts for saccharide dehydration to 5-hydroxymethylfurfural. Chemical Communications, 47 (2011)
26 Reaction phases Biphasic gave the best yields, with the solvent extracting HMF Inhibits degrading/polymerizing of HMF in the water phase as it is extracted HMF + hydrated HMF Polymer (Humins) formation HMF + glucose Ratio of solvent to water likely requires optimization depending on the system solvent:h2o optimum at 3:2 or 4:1 Higher concentrations of sugar in water does create more insoluble hummins and side reactions * Rasmussen, H. et al. Formation of degradation compounds from lignocellulosic biomass in the biorefinery: Sugar reaction mechanisms, Carbohydrate Research, 385 (2014)
27 Agitation Agitation is very important Creates maximum contact between the 2 phases. Important to transfer HMF from the aqueous phase Decreases HMF degradation and polymerization Catal yst *More humins with scale up in 20 ml microwave vial Alternative to agitation in larger scale processing could be sonication
28 Solvent type Extraction solvent is important Extracts HMF from water M-THF: 8% HMF yield from glucose MIBK: 27% 2-butanol: 30%, and 2% less HMF in water phase Catal yst 2-butanol gave best results, but similar to MIBK or Glucose Is MIBK better for continuous processing? water -2-butanol dissolves a large amount of
29 Concentration of Sugar in the Aqueous Phase The higher the concentration, the lower the yield Due to HMF coming in contact with glucose and itself to form humins This will also require optimization depending on the system 30 wt% glucose in water creates a large amount of side products Determined by HPLC Also much lower yields 6 wt% glucose in water used in most trials to provide high yields of HMF
30 Scaling up: Pretreatment reactor Built for 230 C and 30 bar Heated by steam (22bar) Used for batch reactions
31 Both Mild and Harsh systems for wheat straw scaled up in the Demo-Plant Test Production time Demo Run Plan Target: collecting 100 litres of xylose rich hydrolysate and 100 litres of furfural rich hydrolysate after dilute acid hydrolysis of wheat straw. Temperature Acid Load Residence time Sampling Unit h C % min Litres , , ,2-0, ,
32 Biorefinery Demo Plant
33 Demo plant Domsjö Biorefinery site
34 Demo Plant Facts Fully integrated process from feedstock to distilled product Operated 24h/ 7d Two continuous flow-through hydrothermal reactors One or two step acid hydrolysis Dilute acid pretreatment + enzymatic hydrolysis Five 10 m 3 bio-reactors Enzymatic hydrolysis Fermentation Cultivation GMM certified Flexible Process configurations Forest and agro feedstocks Biorefinery applications (sugar platform) Capacity, 2 tons of dry wood chips / 24 h
35 Layout 1. Raw material intake 2. Feeding vessel 3. Steaming and impregnation 4. Pretreatment 5. Neutralisation and inhibitor control 6. Enzymatic hydrolysis and fermentation 7. Yeast propagation 8. Distillation 9. Product tank 10. Filter press 11. Solid material to incineration 12. Liquid to incineration/ biogas production 13. Evaporation Equipment
36 Hydrothermal Pre-treatment of Lignocellulose Feedstock Feed stock wood chips screw-s impregnation tank horizontal reactor steam screw-s 1 H 2 SO 4 steam screw-s vertical reactor filtrate sample position slurry tank
37 Earlier experiences (not targeting high yield of furans) Wheat straw Mild pretreatment; ~2-6 g/l furfural, ~0-1 g/l HMF. Harsh preteratment >10g/l Spruce chips Mild - medium pretreatment; ~2g/l furfural, ~3 g/l HMF Pine chips Medium harsh pretreatment; ~4 g/l furfural, ~8-10 g/l HMF.
38 Process Sawdust and Wheat Straw Fermentation & distillation Ethanol Pretreatment & fractionation less hydrolysed Cellulose Enzymatic treatment Sugars Chemical Processes HMF Furfuryl alcohol Dimethylfuran (fuel) Ligno-cellulosic Biomass (sawdust) Sugars and furans Fractionation Chemical Processes Furfural Furfuryl alcohol FA/Furfural-mix C5 & C6 (oligo- & polysacharides) Lignin-rich solid residue Or further hydrolysis to furans Pellet processsing Energy
39 Discussion Understanding of the different streams. Contents, Assays, purity, analytical methods and control. Control of hydrolysis and extraction of Furans (Pilot/Demo plant) How to process the different streams before chemical processing if needed. Filtration, extraction, other methods Defining Target furans of value based on the different streams and demand. No industrial process available for HMF from lignocellulose
40 Separation Development Feed stream: Sawdust hydrolysate containing furans, excluding lignin (from Örnsköldsvik). Membrane filtration to separate furans from hydrolysate Laboratory tests either at SPPD or at Alfa Laval Pilot scale tests at Örnsköldsvik Purified streams used for downstream chemistry Extraction to separate furans from hydrolysate Investigate downstream separation of product streams (when applicable)
41 Reason for using filtration technology Less chemicals in aqueous streams Greater ease of disposal Less need for additional chemical adidtional for clean up Typically a TMP mill will release approx 3-5kg carbohydrates per m3 of water This means approx kg of carbohydrates per hour Potentially 3500 tonnes per annum lost
42 Potential of processing
43 Concept of process
44 Plant design
45 Microwave applications Lab scale Up to 10 ml Pilot scale Potential up to 0.6 m 3
46 Glucose/Fructose to HMF and downstream H 3 C O OH OH OH O O HO OH Fructose HMF From Cellulose H 3 C O OH OH OH O O HO OH Fructose HMF Fructose is more reactive and selective to make HMF than glucose i.e. higher yield Starting from glucose likely involves isomerization to fructose before dehydration to HMF FDCA Dimethyl furan & Other Chemicals 2,5-bishydroxymethyl furan
47 Conclusions of Furu2Furan Literature review, lab based experiments, pilot scale experiments and demo plant runs carried All in a period of 9 months Additional work Environmental aspects Financial aspects Logistics Devising alternative pathways to new chemical derivatives Investigating pilot scale microwave processing Strong links built between industry partners New projects underway (OptiFuran, Furan2Market)
The CIMV organosolv Process. B. Benjelloun
The CIMV organosolv Process B. Benjelloun 2 BIOREFINERY CONCEPT THE CIMV PROCESS Based on the oil refining model. Promote 100% of the non-food Biomass in Biofuels and/or Bioproducts. High feedstocks fexilibility
More informationWP No.4: Innovative chemical conversion and synthesis - Highlights
WP No.4: Innovative chemical conversion and synthesis - Highlights E. Papadopoulou, P. Schöenicke, B. Kamm, J. Rogut, G. Marcotullio, D. van Es, E., R. Gosselink, H. Hagen, H. Reith, B. Estrine Development
More informationThe kraft pulp mill biorefinery platform
The kraft pulp mill biorefinery platform Peter Axegård, INNVENTIA AB, Sweden, peter.axegard@innventia.com Niklas berglin, INNVENTIA, Sweden, niklas.berglin@innventia.com Karin Lindgren, INNVENTIA, Sweden,
More informationLevulinic Acid Production From Bagasse CPD-3271
Levulinic Acid Production From Bagasse CPD-3271 Bagasse (lignocellulose) 1 2 3 Cellulose Hemicellulose Lignin 4 Hexose HMF 6 5 Levulinic Acid 9 7 Pentose 8 Furfural Tar 10 11 12 Asphalt-like Substance
More informationIndustrial Biotechnology and Biorefining
Industrial Biotechnology and Biorefining Industrial Biotechnology and Biorefining The Centre for Process Innovation From innovation to commercialisation The High Value Manufacturing Catapult is a partnership
More informationRenewable Chemicals from the Forest Biorefinery
11 th Annual Congress on Industrial Biotechnology May 12 15, 2014 Philadelphia, PA Renewable Chemicals from the Forest Biorefinery François Zasieczny, Mariya Marinova, Tom Browne, Michel Perrier The Forest
More informationThomas Grotkjær Biomass Conversion, Business Development
NOVOZYMES AND BETA RENEWABLES DEPLOY WORLD CLASS CELLULOSIC ETHANOL TECHNOLOGY TO MARKET FROM BIOMASS TO BIOENERGY BIO WORLD CONGRESS, PHILADELPHIA, 13 MAY 2014 Thomas Grotkjær Biomass Conversion, Business
More informationBy Dr S.K.PURI Indian Oil Corporation Limited, R&D Centre, FARIDABAD 22 nd Jan., 2016
2 nd Generation Ethanol -A Prospective- By Dr S.K.PURI Indian Oil Corporation Limited, R&D Centre, FARIDABAD 22 nd Jan., 2016 BIO-FUELS Fuel produced from renewable biomass material, commonly used as an
More informationCellulosic Biomass Chemical Pretreatment Technologies
Life-changing Research and Development Cellulosic Biomass Chemical Pretreatment Technologies September 6, 2007 Keith Pauley Keith.Pauley@matricresearch.com 800-611-2296 Chemical and Environmental Technologies
More informationBreaking the Chemical and Engineering Barriers to Lignocellulosic Biofuels
Breaking the Chemical and Engineering Barriers to Lignocellulosic Biofuels A Workshop to Develop the Roadmap for Making Lignocellulosic Biofuels a Practical Reality ACS Headquarters Washington, D.C. June
More informationECN Research and Development in bioenergy
ECN Research and Development in bioenergy June 2014, Environmental Day, Sao Paulo Tatjana Komissarova, Corporate business developer www.ecn.nl BRAZIL Brazil is nowadays the largest and BEST bioethanol
More informationThe German Lignocellulose Feedstock Biorefinery Project
The German Lignocellulose Feedstock Biorefinery Project Jochen Michels, Kurt Wagemann, DECHEMA e.v. Frankfurt am Main Project information Joint Project of 15 Partners Industrial: 4 Partners SME: Res. Inst.*:
More informationEmerging biorefinery concepts and research infrastructure development needs
Emerging biorefinery concepts and research infrastructure development needs Anna Leinonen (VTT Oy) Frederik de Bruyn (BBEPP), Benoit Joffres (INRA), Jonas Joelsson (SP), Klaus Niemelä (VTT Oy) Christine
More informationSeparation and Purification: the Missing Link Between Biomass Deconstruction and Commercial Products
Separation and Purification: the Missing Link Between Biomass Deconstruction and Commercial Products World Congress on Industrial Biotechnology May 12th John Bhatt Novasep Inc. 1 Industrial Purification
More informationThe Biorefinery approach to production of lignocellulosic ethanol and chemicals from lignocellulosic biomass
The Biorefinery approach to production of lignocellulosic ethanol and chemicals from lignocellulosic biomass IEA Bioenergy Conference, Vienna 13-14.11.2012 Gisle L Johansen Senior Vice President R&D and
More informationAvantium Renewable Chemistries Update for IFBC2017. Alan Smith 9-May-2017
Avantium Renewable Chemistries Update for IFBC2017 Alan Smith 9-May-2017 Avantium, a Leading Renewable Chemicals Technology Company From Strong shareholder base with strategic and financial partners to
More informationLignin valorization towards materials, chemicals and energy
Lignin valorization towards materials, chemicals and energy 2 nd Lund symposium on lignin and hemicellulose valorisation, November 3-4, 2015 Lund Dr. Richard Gosselink Contents Lignin valorization Biorefineries
More informationBiorefinery concepts for non-wood raw materials Dr. Päivi Rousu Vice President, R&D, IPR
The future is BIOREFINING Biorefinery concepts for non-wood raw materials Dr. Päivi Rousu Vice President, R&D, IPR Outline of presentation Chempolis corporation formico - 3 rd generation biorefining technologies
More informationValue Maximization through PRAJ's 2nd Generation Smart Bio Refinery. Amol Sheth October, 17 th 2016
Value Maximization through PRAJ's 2nd Generation Smart Bio Refinery Amol Sheth October, 17 th 2016 Discussion Points Technology development & commercialization Praj s 2G Ethanol Technology Innovative Tech.
More informationWOOD BASED BIOREFINERIES OPPORTUNITIES AND CHALLENGES. Dr. Christian Hübsch, UPM Biochemicals IFIB 2015, Lodi,
WOOD BASED BIOREFINERIES OPPORTUNITIES AND CHALLENGES Dr. Christian Hübsch, UPM Biochemicals IFIB 2015, Lodi, 24.9.2015 UPM today UPM Plywood Plywood and veneer products UPM Biorefining Pulp Plantations
More informationTMP-Bio for Converting Cellulosic Biomass to 2nd Generation Sugar and Near-native Lignin
TMP-Bio for Converting Cellulosic Biomass to 2nd Generation Sugar and Near-native Lignin Changbin Mao, Zhirun Yuan, Luis Fernando Del Rio, Waleed Wafa Al Dajani, David Wong, Thomas Browne FPInnovations,
More informationEthanol From Cellulose: A General Review
Reprinted from: Trends in new crops and new uses. 2002. J. Janick and A. Whipkey (eds.). ASHS Press, Alexandria, VA. Ethanol From Cellulose: A General Review P.C. Badger INTRODUCTION The use of ethanol
More informationEXPERTISE BIOMASS PRETREATMENT BIOMASS PRETREATMENT BIOCATALYSIS FERMENTATION GREEN CHEMISTRY PRODUCT RECOVERY AND PURIFICATION
BIOMASS PRETREATMENT BIOMASS PRETREATMENT BIOCATALYSIS FERMENTATION GREEN CHEMISTRY PRODUCT RECOVERY AND PURIFICATION BIOMASS PRETREATMENT Equipment overview: Reactors for chemical pretreatment of biomass:
More informationThe sunliquid process - cellulosic ethanol from agricultural residues. Dr. Ing. Paolo Corvo Biotech & Renewables Center
The sunliquid process - cellulosic ethanol from agricultural residues Dr. Ing. Paolo Corvo Biotech & Renewables Center Introduction to Clariant and the Biotech & Renewable Center Dr. Ing. Paolo Corvo Biotech
More informationBioprocess Pilot Facility
Bioprocess Pilot Facility CONFIDENTIAL State of the art R&D and Pilot Facilities State-of-the-art lab space and offices Open access and shared facilities Umbrella permits Shared services Unique testing
More informationFROM KRAFT MILL TO FOREST BIOREFINERY: AN ENERGY AND WATER PERSPECTIVE. II. CASE STUDY
CELLULOSE CHEMISTRY AND TECHNOLOGY FROM KRAFT MILL TO FOREST BIOREFINERY: AN ENERGY AND WATER PERSPECTIVE. II. CASE STUDY MARIYA MARINOVA, ENRIQUE MATEOS-ESPEJEL and JEAN PARIS École Polytechnique, Chemical
More informationInnovative Forest Products Biorefinery
Helsinki University of Technology Innovative Forest Products Biorefinery Adriaan van Heiningen and Tapani Vuorinen Helsinki University of Technology Department of Forest Products Technology Espoo, Finland
More informationThe future is BIOREFINING
The future is BIOREFINING Stepping up to THE CHALLENGE If we want a more sustainable future, we need to make better use of renewable biomass residues. Advanced technology from Chempolis makes it possible
More informationENABLING THE BIO-ECONOMY
ENABLING THE BIO-ECONOMY APPLICATIONS CENTER 15 T W Alexander Drive Durham, NC 27703, USA PROCESS OPERATIONS CENTER 5516 Industrial Park Road Norton, VA 24273, USA BIOTECHNOLOGY CENTER Génavenir 1, 1 rue
More informationEthanol Production from Biomass - Optimization of Simultaneous Saccharification and Fermentation with Respect to Stirring and Heating
Ethanol Production from Biomass - Optimization of Simultaneous Saccharification and Fermentation with Respect to Stirring and Heating JESPER NÖRGÅRD Department. of Chemical Engineering, Lund Institute
More informationChallenges of Ethanol Production from Lignocellulosic Biomass
Challenges of Ethanol Production from Lignocellulosic Biomass Maha Dakar Varieties of Carbohydrates Sugar Starch Cellulose/Hemicellulose What All Plants Have in Common Cellulose Glucose Why is it difficult
More informationDuPont Cellulosic Ethanol: Sustainable, Economic, Farm-to-Fuel Solutions
DuPont Cellulosic Ethanol: Sustainable, Economic, Farm-to-Fuel Solutions May 2013 Copyright 2013 DuPont. All rights reserved. 1 DuPont Industrial Biosciences Focused growth through bioprocessing technologies
More informationAdvanced biofuels and added value products from residual quasi-homogeneous biomass: from ethanol to drop-infuels
Advanced biofuels and added value products from residual quasi-homogeneous biomass: from ethanol to drop-infuels Jean-Michel Lavoie (Ph.D) Associate Professor and Chairholder Industrial research chair
More informationDoes densification (pelletisation) restrict the biochemical conversion of biomass?
Does densification (pelletisation) restrict the biochemical conversion of biomass? Linoj Kumar, Zahra Tooyserkani Shahab Sokhansanj, Richard Chandra Jack Saddler* Forest Products Biotechnology/Bioenergy
More informationProcessing Recalcitrant Feedstocks in a Biorefinery
Processing Recalcitrant Feedstocks in a Biorefinery Johnway Gao Dwight Anderson Benjamin Levie Paul Spindler October 10-12, 2012 For Bio Pacific Rim Summit on Industrial Biotechnology and Bioenergy Vancouver
More informationFrom Non-Food Feedstock to Fuel: Here and Now Kerry Nixon, Manager, Central Minnesota Ethanol Coop Fueling the Future: The Role of Woody Biomass for Energy Workshop March 26, 2009 Ponsford Sponsored by:
More informationPretreatment of Prevalent Canadian West Coast Softwoods Using the Ethanol Organosolv Process Assessing Robustness of the Ethanol Organosolv Process
Pretreatment of Prevalent Canadian West Coast Softwoods Using the Ethanol Organosolv Process Assessing Robustness of the Ethanol Organosolv Process Johanna Johansson Department of Chemical Engineering,
More informationLignin conversion into bio-based chemicals
Engineering Conferences International ECI Digital Archives BioEnergy IV: Innovations in Biomass Conversion for Heat, Power, Fuels and Chemicals Proceedings Spring 6-12-2013 Lignin conversion into bio-based
More informationRenewable Energy Systems
Renewable Energy Systems 9 Buchla, Kissell, Floyd Chapter Outline Biomass Technologies 9 9-1 THE CARBON CYCLE 9-2 BIOMASS SOURCES 9-3 BIOFUELS: ETHANOL 9-4 BIOFUELS: BIODIESEL AND GREEN DIESEL 9-5 BIOFUELS
More informationCORBION: DEVELOPING A BIOBASED PORTFOLIO
CORBION: DEVELOPING A BIOBASED PORTFOLIO Hans van der Pol, Ph.D. Strategic Marketing Director New Business Ventures Bio 2014 Philadelphia May 12 15, 2014 Corbion Purac profile o Corbion: A Dutch multinational
More informationGCE Environmental Technology. Energy from Biomass. For first teaching from September 2013 For first award in Summer 2014
GCE Environmental Technology Energy from Biomass For first teaching from September 2013 For first award in Summer 2014 Energy from Biomass Specification Content should be able to: Students should be able
More informationBiofuel production using total sugars from lignocellulosic materials. Diego Alonso Zarrin Fatima Szczepan Bielatowicz Oda Kamilla Eide
Biofuel production using total sugars from lignocellulosic materials Diego Alonso Zarrin Fatima Szczepan Bielatowicz Oda Kamilla Eide scope of the presentation 1. Available lignocellulosic materials 2.
More informationShodex HPLC approach for biomass related analysis
Shodex HPLC approach for biomass related analysis Kanna Ito, Shodex /Showa Denko America, Inc. Data provided by Showa Denko K.K. Introduction: Biomass is a renewable energy source obtained from biological
More informationComparison of Laboratory and Industrial Saccharomyces cerevisiae Strains for Their Inhibitor Resistance and Xylose Utilization
Comparison of Laboratory and Industrial Saccharomyces cerevisiae Strains for Their Inhibitor Resistance and Xylose Utilization Geng Anli*, Wang Zhankun, Lai Kok Soon and Tan Wei Yi Mark, Goh Kiow Leng
More informationGHG savings with 2G Ethanol Industrial Plant. Pierluigi Picciotti BD Director North America & APAC July 26 th, 2017 Montreal
GHG savings with 2G Ethanol Industrial Plant Pierluigi Picciotti BD Director North America & APAC July 26 th, 2017 Montreal 1 Beta Renewables Introduction Beta Renewables is a joint venture, created in
More informationSteam Pretreatment Optimisation for Sugarcane Bagasse in Bioethanol Production
Steam Pretreatment Optimisation for Sugarcane Bagasse in Bioethanol Production Johan Sendelius Master of Science Thesis 2005 Department of Chemical Engineering, Lund University, Sweden Abstract: Steam
More informationBioeconomy Transformation summary of the bioeconomy activities at VTT
VTT TECHNICAL RESEARCH CENTRE OF FINLAND LTD Bioeconomy Transformation summary of the bioeconomy activities at VTT Bio4Fuels Days 2017: Scientific meeting November 2-3, 2017 Trondheim Research Professor
More informationMikko Hupa Åbo Akademi Turku, Finland
Åbo Akademi Chemical Engineering Department Course The Forest based Biorefinery Chemical and Engineering Challenges and Opportunities May 3-7, 2010 Thermal conversion of biomass Mikko Hupa Åbo Akademi
More informationExtraction of high molecular mass hemicelluloses prior to ethanol production. Alkali steam pretreatment of wheat and barley straw. Elisabeth Joelsson
Extraction of high molecular mass hemicelluloses prior to ethanol production Alkali steam pretreatment of wheat and barley straw Elisabeth Joelsson Department of Chemical Engineering Lund University P.O.
More informationStudy of Different Bio-Processing Pathways in a Lignocellulosic Biorefinery by Process Simulation
A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 35, 2013 Guest Editors: Petar Varbanov, Jiří Klemeš, Panos Seferlis, Athanasios I. Papadopoulos, Spyros Voutetakis Copyright 2013, AIDIC Servizi
More informationPERP Program - Ethanol New Report Alert
PERP Program - Ethanol New Report Alert February 2006 Nexant s ChemSystems Process Evaluation/Research Planning program has published a new report, Ethanol (04/05-8). To view the table of contents or order
More informationButanol Fermentation from Low-Value Sugar-Based Feedstocks by Clostridia
Clostridium XII, 1 Sept. 2, Nottingham, UK Butanol Fermentation from Low-Value Sugar-Based Feedstocks by Clostridia Ye Ni, Zhihao Sun School of Biotechnology, Jiangnan University Wuxi, China 2.9.1 Clostridium
More informationRAW MATERIALS IN POLYMER TECHNOLOGY
RAW MATERIALS IN POLYMER TECHNOLOGY Polymer science and technology I March 5, 2018 Petrochemical or fossil plastics are made of fossil feedstocks like petroleum and natural gas which has taken millions
More informationNovel carbon-based catalysts as a part of biomass value chain. Riikka Lahti Kokkola University Consortium Chydenius Kokkola Material Week
Novel carbon-based catalysts as a part of biomass value chain Riikka Lahti Kokkola University Consortium Chydenius 31.10.2017 Kokkola Material Week Carbon sources from lignocelluloses Finland is one of
More informationLignocellulosic biorefinery pathways to biobased chemicals and materials
Lignocellulosic biorefinery pathways to biobased chemicals and materials 1 st Int. Forest Biorefinery Conference, Thunder Bay, Canada May 9-11, 2017 Richard Gosselink, Carmen Boeriu, Paulien Harmsen, Jeroen
More informationMobilisation and utilisation of recycled wood for lignocellulosic(lc)bio-refinery processes. Dr. Guido Hora, Fraunhofer WKI, GERMANY
ReWoBioRef Mobilisation and utilisation of recycled wood for lignocellulosic(lc)bio-refinery processes Dr. Guido Hora, Fraunhofer WKI, GERMANY Background and objectives There will be a growing demand within
More informationHYBRID STAGED THERMOLYSIS TO VALORISE BIOMASS Paul de Wild, March 11, 2009
HYBRID STAGED THERMOLYSIS TO VALORISE BIOMASS Paul de Wild, March 11, 2009 Bioenergy - II: Fuels and Chemicals from Renewable Resources March 8-13, 2009, Rio de Janeiro, Brazil INTRODUCTION Lignocellulosic
More information2015 AQ Summit: Research Update by Peter Van Walsum
The University of Maine DigitalCommons@UMaine Annual Maine Aquaculture R&D and Education Summits Conferences and Summits 1-14-2015 2015 AQ Summit: Research Update by Peter Van Walsum Peter Van Walsum Follow
More informationMild fractionation of wood and plants into G2 Micro Cellulose and Lignine
Mild fractionation of wood and plants into G2 Micro Cellulose and Lignine BIOeCON G2 technology unique, simple, and cost effective Internationaal Innovatie-evenement papieren kartonketen February 1, 2017,
More informationCOMPARISON OF DIFFERENT PRETREATMENT METHODS ON DEGRADATION OF RYE STRAW
COMPARISON OF DIFFERENT PRETREATMENT METHODS ON DEGRADATION OF RYE STRAW Marti Tutt, Timo Kikas, Juri Olt Estonian University of Life Sciences marti.tutt@emu.ee Abstract. This article investigates the
More informationWageningen UR (University & Research centre)
Wageningen UR (University & Research centre) For quality of life Jan E. G. van Dam Wageningen UR mission To explore the potential of nature to improve the quality of life Three partners Wageningen University
More informationBIOMASS (TO BIOETHANOL) SUPPLY CHAIN DESIGN AND OPTIMISATION
Proceedings of the 14 th International Conference on Environmental Science and Technology Rhodes, Greece, 3-5 September 2015 BIOMASS (TO BIOETHANOL) SUPPLY CHAIN DESIGN AND OPTIMISATION DANIA K. 1, DRAKAKI
More informationProduction of xylitol from biomass using an inhibitor-tolerant fungus
Production of xylitol from biomass using an inhibitor-tolerant fungus Nancy Nichols National Center USDA ARS National Center for Agricultural Utilization Research Peoria IL USA Peoria, IL Biomass conversion
More informationXylitol production from lignocellulosic hydrolysates
Xylitol production from lignocellulosic hydrolysates Young-Jae Jeon a, Hyoun-Sung Shin b and Peter L. Rogers a a : School of Biotechnology and Biomolecular Sciences The University of New South Wales b
More informationREDEFINERY: A Large scale Biorefinery Cluster Initiative
REDEFINERY: A Large scale Biorefinery Cluster Initiative Presentation: 1. Short Intro to BBD 2. REDEFINERY Aldert van der Kooij Agro meets Chemistry The conversion of lignocellulose into chemical building
More informationPotential of Bioethanol Production and Optimization Test from Agricultural Waste: The Case of Wet Coffee Processing Waste (Pulp)
Potential of Bioethanol Production and Optimization Test from Agricultural Waste: The Case of Wet Coffee Processing Waste (Pulp) Ayele Kefale*, Mesfin Redi**, Araya Asfaw*** *Environmental Science Program,
More informationOutline. Comparative Fast Pyrolysis of Agricultural Residues for Use in Biorefineries. ECI Bioenergy-II:
Comparative Fast Pyrolysis of Agricultural Residues for Use in Biorefineries Institute for Wood Technology and Wood Biology, amburg e ECI Bioenergy-II: Fuels and Chemicals from Renewable Resources Rio
More informationTechnical background on the LanzaTech Process
Technical background on the LanzaTech Process Introduction LanzaTech s gas fermentation process is a new approach to reduce CO 2 emissions while producing low carbon liquid fuels and chemicals. The technology
More informationLignocellulosic conversion to ethanol: the environmental life cycle impacts
Lignocellulosic conversion to ethanol: the environmental life cycle impacts Aiduan Li, Marcelle C McManus, Geoff P Hammond Sustainable Energy Research Team University of Bath United Kingdom Contents Sustainable
More informationCommercial Lignin: Co-product Of Cellulosic Sugar Production
Commercial Lignin: Co-product Of Cellulosic Sugar Production Not All Lignins Are Created Equal Fred Moesler Chief Technology Officer, Renmatix May 13, 2015 Economically Deconstructing Biomass to Valuable
More informationRecent Developments and Current Situation of Cellulosic Ethanol R&D in Brazil
Recent Developments and Current Situation of Cellulosic Ethanol R&D in Brazil Research Center in Applied Chemistry Department of Chemistry Federal University of Paraná (UFPR), Brazil www.quimica.ufpr.br/paginas/luiz-ramos
More informationWhat is Bioenergy? William Robinson B9 Solutions Limited
What is Bioenergy? William Robinson B9 Solutions Limited Contents Introduction Defining Bioenergy Biomass Fuels Energy Conversion Technologies Conclusion Introduction William Robinson B9 employee for nearly
More informationSimulation of the BioEthnaol Process
Ian David Lockhart Bogle and Michael Fairweather (Editors), Proceedings of the 22nd European Symposium on Computer Aided Process Engineering, 17-20 June 2012, London. 2012 Elsevier B.V. All rights reserved.
More informationValue creation in bio-energy
Value creation in bio-energy Steve Hartig President Biofuels at DSM Bio-Based Products & Services Carnegie Biofuels seminar - December 11, 2012 Copenhagen Safe harbor statement This presentation may contain
More informationHYDROCONVERSION OF FAST PYROLYSIS BIO-OIL: UNDERSTANDING AND LIMITING MACROMOLECULES FORMATION. Alain Quignard / IFPEN
Flash Pyrolysis Flash Pyrolysis Flash Pyrolysis 2 step HDT 1) Stabilization 2) Hydroconversion Flash Pyrolysis HYDROCONVERSION OF FAST PYROLYSIS BIO-OIL: UNDERSTANDING AND LIMITING MACROMOLECULES FORMATION
More informationCorn Wet Mill Improvement and Corn Dry Mill Improvement Pathways Summary Description
Corn Wet Mill Improvement and Corn Dry Mill Improvement Pathways Summary Description DE Pathway bjectives The Biomass Program objective for both the corn wet mill and dry mill pathways is to improve the
More informationTOWARDS SUSTAINABLE AND EFFICIENT BIOFUELS PRODUCTION USE OF PERVAPORATION IN PRODUCT RECOVERY AND SEPARATION
1 TOWARDS SUSTAINABLE AND EFFICIENT BIOFUELS PRODUCTION USE OF PERVAPORATION IN PRODUCT RECOVERY AND SEPARATION POKE Summer School 10. 16.8.2014 Saaremaa, Estonia D.Sc.(Tech.) Johanna Niemistö FACULTY
More informationNovel Ni-based catalysts for the hydrotreatment of fast pyrolysis oil
Engineering Conferences International ECI Digital Archives BioEnergy IV: Innovations in Biomass Conversion for Heat, Power, Fuels and Chemicals Proceedings Spring 6-11-2013 Novel Ni-based catalysts for
More informationOn the Road to a New Sweet Sorghum Industry in the USA
On the Road to a New Sweet Sorghum Industry in the USA Gillian Eggleston 1 and Matthew Heckemeyer 2 1 Lead Scientist Sugar & Energy CRIS Project USDA-ARS-SRRC New Orleans, LA, USA 2 CEO Heckemeyer Mill
More informationProduct and chain development for Oil Palm
Product and chain development for Oil Palm Bio-based materials and renewable energy 26 09 06 Jan E.G van Dam Div Biobased Products Wageningen UR Bio-based economy.the solution for sustainable developments...?...
More informationBiorefinery, the bridge between Agriculture and Chemistry
Biorefinery, the bridge between Agriculture and Chemistry Gent 19 September 2005 Johan Sanders Professor Valorisation of Plant Production Chains Wageningen University and Researchcenter Energy consumption
More informationPyNe -- Innsbruck WP 2A Pyrolysis Biorefinery
PyNe -- Innsbruck WP 2A Pyrolysis Biorefinery Doug Elliott September 28, 2005 Presentation Organization Biorefinery basics U.S. Department of Energy program Earlier PyNe efforts Other Biorefinery concepts
More informationFrom Initiative to Institute April 8, Hemant Pendse, Managing Director
FBRI Pulp & Paper Foundation Paper Days: From Initiative to Institute April 8, 2009 Hemant Pendse, Managing Director FBRI s Core Research From the forest floor to the factory floor, researchers, students,
More informationBackgrounder. Raw material change at BASF. Natural gas, biomass and carbon dioxide can supplement crude oil as a raw material for chemical production
Backgrounder Raw material change at BASF Natural gas, biomass and carbon dioxide can supplement crude oil as a raw material for chemical production March 2014 P 075/14e Christian Böhme Telefon: +49 621
More informationBiomass as a Source of Carbon: The Conversion of Renewable Feedstocks into Chemicals and Materials
Biomass as a Source of Carbon: The Conversion of Renewable Feedstocks into Chemicals and Materials Joseph J. Bozell University of Tennessee Knoxville, TN The exceptional current interest in biorefinery
More informationA Comparison of Dilute Sulfuric and Phosphoric Acid Pretreatments in Biofuel Production from Corncobs
A Comparison of Dilute Sulfuric and Phosphoric Acid Pretreatments in Biofuel Production from Corncobs Jirakarn Nantapipat, Apanee Luengnaruemitchai, and Sujitra Wongkasemjit Abstract Biofuels, like biobutanol,
More informationCellulosic and starch-based Raw Materials in Ethanol Production
Cellulosic and starch-based Raw Materials in Ethanol Production 2. European Bioethanol Technology Meeting Detmold (Germany) April 25-26, 2006 Sven Fleischer and Thomas Senn Technology with Education and
More informationContinuous Countercurrent Extraction of Hemicellulose from Pretreated Wood Residues
Copyright Extraction 2001 of Hemicellulose by Humana Press Inc. 253 All rights of any nature whatsoever reserved. 0273-2289/01/91 93/0253/$13.75 Continuous Countercurrent Extraction of Hemicellulose from
More informationINTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING
INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING V o l u m e 7 2009 Article A78 Bioenergy II: Bio-Ethanol from Municipal Solid W a s t e (MSW): The UK P o t e n t i a l and Implication f o r Sustainable
More informationOptimization of Controlled ph Liquid Hot Water Pretreatment of Corn Fiber and Stover
Optimization of Controlled ph Liquid Hot Water Pretreatment of Corn Fiber and Stover Nathan Mosier, Rick Hendrickson, Youngmi Kim, Meijuan Zeng, Bruce Dien, Gary Welch, Charles Wyman and Michael Ladisch
More informationProduction of bio-based chemicals and polymers from industrial waste and byproduct streams
Section II. Developments in biorefinery: feedstocks, processes and products (I) Production of bio-based chemicals and polymers from industrial waste and byproduct streams Apostolis Koutinas Group of Food
More informationEthanol from lignocellulosic biomass: a comparison between conversion technologies
17 th European Symposium on Computer Aided Process Engineering ESCAPE17 V. Plesu and P.S. Agachi (Editors) 2007 Elsevier B.V. All rights reserved. 1 Ethanol from lignocellulosic biomass: a comparison between
More informationTorrefaction to Improve Biomass for Energy and Biofuels Production and Carbon Sequestion. Chris Hopkins, Research Associate
Torrefaction to Improve Biomass for Energy and Biofuels Production and Carbon Sequestion Chris Hopkins, Research Associate Funding Sources and Partners North Carolina State University Golden LEAF Foundation
More informationNordic Association of Agricultural Scientists
NJF Report Vol 3 No 4 Year 2007 Nordic Association of Agricultural Scientists NJF Seminar 405 Production and Utilization of Crops for Energy Vilnius, Lithuania, 25-26 September 2007 Straw biomass potential
More informationBrasil EU Workshop Gasification of bagasse to syngas and advanced liquid fuel production. December 8 th 2015 São Paulo, Brasil Martin van t Hoff
Brasil EU Workshop Gasification of bagasse to syngas and advanced liquid fuel production December 8 th 2015 São Paulo, Brasil Martin van t Hoff ECN & Royal Dahlman A 15 year relationship in R&D, Engineering
More informationClearFuels Technology Inc.
ClearFuels Technology Inc. Hawai i Energy Policy Forum Wednesday, October 12, 2005 -- 10:00 a.m. - 2:30 p.m. Production of Ethanol from Biomass Enabling Highly Efficient Low Cost Sustainable Energy Production
More informationDriving on sunshine, converting seaweed to furanic biofuels
Driving on sunshine, converting seaweed to furanic biofuels J.W. van Hal G. van Hees mw E.M Cobussen - Pool Huijgen, W.J.J. Juni 2017 ECN-L--17-022 Presented at the 6 th Congress of the International Society
More informationTowards Sustainable Production of Biofuels: the Eni s Way
Towards Sustainable Production of Biofuels: the Eni s Way Resource Efficiency e Sustainable Development Goals: il ruolo del Life Cycle Thinking Siena, 22-23 Giugno 2017 Alberto Delbianco (SVP DOW R&D),
More informationbio-oil produced from composted lignocellulosic biomass
bio-oil produced from composted lignocellulosic biomass D. Kpogbemabou, R. Beauchet, L. Pinard, L. Lemée laurent.lemee@univ-poitiers.fr http://ic2mp.labo.univ-poitiers.fr Athens 2017 1 Climate change The
More information11.3 Gross Income, net cash flow and economic criteria Net present and net future values Sensitivities Conclusions and
Table of Contents Summary iii 1 Introduction... 1 2 Process options and selection... 2 2.1 Process Concept Chosen... 2 3 Basis of design... 5 3.1 Boundary conditions... 5 3.2 Continuous, batch, combination...
More information