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1 EQUIP OD45 2X10L JUG FR 1/7 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product information Trade name EQUIP OD45 2X10L JUG FR Product code (UVP) Product code AE F K05 A9 Usage herbicide Company Bayer CropScience AG Alfred-Nobel-Straße Monheim Germany Telephone +49(0) Telefax +49(0) Responsible Department Material and Transport Safety Management +49(0) /12588 Emergency telephone number +49(0) (Sicherheitszentrale Dormagen, Bayer AG) 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Oil dispersion (OD) Foramsulfuron + Isoxadifen-ethyl (22,5 + 22,5 g/l) Hazardous components Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%] EINECS-No. Isoxadifen-ethyl Xn, N R22, R43, 2,50 R50/53 Foramsulfuron ,40 Solvent Naphtha (petroleum), Xn, N R51/53, R65, >= 10,00 heavy aromatic R66 Calcium Xi, N R38, R41, >= 1,00-5,00 dodecylbenzenesulfonate, branched R51/53 1-Octanol Xi R36/37/38 >= 1,00-5,00 3. HAZARDS IDENTIFICATION Risk advice to man and the environment Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES

2 EQUIP OD45 2X10L JUG FR 2/7 Inhalation Remove to fresh air. Keep patient warm and at rest. Consult a physician after significant exposure. Skin contact Take off all contaminated clothing immediately. Wash off with soap and water. If skin irritation persists, call a physician. Eye contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Protect unharmed eye. Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Call a physician immediately. Notes to Physician Symptoms May cause skin and eye irritation. Treatment Elementary aid, decontamination and symptomatic treatment. In the event of a mouthful or more being ingested, the following measures should be considered: If ingested, irrigate the stomach using activated charcoal in addition. Elimination by dialysis (forced alkaline diuresis). 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media water spray alcohol-resistant foam dry powder carbon dioxide (CO2) Extinguishing media which must not be used for safety reasons high volume water jet Specific hazards during fire fighting In the event of fire the following can be released: carbon monoxide (CO) nitrogen oxides (NOx) hydrogen chloride (HCl) Special protective equipment for fire-fighters Wear full protective suit. In the event of fire, wear self-contained breathing apparatus. Further information Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES

3 EQUIP OD45 2X10L JUG FR 3/7 Personal Precautions Evacuate personnel to safe areas. Use personal protective equipment. Remove all sources of ignition. Environmental Precautions Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Methods for Cleaning Up Take up with absorbent material (e.g. sand, earth or a proprietary absorbent material). Keep in suitable, closed containers for disposal. Additional Advice Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section HANDLING AND STORAGE Handling Advice on safe handling Use only in area provided with appropriate exhaust ventilation. Advice on protection against fire and explosion The product is neither sensitive to impacts nor to rub effects and is therefore not explosive. Storage Requirements for storage areas and containers Store in original container. Keep tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Protect against frost. Advice on common storage Keep away from food, drink and animal feedingstuffs. German storage class 12 Non Combustible Liquids Storage stability Storage period > 24 Months Storage temperature 2-30 C Other data The storage temperature should lie between 0 C and 30 C, maximum up to 50 C. Suitable materials Plastic container of HDPE 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Control parameters Update Basis Solvent Naphtha (petroleum), 200 mg/m3 (MAK) TRGS 900 heavy aromatic

4 EQUIP OD45 2X10L JUG FR 4/7 Engineering measures See chapter 7; no measures exceeding those mentioned are necessary. Personal protective equipment Respiratory Protection Short term: filter apparatus, Filter A/P2 Hand Protection Eye protection Skin and body protection PVC or nitrile rubber gloves Safety glasses / face shield protective suit Hygiene measures When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. Protective measures Avoid contact with skin and eyes. Do not inhale aerosols 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form liquid Colour light yellow to brownish Odour aromatic Safety data ph 5,2 (1% in distilled water) Flash Point > 110 C DIN EN ISO 2719 ( ) Density 0,9652 g/cm³ at 20 C Water Solubility dispersible Viscosity, kinematic 36 mm2/s at 40 C Shear stress of 20/sec Surface tension 29,6 mn/m at 40 C Explosivity The product is not explosive. 10. STABILITY AND REACTIVITY Hazardous Reactions None known. Stable under recommended storage conditions.

5 EQUIP OD45 2X10L JUG FR 5/7 11. TOXICOLOGICAL INFORMATION Acute Oral Toxicity LD50 (rat) > mg/kg Acute Inhalation Toxicity Acute Dermal Toxicity Skin Irritation Eye Irritation Sensitization LC50 (rat) > 5,25 mg/l LD50 (rat) > mg/kg irritating (rabbit) slight irritant effect - does not require labelling (rabbit) Non-sensitizing (guinea pig) OECD 406, Buehler test Further information The following toxicological data shown are those obtained from tests on products of similar composition. 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to Fish Toxicity to daphnia Toxicity to algae LC50 (Rainbow trout (Oncorhynchus mykiss)) 14 mg/l Exposure time: 96 h EC50 (Water flea (Daphnia magna)) 6,9 mg/l Exposure time: 48 h EC50 (Selenastrum capricornutum) > 5 mg/l Exposure time: 96 h Further information on ecology Additional ecological information The ecotoxicological data refer to a similar formulation. 13. DISPOSAL CONSIDERATIONS Product Do not dispose of waste into sewer. Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. Contaminated packaging Rinse empty containers with water and use the rinse-water to prepare the working solution. Empty containers should be taken for local recycling or waste disposal. Packaging that cannot be cleaned should be disposed of as product waste. Waste key for the unused product agrochemical waste containing dangerous substances 14. TRANSPORT INFORMATION

6 EQUIP OD45 2X10L JUG FR 6/7 ADR/RID/ADNR UN-No 3082 Labels 9 Packaging group III Hazard no. 90 Description of the goods IMDG UN-No 3082 Class 9 Packaging group III EmS F-A, S-F Marine pollutant Description of the goods IATA UN-No 3082 Class 9 Packaging group Description of the goods UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOXADIFEN-ETHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC SOLUTION) Marine pollutant ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOXADIFEN-ETHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC SOLUTION ) III ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ISOXADIFEN-ETHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY AROMATIC SOLUTION ) 15. REGULATORY INFORMATION Classification and labelling in accordance with the EC Directive on dangerous preparations 1999/45/EC as amended. Classification: Hazard warning labelling compulsory Hazardous components which must be listed on the label: Isoxadifen-ethyl Foramsulfuron Symbol(s) Xi Irritant N Dangerous for the environment R-phrase(s) R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) S35 This material and its container must be disposed of in a safe way. S57 Use appropriate container to avoid environmental contamination.

7 EQUIP OD45 2X10L JUG FR 7/7 Exceptional labelling To avoid risks to man and the environment, comply with the instructions for use. Contains isoxadifen-ethyl. May produce an allergic reaction. National legislation Water contamination class (Germany) Major Accident Hazard Legislation WGK 2 water endangering Classification according to VwVwS, Annex 4 Subjected to the "Disasters and Major Accidents Act " 96/82/EC Annex I, list of dangerous substances, No. 9i 16. OTHER INFORMATION Further information Text of R phrases mentioned in Section 2: R22 Harmful if swallowed. R36/37/38 Irritating to eyes, respiratory system and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. For further information on active ingredients see also: Wirkstoffe in Pflanzenschutz- und Schädlingsbekämpfungsmitteln: physikalisch-chemische und toxikologische Daten IVA, Industrieverb. Agrar e.v. - 3., neubearb. Aufl. - München; Wien; Zürich; BLV Verl.-Ges.mbH, 2000 ISBN The information given in this Data Sheet has been included in accordance with the guidelines established by EC Directive 1991/155/EC as amended. This data sheet complements the user's instructions, but does not replace them. The information it contains is based on the knowledge available about the product concerned at the time it was compiled. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The required information complies with current EEC legislation. Addressees are requested to observe any additional national requirements. This information is based on our present state of knowledge. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. Changes since the last version are highlighted in the margin. This version replaces all previous versions.

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