Safety Data Sheet Dry Vitamin D3 100 HP Revision date : 2017/02/03 Page: 1/11
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- Gwendoline Sims
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1 Revision date : 2017/02/03 Page: 1/11 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: food additive(s); Vitamin * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Synonyms: Preparation based on Vitamin D3 powder in a matrix of carbohydrates gelatin 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic Combustible Dust Combustible Dust (1) Combustible Dust Label elements Signal Word: Warning
2 Revision date : 2017/02/03 Page: 2/11 Hazard Statement: H402 H412 May form combustible dust concentration in air. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements (Prevention): P273 Avoid release to the environment. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified When finely distributed, self-ignition is possible. The product is under certain conditions capable of dust explosion. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name % BHT % Sucrose % starch 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. Assist in breathing if necessary. Consult a physician. If on skin: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. If irritation develops, seek medical attention. If swallowed: Rinse mouth and then drink plenty of water. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Seek medical attention if necessary. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known.
3 Revision date : 2017/02/03 Page: 3/11 Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, carbon dioxide, foam, dry powder Unsuitable extinguishing media for safety reasons: water jet Additional information: Avoid whirling up the material/product because of the danger of dust explosion. Special hazards arising from the substance or mixture Hazards during fire-fighting: carbon oxides, harmful vapours The substances/groups of substances mentioned can be released in case of fire. Burning produces harmful and toxic fumes. Dust explosion hazard. Advice for fire-fighters Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. Further information: Dusty conditions may ignite explosively in the presence of an ignition source causing flash fire. 6. Accidental release measures Further accidental release measures: Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Avoid the formation and build-up of dust - danger of dust explosion. Dust in sufficient concentration can result in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition. Personal precautions, protective equipment and emergency procedures Information regarding personal protective measures see, section 8. Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation. Do not breathe dust. Ensure adequate ventilation. Environmental precautions Do not discharge into drains/surface waters/groundwater. Inform authorities in the event of product spillage to water courses or sewage systems. Methods and material for containment and cleaning up For small amounts: Sweep/shovel up. For large amounts: Sweep/shovel up. Collect waste in suitable containers, which can be labeled and sealed.
4 Revision date : 2017/02/03 Page: 4/11 Dispose of absorbed material in accordance with regulations. Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. Spills should be contained and placed in suitable containers for disposal. Nonsparking tools should be used. 7. Handling and Storage Precautions for safe handling Avoid dust formation. Ensure thorough ventilation of stores and work areas. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts. Protection against fire and explosion: Avoid dust formation. Dust in sufficient concentration can result in an explosive mixture in air. Handle to minimize dusting and eliminate open flame and other sources of ignition. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Dry powders can build static electricity charges when subjected to the friction of transfer and mixing operations. Provide adequate precautions, such as electrical grounding and bonding, or inert atmospheres. Refer to NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids (2013 Edition) for safe handling. Conditions for safe storage, including any incompatibilities Segregate from strong bases. Segregate from strong oxidizing agents. Segregate from strong acids. Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Protect from the effects of light. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Sucrose OSHA PEL PEL 15 mg/m3 Total dust ; PEL 5 mg/m3 Respirable fraction ; TWA value 15 mg/m3 Total dust ; TWA value 5 mg/m3 Respirable fraction ; ACGIH TLV TWA value 10 mg/m3 ; starch OSHA PEL PEL 15 mg/m3 Total dust ; PEL 5 mg/m3 Respirable fraction ; TWA value 15 mg/m3 Total dust ; TWA value 5 mg/m3 Respirable fraction ; ACGIH TLV TWA value 10 mg/m3 ; Advice on system design: It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion suppression system or an oxygen deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). Use only appropriately classified electrical equipment and powered industrial trucks. Personal protective equipment Respiratory protection: Wear a NIOSH-certified (or equivalent) particulate respirator.
5 Revision date : 2017/02/03 Page: 5/11 Hand protection: Chemical resistant protective gloves Eye protection: Wear safety goggles (chemical goggles) if there is potential for airborne dust exposures. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Wear protective clothing as necessary to prevent contact. Avoid inhalation of dust. Wash soiled clothing immediately. Hands and/or face should be washed before breaks and at the end of the shift. No eating, drinking, smoking or tobacco use at the place of work. Remove contaminated clothing. 9. Physical and Chemical Properties Form: Odour: Odour threshold: Colour: ph value: Melting point: Boiling point: Flash point: Flammability: Flammability of Aerosol Products: Lower explosion limit: Upper explosion limit: Autoignition: Vapour pressure: Bulk density: Vapour density: Partitioning coefficient n- octanol/water (log Pow): Self-ignition temperature: Thermal decomposition: Viscosity, dynamic: Solubility in water: Evaporation rate: powder odourless not applicable, odour not perceivable white not determined not applicable not applicable not applicable, the product is a solid No data available. not applicable, the product does not form flammable aerosoles For solids not relevant for classification and labelling. For solids not relevant for classification and labelling. No data available. negligible approx. 0.6 g/cm3 negligible not applicable for mixtures not self-igniting No data available. not applicable, the product is a solid ( C) emulsifiable negligible 10. Stability and Reactivity Reactivity Corrosion to metals: No corrosive effect on metal. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing.
6 Revision date : 2017/02/03 Page: 6/11 Chemical stability Possibility of hazardous reactions Dust explosion hazard. Conditions to avoid Avoid dust formation. Avoid all sources of ignition: heat, sparks, open flame. Avoid humidity. Incompatible materials No substances known that should be avoided. Hazardous decomposition products Decomposition products: No hazardous decomposition products known. Thermal decomposition: No data available. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Assessment of acute toxicity:virtually nontoxic after a single ingestion. Assessment of acute toxicity:of very high toxicity after short-term inhalation. Of very high toxicity after short-term skin contact. Of very high toxicity after single ingestion. Oral Type of value: LD50 Species: rat Value: mg/kg Literature data. Inhalation Type of value: LC50 Species: rat Value: approx mg/l Exposure time: 4 h
7 Revision date : 2017/02/03 Page: 7/11 Tested as dust aerosol. Literature data. The EU classification 'very toxic by inhalation' obtained from examination with inhalable aerosol. Dermal Type of value: LD50 Species: rat Value: mg/kg Literature data. Irritation / corrosion Assessment of irritating effects: Not irritating to the skin. Not irritating to the eyes. Assessment of irritating effects: Not irritating to the skin. Not irritating to the eyes. Assessment of irritating effects: Not irritating to the skin. Not irritating to the eyes. Sensitization Assessment of sensitization: No data available. Assessment of sensitization: The chemical structure does not suggest a sensitizing effect. Assessment of sensitization: No sensitizing effect. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: No known chronic effects. Assessment of repeated dose toxicity: The substance may cause damage to the liver after repeated ingestion of high doses, as shown in animal studies. Repeated exposure may cause adverse thyroid effects as indicated in animal studies. Prolonged and repeated exposure may cause lung damage. May cause liver and kidney damage. Assessment of repeated dose toxicity: Repeated oral exposure to small quantities may affect certain organs. The substance may cause damage to the kidney even after repeated ingestion of low doses, as shown in animal studies. The substance may cause damage to blood vessels even after repeated ingestion of low doses, as shown in animal studies. Genetic toxicity Assessment of mutagenicity: Mutagenicity tests revealed no genotoxic potential.
8 Revision date : 2017/02/03 Page: 8/11 Assessment of mutagenicity: Results from a number of genotoxicity studies with microorganisms, mammalian cell culture and mammals are available. Taking into account all of the information, there is no indication that the substance is genotoxic. Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria, microorganims and mammalian cell culture. Literature data. Carcinogenicity Assessment of carcinogenicity: The substance caused cancer in animal studies. The International Agency for Research on Cancer (IARC) has classified this substance as group 3, not classifiable as to its carcinogenicity to humans. Reproductive toxicity Assessment of reproduction toxicity: No data available. Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. Teratogenicity Assessment of teratogenicity: No data available. Other Information The product has not been tested. The statement has been derived from the properties of the individual components. Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely harmful for aquatic organisms. May cause long-term adverse effects in the aquatic environment. Aquatic toxicity
9 Revision date : 2017/02/03 Page: 9/11 Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. The product has not been tested. It is a naturally occuring substance (e.g. in the metabolism of organisms), whose molecular structure is not supposed to have harmful effects. Toxicity to fish LC0 (96 h) >= 0.57 mg/l, Brachydanio rerio (OECD 203; ISO 7346; 84/449/EEC, C.1, semistatic) The statement of the toxic effect relates to the analytically determined concentration. Limit concentration test only (LIMIT test). LC50 (96 h) > 10,000 mg/l, Leuciscus idus (DIN Part 15, static) The product has low solubility in the test medium. An aqueous dispersion has been tested. Tested above maximum solubility. The details of the toxic effect relate to the nominal concentration. Aquatic invertebrates EC0 (48 h) 0.48 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The statement of the toxic effect relates to the analytically determined concentration. EC50 (48 h) > 100 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) The product has low solubility in the test medium. An eluate has been tested. The details of the toxic effect relate to the nominal concentration. No toxic effects occur within the range of solubility. Aquatic plants EC50 (72 h) > 0.40 mg/l (growth rate), Scenedesmus subspicatus (Guideline 92/69/EEC, C.3, static) The statement of the toxic effect relates to the analytically determined concentration. EC50 (96 h) > 0.17 mg/l (growth rate), Selenastrum capricornutum (OECD Guideline 201, static) The product has low solubility in the test medium. An eluate has been tested. No toxic effects occur within the range of solubility. The statement of the toxic effect relates to the analytically determined concentration. No observed effect concentration (96 h) 0.17 mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201, static) The statement of the toxic effect relates to the analytically determined concentration. The product has low solubility in the test medium. An eluate has been tested. No toxic effects occur within the range of solubility. Persistence and degradability Assessment biodegradation and elimination (H2O) Biodegradable.
10 Revision date : 2017/02/03 Page: 10/11 Not readily biodegradable (by OECD criteria). Poorly biodegradable. Not readily biodegradable (by OECD criteria). Poorly biodegradable. Bioaccumulative potential Bioaccumulation potential Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Bioconcentration factor: 30-48, Fish (calculated) Mobility in soil Assessment transport between environmental compartments No data available. Additional information Other ecotoxicological advice: The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components. 13. Disposal considerations Waste disposal of substance: Do not discharge substance/product into sewer system. Dispose of in accordance with national, state and local regulations. Container disposal: Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations
11 Revision date : 2017/02/03 Page: 11/11 Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed Food DSL, CA released / listed 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2017/02/03 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. END OF DATA SHEET
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