MATERIAL SAFETY DATA SHEET

Transcription

1 NIPPON CHEMICAL INDUSTRIAL CO., LTD. Page 1 5 MATERIAL SAFETY DATA SHEET [ HISHICOLIN PX-4MI ] MSDS No.: Established: 09/07/2005 Revised: 10/24/ CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME (GRADES): HISHICOLIN PX-4MI NAME OF MANUFACTURER: NIPPON CHEMICAL INDUSTRIAL CO., LTD. HEAD OFFICE (ADDRESS): 11-1, 9-chome, Kameido, Koto-ku, Tokyo, , Japan NAME OF SECTION: Organic Chemicals Sales Dept., Organic Chemicals Division TEL , FAX EMERGENCY TELEPHONE: Same phone number listed above 2. COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE OR PREPARATION: Substance CHEMICAL NAME(GENERIC NAME): Methyltri-n-butylphosphonium iodide INGREDIENTS AND COMPOSITION: min 98% CHEMICAL FORMULA: (C4H9)3 CH3P + I- CAS No.: JAPANESE OFFICIAL GAZETTE SERIAL No.: (2)-4016 TSCA INVENTORY: Not registered EINECS No.: Not registered INGREDIENTS CONTRIBUTING TO THE HAZARD: Methyltri-n-butylphosphonium iodide INPURITIES CONTRIBUTING TO THE HAZARD: None 3. HAZARDS IDENTIFICATION MOST IMPORTANT HAZARDS: Irritant HUMAN HEALTH: Have acute toxicity. Irritating to skin, mucous membrane. ENVIRONMENTAL EFFECT: Have no biodegradation. PHYSICAL AND CHEMICAL HAZARDS: It may be dust explosion. 4. FIRST-AID MEASURES INHALATION: Immediately have the victim rest covered with blanket and move to a place under fresh air and consult with a physician as soon as possible. In case of respiratory distress or arrest, immediately give rescue breathing to the victim. If inhaled, remove to fresh air. Use a bag valve mask or similar device to perform artificial respiration (rescue breathing) if needed. Get medical attention.

2 NIPPON CHEMICAL INDUSTRIAL CO., LTD. Page 2 5 SKIN CONTACT: Quickly take off the contaminated cloth or shoes, wash the part of adhesion with soap suds and wash away using a plenty of water, and immediately consult with a physician. EYE CONTACT: In case of contact, Wash with clean water for at least 15 minutes and consult with a physician. INGESTION: Administer salt water and force the victim to vomit and lower the body-intake as much as possible. 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Use carbon dioxide, dry chemical, water spray and sand. SPECIFIC HAZARDS: Combustion products are phosphorus pentoxide and carbon dioxide. PROTECTION FIRE-FIGHTERS: Use breathing equipment or gas helmet. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Wear proper protective equipm ent (gloves, safety goggles etc.) METHODS FOR CLEANING UP: Small spills: Carefully sweep up. Place in a bag and hold for waste disposal. Use suitable protective equipment (gloves, safety goggles etc.) Large spills: Cover with plastic sheet to minimize spreading and collect spilled material in appropriate container for disposal. 7. HANDLING AND STORAGE HANDLING: TECHNICAL MEASURES: PRECAUTIONS: SAFE HANDLIN G ADVICE: STORAGE: STORAGE CON DITIONS: INCOMPATIBLE PRODUCTS: PACKAGING MATERIALS: Do not get in eyes, on skin or on clothing. Wear proper protective equipment during use. Preclude generation of dusts of the product. Wear personal protective equipm ent. Store in a dark, cool place keeping isolated from inflamm able substances, combustible substances and explosive substances as avoiding mixing with oxidizing agents. Metals and bases Store in a glass jar or vinyl bag. Avoid contact with metallic container.

3 NIPPON CHEMICAL INDUSTRIAL CO., LTD. Page EXPOSURE CONTROL/PERSONAL PROTECTION ENGINEERING MEASURES: Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY PROTECTION: Use a dust-proof mask. HAND PROTECTION: Protective gloves EYE PROTECTION: Protective goggles or face mask SKIN AND BODY PROTECTION: It is desired to use dust-resisting protective equipment. HYGIENE MEASURES: Any air-purifying respirator with a full-face piece and an organic vapor canister. For Unknown Concentrations or Immediately Dangerous to Life or Health: Any supplied-air respirator with full-face piece and operated in a pressure demand or other positive-pressure mode in combination with a separate escape supply. Any self-contained breathing apparatus with a full-face piece. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Crystal COLOUR: White to slight yellow ODOR: Odorless ph VALUE: Not applicable MELTIN G POINT: 135 FLASH POINT: Non combustible (>240 ) DENSITY (POWDER): g/cm 3 (10 ) SOLUBILITY: Soluble in water (3% at 10 ), alcohols, acetone and chloroform. 10. PHYSICAL HAZARD (STABILITY & REACTIVITY) STABILITY: CONDITION TO AVOID: Sunlight or ultraviolet rays may cause sometimes color change of product. MATERIALS TO AVOID: Decomposed by bases. Metals are corroded for long term, changing product color. HAZARDOUS DECOMPOSITION PRODUCTS:

4 NIPPON CHEMICAL INDUSTRIAL CO., LTD. Page 4 5 Hydrogen iodide, phosphorus, phosphine gas 11. TOXICOLOGICAL INFORMATION ACUTE TOXICITY: ORAL: LOCAL EFFECTS: Skin sensitization test: Ames test: MUTAGENICITY: Ames test: 676mg/kg male mouse LD50 183mg/kg female mouse LD50 No findings Salmonella, bacillus coli; Negative Salmonella, bacillus coli; Negative 12. ECOLOGICAL INFORMATION PERSISTENCE/DEGRADABILITY: Not readily biodegradable. AQUATIC LIFE: Algae growth stunting EdC50 (72h); 83 mg/l EdC50 (0-72h); Not less than 160 mg/l NOEC; 10 mg/l Acute toxicity for water flea ECC50 (3h); 5.6 mg/l 95% Reliability limit; mg/l NOEC; 1.0 mg/l 13. DISPOSAL CONSIDERATION WASTE FROM RESIDUES: Whatever can not be saved for recovery may be burned in an approved incinerator or disposed in an approved waste facility. At that time, phosphorus pentoxide, hydrogen iodide, and carbon oxide are produced Ensure compliance with regional or national regulations. CONTAMINATED PACKAGING: Dispose according to regional or national regulations. 14. TRANSPORT INFORMATION INTERNATIONAL REGULATIONS: IMDG, IATA UN CLASS: 6.1 UN No.: 3464 (Organophosphorus compound, toxic, solid, n.o.s) PACKING GROUP: III SPECIFIC SAFETY MEASURES AND CONDITIONS FOR TRAN SPORT: 1) Shelter it from the sunlight and transport in a condition of the less than 40 C. 2) In the transporting; confirm no leakage from the container.

5 NIPPON CHEMICAL INDUSTRIAL CO., LTD. Page 5 5 Avoid the drop, fall, and shock. 3) Packing; Plastic container 4) Indication; HISHICOLIN PX-4MI, lot No., net weight, maker, and address. 15. REGULATORY INFORMATION REGULATIONS: LAW FOR SAFETY OF VESSELS: Enforcement regulation, Article 2 (Hazardous material), Notice; schedule No.4, Poison class AVIATION LAW: Enforcement regulation; Article 194, Notice; schedule No.9, Poison PORT REGURATION LAW: Enforcement regulation, Article 12, Notice; schedule (Has-Mat) 16. OTHER INFORMATION Notices 1) The Material Safety Data Sheet is a brief summary of general precautions necessary for proper use of Our Company Product. For a special use and handling, use upon safety confirmation and implementation of the measures suited to the application. 2) The contents entered into this sheet was prepared based on the documents and test data available at the time of preparation but does not guarantee at all the descriptions of Composition/Information on Ingredients, Physical & Chemical Properties and Hazards Identification. 3) Every chemical product may present unknown hazards and should be used with utmost caution. All users should bear the responsibility of setting of the safe use conditions. 4) The information herein is subject to change by new findings such as new literatures and test results and revisions of laws and regulations.