Hilti Firestop Intumescent Sealant CFS-IS; CP 611A

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1 Date of issue: 12/11/2015 Revision date: 12/11/2015 Supersedes: 01/12/2014 Version: 10.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Name Product code Mixture Hilti Firestop Intumescent Sealant CFS-IS; CP 611A BU Chemicals Product group Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Hilti (Aust.) Pty. Ltd. Level 5, 1G Homebush Bay Drive 2138 Rhodes - Australia T F serviceaustralia@hilti.com Supplier Hilti (Aust.) Pty. Ltd. Level 5, 1G Homebush Bay Drive 2138 Rhodes - Australia T F serviceaustralia@hilti.com Department issuing data specification sheet Hilti AG Feldkircherstraße Schaan - Liechtenstein T chemicals.hse@hilti.com 1.4. Emergency telephone number Emergency number Schweizerisches Toxikologisches Informationszentrum 24h Service (international) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Mixture/Substance: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Skin Sens. 1 Repr. 2 Aquatic Acute 3 Aquatic Chronic 3 Full text of hazard classes and H-statements : see section Label elements Labelling Hazard pictograms (GHS-UN) H317 H361 H402 H412 Signal word (GHS-UN) GHS07 Warning GHS08 12/11/2015 EN (English) 1/7

2 Hazardous ingredients Hazard statements (GHS-UN) Precautionary statements (GHS-UN) polypropylene glycol alkyl phenyl ether, Zinc borate H317 - May cause an allergic skin reaction H361 - Suspected of damaging fertility or the unborn child H412 - Harmful to aquatic life with long lasting effects P280 - Wear eye protection, protective clothing, protective gloves P308+P313 - IF exposed or concerned: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to the United Nations GHS (Rev. 4, 2011) Zinc borate (CAS ) Repr. 2, H361 Aquatic Chronic 2, H411 polypropylene glycol alkyl phenyl ether (CAS ) Skin Sens. 1B, H317 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion Get medical advice/attention if you feel unwell. Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact May cause an allergic skin reaction Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Self-contained breathing apparatus. Complete protective clothing. 12/11/2015 EN (English) 2/7

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders Protective equipment For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Recover mechanically the product. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures Wear personal protective equipment. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Keep cool. Store in a dry place. Storage temperature 5-25 C SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection Eye protection Skin and body protection Protective gloves. PICM009. Safety glasses. PICM004. Wear suitable protective clothing. PICM010. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Pasty. Molecular mass t determined Colour dark grey. Odour characteristic. Odour threshold t determined ph 8.5 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point 12/11/2015 EN (English) 3/7

4 Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 1.4 g/cm³ 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions dangerous reactions known under normal conditions of use Conditions to avoid ne under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Zinc borate ( ) LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation mg/kg (Rat) mg/kg (Rabbit) ph: 8.5 ph: 8.5 May cause an allergic skin reaction. 12/11/2015 EN (English) 4/7

5 Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Suspected of damaging fertility or the unborn child. SECTION 12: Ecological information Toxicity Ecology - general Zinc borate ( ) LC50 fish 1 The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 2.4 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) Persistence and degradability Zinc borate ( ) Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. Adsorbs into the soil Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste disposal recommendations Dispose of contents/container in accordance with licensed collector s sorting instructions. Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number t regulated for transport UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 12/11/2015 EN (English) 5/7

6 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport Carriage prohibited (ADN) t subject to ADN - Rail transport Carriage prohibited (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture 12/11/2015 EN (English) 6/7

7 SECTION 16: Other information Full text of H-statements: Aquatic Acute 3 Hazardous to the aquatic environment Acute Hazard, Category 3 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Repr. 2 Reproductive toxicity, Category 2 Skin Sens. 1 Sensitisation Skin, Category 1 Skin Sens. 1B Sensitisation Skin, category 1B H317 May cause an allergic skin reaction H361 Suspected of damaging fertility or the unborn child H411 Toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects SDS_UN_Hilti This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 12/11/2015 EN (English) 7/7

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