Version 2.2 Revision Date SECTION 1: Identification of the substance/mixture and of the company/undertaking
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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product information Product Name : Material : Company : Chevron Phillips Chemical Company LP Six Pines Drive The Woodlands, TX Emergency telephone: Health: (North America) (International) Transport: CHEMTREC or (int'l) Asia: CHEMWATCH ( ) China: EUROPE: BIG (phone) or (telefax) Mexico CHEMTREC (24 hours) South America SOS-Cotec Inside Brazil: Outside Brazil: Argentina: +(54) Responsible Department : Product Safety and Toxicology Group address : SDS@CPChem.com Website : SECTION 2: Hazards identification Classification of the substance or mixture This product has been classified in accordance with the hazard communication standard 29 CFR ; the SDS and labels contain all the information as required by the standard. Classification : Flammable gases, Category 1 Gases under pressure, Compressed gas Simple Asphyxiant Labeling SDS Number: /12
2 Symbol(s) : Signal Word : Danger Hazard Statements : H220: Extremely flammable gas. H280: Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. Precautionary Statements : Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. Response: P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely. P381 Eliminate all ignition sources if safe to do so. Storage: P410 + P403 Protect from sunlight. Store in a well-ventilated place. Carcinogenicity: IARC NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3: Composition/information on ingredients Synonyms : None established Molecular formula : UVCB Component CAS-No. Weight % Fuel Gas Hydrogen Ethylene Methane Ethane SECTION 4: First aid measures General advice : Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Wash off with soap and water. SDS Number: /12
3 In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. SECTION 5: Firefighting measures Flash point : No data available Autoignition temperature : 585 C (1,085 F) Suitable extinguishing media Unsuitable extinguishing media Special protective equipment for fire-fighters : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. : High volume water jet. : Wear self-contained breathing apparatus for firefighting if necessary. Further information : For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Fire and explosion protection Hazardous decomposition products : Do not spray on an open flame or any other incandescent material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. : No data available. SECTION 6: Accidental release measures Personal precautions : Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. SECTION 7: Handling and storage Handling Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open SDS Number: /12
4 drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Advice on protection against fire and explosion : Do not spray on an open flame or any other incandescent material. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Storage Requirements for storage areas and containers : Prevent unauthorized access. No smoking. Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards. SECTION 8: Exposure controls/personal protection Ingredients with workplace control parameters US Ingredients Basis Value Control parameters Note Ethylene ACGIH TWA 200 ppm, asphyxia, A4, A4 Not classifiable as a human carcinogen asphyxia Asphyxia Engineering measures Adequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user should read and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limited time or under certain circumstances. Personal protective equipment Respiratory protection : Wear a supplied-air NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that provides protection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release, exposure levels are not known, or other circumstances where airpurifying respirators may not provide adequate protection. Hand protection : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. Eye protection : Eye wash bottle with pure water. Safety glasses. SDS Number: /12
5 Skin and body protection : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Wear as appropriate:. Flame retardant antistatic protective clothing. Workers should wear antistatic footwear. Hygiene measures : Wash hands before breaks and at the end of workday. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Appearance Form Physical state Color Odor : Compressed gas : Gaseous : Colorless : Odorless Safety data Flash point : No data available Lower explosion limit Upper explosion limit Oxidizing properties : 4 %(V) : 75 %(V) : No Autoignition temperature : 585 C (1,085 F) Molecular formula Molecular weight ph Freezing point : UVCB : Not applicable : Not applicable : No data available Pour point Not applicable Boiling point/boiling range Vapor pressure : -253 C (-423 F) : No data available Density Water solubility Partition coefficient: n- octanol/water Viscosity, dynamic : LB/FT3 at ( MMHG) : Partly soluble : No data available : cp Relative vapor density : 0.5 SDS Number: /12
6 (Air = 1.0) Evaporation rate : Not applicable SECTION 10: Stability and reactivity Chemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Possibility of hazardous reactions Conditions to avoid : Heat, flames and sparks. Materials to avoid Hazardous decomposition products Other data : May react with oxygen and strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. : No data available : No decomposition if stored and applied as directed. SECTION 11: Toxicological information Acute oral toxicity : No data available Negligible or unlikely exposure pathways Acute inhalation toxicity : LC50: > 8000 ppm Test atmosphere: gas Method: Acute toxicity estimate Acute dermal toxicity : Negligible or unlikely exposure pathways Skin irritation : No skin irritation Eye irritation : No eye irritation Sensitization Repeated dose toxicity : No adverse effects expected. : This information is not available. Carcinogenicity SDS Number: /12
7 Ethylene : Species: Rat Dose: , 1000, 3000 ppm Exposure time: 2 yrs Number of exposures: 6 h/d, 5 d/wk Remarks: no increase incidence of tumors Reproductive toxicity Ethylene Ethane : Species: Rat Application Route: Inhalation Dose: , 1000, 5000 ppm Number of exposures: 6 h/d NOAEL Parent: 5000 ppm NOAEL F1: 5000 ppm no abnormalities observed Species: Rat Sex: male and female Application Route: Inhalation Dose: 0, 1600, 5000, ppm Exposure time: 6 weeks Number of exposures: 6 hours/day, 7 days/week Test period: 6 weeks Test substance: yes Method: OECD Guideline 422 NOAEL Parent: ppm NOAEL F1: ppm no abnormalities observed Developmental Toxicity Ethylene : Species: Rat Application Route: Inhalation Dose: , 1000, 5000 ppm Number of exposures: 6 h/d NOAEL Teratogenicity: 5000 ppm NOAEL Maternal: 5000 ppm No toxicity to reproduction Animal testing did not show any effects on fertility. Further information : No data available. SECTION 12: Ecological information Elimination information (persistence and degradability) Bioaccumulation Ethane : This material is not expected to bioaccumulate. This substance is not considered to be persistent, bioaccumulating and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulating (vpvb). SDS Number: /12
8 Biodegradability : Not applicable Ecotoxicology Assessment Results of PBT assessment Additional ecological information : This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher. : No data available SECTION 13: Disposal considerations The information in this SDS pertains only to the product as shipped. Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility. Product Contaminated packaging : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14: Transport information The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and the bill of lading. US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION) UN2034, HYDROGEN AND METHANE MIXTURES, COMPRESSED, 2.1 IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS) UN2034, HYDROGEN AND METHANE MIXTURE, COMPRESSED, 2.1 IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION) UN2034, HYDROGEN AND METHANE MIXTURE, COMPRESSED, 2.1 ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE)) UN2034, HYDROGEN AND METHANE MIXTURE, COMPRESSED, 2.1, (B/D) SDS Number: /12
9 RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE)) UN2034, HYDROGEN AND METHANE MIXTURE, COMPRESSED, 2.1 ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS) UN2034, HYDROGEN AND METHANE MIXTURE, COMPRESSED, 2.1 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information National legislation SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Gases under pressure Simple Asphyxiant EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO KNOW CERCLA Reportable Quantity : This material does not contain any components with a CERCLA RQ. SARA 302 Reportable Quantity : This material does not contain any components with a SARA 302 RQ. SARA 302 Threshold Planning Quantity SARA 304 Reportable Quantity : This material does not contain any components with a section 302 EHS TPQ. : This material does not contain any components with a section 304 EHS RQ. SARA 313 Ingredients : The following components are subject to reporting levels established by SARA Title III, Section 313: : Ethylene Clean Air Act SDS Number: /12
10 Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). The following chemical(s) are listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F): : Methane Ethylene Ethane The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR ): : Ethylene US State Regulations Pennsylvania Right To Know : Fuel Gas Methane Hydrogen Ethylene Ethane Nitrogen Carbon Monoxide California Prop. 65 Ingredients : WARNING: This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Notification status Europe REACH : Not in compliance with the inventory United States of America (USA) : On the inventory, or in compliance with the inventory TSCA Canada DSL : On the inventory, or in compliance with the inventory Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : Not in compliance with the inventory Japan ENCS : On the inventory, or in compliance with the inventory Korea KECI : On the inventory, or in compliance with the inventory Philippines PICCS : Not in compliance with the inventory China IECSC : Not in compliance with the inventory SDS Number: /12
11 SECTION 16: Other information NFPA Classification : Health Hazard: 0 Fire Hazard: 4 Reactivity Hazard: Further information Legacy SDS Number : 5860 Significant changes since the last version are highlighted in the margin. This version replaces all previous versions. The information in this SDS pertains only to the product as shipped. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Key or legend to abbreviations and acronyms used in the safety data sheet ACGIH American Conference of LD50 Lethal Dose 50% Government Industrial Hygienists AICS Australia, Inventory of Chemical Substances LOAEL Lowest Observed Adverse Effect Level DSL Canada, Domestic Substances NFPA National Fire Protection Agency List NDSL Canada, Non-Domestic Substances List NIOSH National Institute for Occupational Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure Scenario Tool OSHA Occupational Safety & Health Administration EOSCA European Oilfield Specialty PEL Permissible Exposure Limit Chemicals Association EINECS European Inventory of Existing Chemical Substances PICCS Philippines Inventory of Commercial Chemical Substances MAK Germany Maximum Concentration PRNT Presumed Not Toxic Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthorization Act. IARC International Agency for Research TLV Threshold Limit Value on Cancer IECSC Inventory of Existing Chemical TWA Time Weighted Average Substances in China ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act SDS Number: /12
12 KECI New Chemical Substances Korea, Existing Chemical Inventory UVCB Unknown or Variable Composition, Complex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials Information System LC50 Lethal Concentration 50% SDS Number: /12
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1. Identification Product name : Supplier : Sika Corporation 201 Polito Avenue Lyndhurst, NJ 07071 USA www.sikausa.com Telephone : (201) 933-8800 Telefax : (201) 804-1076 E-mail address : ehs@sika-corp.com
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1. Identification name : Supplier : Sika Corporation Address : 201 Polito Avenue Lyndhurst, NJ 07071 USA www.sikausa.com Telephone : (201) 933-8800 Telefax : (201) 804-1076 Emergency telephone : CHEMTREC:
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1. Identification name : Supplier : Sika Corporation Address : 201 Polito Avenue Lyndhurst, NJ 07071 USA www.sikausa.com Telephone : (201) 933-8800 Telefax : (201) 804-1076 Emergency telephone : CHEMTREC:
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