SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients. 4. First-aid measures

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions Adhesive. None known. Manufacturer / Importer / Supplier / Distributor information Company Name LATICRETE International Address 1 Laticrete Park, N Bethany, CT Telephone (203) Contact person Steve Fine Website Emergency phone number Call CHEMTREC day or night USA/Canada Mexico Outside USA/Canada Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Specific target organ toxicity, repeated exposure Category 2 (Kidney) Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Warning May cause damage to organs (Kidney) through prolonged or repeated exposure. Do not breathe mist or vapor. Get medical advice/attention if you feel unwell. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. Supplemental information Not applicable. 3. Composition/information on ingredients Mixtures Chemical name Calcium chloride Ethylene glycol CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Skin contact Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Wash skin with soap and water. Get medical attention if symptoms occur Version #: 01 Revision date: - Issue date: 25-November / 6

2 Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Flush eyes thoroughly with water for at least 15 minutes. Get medical attention if symptoms persist. Rinse mouth. Do not induce vomiting. Get medical attention if any discomfort continues. Symptoms include redness, itching and pain. Treat symptomatically. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Ethylene glycol (CAS ) Biological limit values Appropriate engineering controls Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see Section 13 of the SDS. Environmental manager must be informed of all major releases. Do not breathe mist or vapor. Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Keep container tightly closed. Store in a cool and well-ventilated place. Type Value Form Ceiling 100 mg/m3 Aerosol. No biological exposure limits noted for the ingredient(s). Provide adequate ventilation and minimize the risk of inhalation of vapors. Individual protection measures, such as personal protective equipment Eye/face protection Risk of contact: Wear protective gloves and goggles/face shield. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants Version #: 01 Revision date: - Issue date: 25-November / 6

3 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold Liquid. Liquid. White. Sweet. ph 6-10 Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 212 F (100 C) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density 1.04 Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Soluble in water. The product is stable and non reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Heat, flames and sparks. Oxidizing agents. Carbon dioxide (CO2). Carbon monoxide. Information on likely routes of exposure Ingestion May cause discomfort if swallowed. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity In high concentrations, vapors may be irritating to the respiratory system. May cause skin irritation. May cause eye irritation. Symptoms include redness, itching and pain. May cause discomfort if swallowed Version #: 01 Revision date: - Issue date: 25-November / 6

4 Components Calcium chloride (CAS ) Acute Oral LD50 Acute Dermal LD50 Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Components Aquatic Fish Species Rat Rabbit Rat May cause skin irritation on prolonged or repeated contact. May cause eye irritation on direct contact. Not a skin sensitizer. Test Results 1000 mg/kg 9530 mg/kg 4700 mg/kg No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. May cause damage to organs (Kidney) through prolonged or repeated exposure by ingestion. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. LC50 Species Fathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available for this product. Partition coefficient n-octanol / water (log Kow) Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information The product is soluble in water. DOT Not regulated as a hazardous material by DOT. IATA Not regulated as a dangerous good. Test Results 8050 mg/l, 96 hours No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied Version #: 01 Revision date: - Issue date: 25-November / 6

5 IMDG Not regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This substance/mixture is not intended to be transported in bulk. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical No LISTED SARA 313 (TRI reporting) Chemical name CAS number % by wt. Ethylene glycol Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) US state regulations US. Massachusetts RTK - Substance List This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK 500 lbs US. California Proposition 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) Version #: 01 Revision date: - Issue date: 25-November / 6 No

6 Country(s) or region Inventory name On inventory (yes/no)* Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe Japan Korea New Zealand Philippines United States & Puerto Rico European List of Notified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date - Version # 01 NFPA Ratings 25-November No References Disclaimer HSDB - Hazardous Substances Data Bank Registry of Toxic Effects of Chemical Substances (RTECS) The information in this (M)SDS was obtained from sources which we believe are reliable but cannot guarantee. Additionally, your use of this information is beyond our control and may be beyond our knowledge. Therefore, the information is provided without any representation or warranty express or implied Version #: 01 Revision date: - Issue date: 25-November / 6